Basf Se Corporation

Nico Veling

Dirk Lawrenz

Carmen-Elena Cimpeanu

Lucia Jimenez Garcia

Rainer Blum

Hermann Seyffer

Juergen Schmidt-Thuemmes

Theo Smit

The present invention relates to a process for producing an aqueous polymer dispersion by free-radically initiated aqueous emulsion polymerization, and also to the aqueous polymer dispersions produced by the process and to the use of these as a binder, adhesive, sizing agent for fibers, for the production of coatings or for the production of a paper coating slip.

Method for producing an aqueous polymer dispersion from vinylaromatic compound and conjugated aliphatic diene

The present invention relates to a process for producing an aqueous polymer dispersion by free-radically initiated aqueous emulsion polymerization, by polymerizing, in an aqueous medium,

Method for preparing an aqueous polymer dispersion from a vinyl aromatic compound and a conjugated aliphatic diene

The invention relates to a use of a coating layer on a paper substrate for blocking oxygen transfer through the coated paper substrate, wherein the coating layer on the paper substrate is obtainable by a process, which comprises the steps of (a) providing a paper substrate with a surface, (b) applying onto the surface of the provided paper substrate an aqueous coating mass, and (c) drying of the paper substrate with the applied aqueous coating mass to obtain the coated paper substrate, wherein the aqueous coating mass contains an aqueous dispersion of a copolymer P, which is obtainable by radically initiated emulsion polymerization of at least 40 parts by weight of styrene and 22 to 49 parts by weight of butadiene and optionally other monomers based on the sum total of the parts by weight of all monomers, which is always 100, in the presence of a first degraded starch. It relates further to a coated paper substrate obtainable with a coating mass comprising the aqueous dispersion of the copolymer P and a further saccharide, which is added after the polymerization of the monomers. It relates also to a process for manufacturing the coated paper substrate obtainable with a coating mass comprising the aqueous dispersion of the copolymer P and the further saccharide.

Use of a coating layer with a styrene-butadiene copolymer on a paper substrate for blocking oxygen transfer

The invention relates to a use of a coating layer on a paper substrate for blocking oxygen transfer through the coated paper substrate, wherein the coating layer on the paper substrate is obtainable by a process, which comprises the steps of (a) providing a paper substrate with a surface, (b) applying onto the surface of the provided paper substrate an aqueous coating mass, and (c) drying of the paper substrate with the applied aqueous coating mass to obtain the coated paper substrate, wherein the aqueous coating mass contains an aqueous dispersion of a polymer P, which is obtainable by radically initiated emulsion polymerization of at least 25 parts by weight of a C-Calkyl acrylate or a C-Calkyl methacrylate based on the sum total of the parts by weight of all monomers, which is always 100, in the presence of a first degraded starch. It relates further to a coated paper substrate obtainable with a coating mass comprising the aqueous dispersion of the polymer P and a further saccharide, which is added after the polymerization of the monomers. It relates also to a process for manufacturing the coated paper substrate obtainable with a coating mass comprising the aqueous dispersion of the polymer P and the further saccharide.

Use of a coating layer with an acrylate polymer on a paper substrate for blocking oxygen transfer

The invention relates to an aqueous dispersion of a polymer P, which comprises the emulsion polymerization of vinyl acetate, an acrylate monomer, which is a C-Calkyl acrylate or a C-Cmethacrylate, an &#x3b1;,&#x3b2;-ethylenically unsaturated C-Ccarboxylic acid and at least one out of glycidyl methacrylate, glycidyl acrylate, allyl methacrylate and allyl acrylate, in the presence of a starch derivative. Optionally, an additional monomer is an ethylenically unsaturated sulfonic acid, an ethylenically unsaturated other monomer or both of them. The aqueous polymer dispersion and a powder form thereof are useful for a paper coating slip containing one of the aforementioned forms. A paper or a cardboard, which is coated with the paper coating slip, shows surface strength, which is expressed by a good dry pick resistance, a good wet pick resistance or good offset test results. The aqueous polymer dispersion or the powder form thereof is furthermore useful as a binder.

Aqueous polymer dispersion for paper with a copolymer of vinyl acetate and an acrylate monomer prepared in the presence of a starch derivative

The invention relates to a process for preparing an aqueous dispersion of a polymer P, which comprises the emulsion polymerization of vinyl acetate, an acrylate monomer, which is a C-Calkyl acrylate or a C-Cmethacrylate, an &#x3b1;,&#x3b2;-ethylenically unsaturated C-Ccarboxylic acid, glycidyl methacrylate or glycidyl acrylate, optionally an ethylenically unsaturated sulfonic acid and optionally an ethylenically unsaturated other monomer. Furthermore, the aqueous polymer dispersion obtainable from this process and a powder form thereof are disclosed. They are useful for a paper coating slip containing one of the aforementioned forms. A paper or a cardboard, which is coated with the paper coating slip, shows surface strength, which is expressed by a good dry pick resistance, a good wet pick resistance or good offset test results. The aqueous polymer dispersion or the powder form thereof is furthermore useful as a binder.

Aqueous polymer dispersion for paper with a copolymer of vinyl acetate and an acrylate monomer

The invention relates to a process for preparing an aqueous dispersion of a polymer P, which comprises the emulsion polymerization of vinyl acetate, an acrylate monomer, which is a C-Calkyl acrylate or a C-Cmethacrylate, an &#x3b1;,&#x3b2;-ethlyenically unsaturated C3-C8 carboxylic acid and at least one out of glycidyl methacrylate, glycidyl acrylate, allyl methacrylate and allyl acrylate, in the presence of a starch derivative. Optionally, an additional monomer is an ethylenically unsaturated sulfonic acid, an ethylenically unsaturated other monomer or both of them. Furthermore, the aqueous polymer dispersion obtainable from this process and a powder form thereof are disclosed. They are useful for a paper coating slip containing one of the aforementioned forms. A paper or a cardboard, which is coated with the paper coating slip, shows surface strength, which is expressed by a good dry pick resistance, a good wet pick resistance or good offset test results. The aqueous polymer dispersion or the powder form thereof is furthermore useful as a binder.

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Heidelberg, Germany

Nico Veling