Rolls-royce Corporation

Rolls-royce North American Technologies Inc.

Ngunjoh Lawrence Ndamka

Li Li

Ann Bolcavage

Taylor K Blair

Stephanie Gong

Sunny Chang

Sean E Landwehr

Matthew R Gold

Bruce Edward Varney

Michael Cybulsky

Paul Morrell

Robert Golden

Taylor Keffer Blair

An example article includes a substrate and a barrier coating on the substrate. The barrier coating includes a matrix including a rare-earth disilicate extending from an inner interface facing the substrate to an outer surface opposite the inner interface. The barrier coating includes a graded volumetric distribution of rare-earth oxide rich (REO-rich) phase regions in the matrix along a direction from the inner interface to the outer surface. The graded volumetric distribution defines a first volumetric density of the REO-rich phase regions at a first region of the matrix adjacent the outer surface. The graded volumetric distribution defines a second volumetric density of the REO-rich phase regions at a second region of the matrix adjacent the inner surface. The second volumetric density is different from the first volumetric density. An example technique includes forming the barrier coating on the substrate of a component.

CMAS-resistant barrier coatings

An article may include a substrate including a ceramic matrix composite (CMC); a composite coating layer including a first coating material that includes a rare-earth disilicate and a second coating material that includes at least one of a rare-earth monosilicate, a CMAS-resistant material, or a high-temperature dislocating material, where the second coating material forms a substantially continuous phase in the composite coating layer.

Composite coating layer for ceramic matrix composite substrate

In some examples, an article may include a substrate and a coating system on the substrate. The coating system may include a layer comprising a plurality of voids, wherein respective voids of the plurality of voids define respective void volumes; and a nucleating agent within at least some of the respective void volumes of the layer, wherein the nucleating agent is configured to induce crystallization of the molten CMAS. The coating system may include an environmental barrier coating, thermal barrier coating, and/or abradable coating.

Coating system including nucleating agent

A method includes predicting a composition of calcium-magnesium-aluminum-silicate (CMAS) to be encountered by a high temperature mechanical system during use of the high temperature mechanical system. The method further includes selecting a composition of a CMAS-resistant barrier coating layer based at least in part on the predicted composition of CMAS. The CMAS-resistant barrier coating layer includes a base composition and at least one secondary oxide selected based on the predicted composition of CMAS. The at least one secondary oxide includes at least one of an oxide of a divalent element, an oxide of a trivalent element, or an oxide of a tetravalent element. The CMAS-resistant barrier coating layer comprises greater than 0 mol. % and less than about 7 mol. % of the at least one secondary oxide.

An article for use in a high-temperature environment that includes a substrate including a superalloy material, a ceramic, or a ceramic matrix composite, and an abradable coating on the substrate, the abradable coating including a rare earth silicate and a dislocator phase, the dislocator phase forms one or more distinct phase regions in the abradable coating and comprises at least one of hafnium diboride (HfB), zirconium diboride (ZrB), tantalum nitride (TaN or TaN), tantalum carbide (TaC), titanium diboride (TiB), zirconium carbide (ZrC), hafnium carbide (HfC), tantalum diboride (TaB), hafnium nitride (HfN), or niobium carbide (NbC).

Low porosity abradable coating

An article includes a substrate, a bond coat on the substrate, and a multilayer environmental barrier coating (EBC) on the bond coat. The multilayer EBC includes a first EBC layer defining a first thickness and a second EBC layer defining a second thickness. The first EBC layer includes a first rare earth disilicate and a first concentration of a sintering aid that includes alumina. The second EBC layer includes a second rare earth disilicate and a second concentration of the sintering aid that includes alumina, less than the first concentration of the sintering aid.

Multilayer environmental barrier coating

An arrangement comprising a component () adjacent to a ceramic matrix composite in a gas turbine engine is shown. The component comprises a nickel-base superalloy substrate () and a cobalt-modified beta-nickel-aluminide coating () on the substrate to prevent interdiffusion between the substrate and the ceramic matrix composite. The substrate is coated by depositing a cobalt layer on the substrate, depositing an aluminium layer on the cobalt layer and then forming a cobalt-modified beta nickel aluminide coating.

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Derby, United Kingdom

Ngunjoh Lawrence Ndamka