The Lubrizol Corporation

Infineum International Limited

Nga H Nguyen

Ronald Lewis

Ewan Galbraith

Paul E Adams

William D Abraham

Yanshi Zhang

Kurt F Wollenberg

Remzi Becer

Peter Miatt

Jun Xu

Matilde Concilio

Ronald M Lewis

The description involves a brush copolymer composition comprising a copolymeric backbone including monomeric repeat units of at least two different acrylate monomers and copolymeric brush arms including monomeric repeat units of at least two different acylated poly(alkylene amine)s, in which the brush arms, the brush copolymer, or both may advantageously exhibit UCST behavior, e.g, in hydrocarbon diluent. Methods of making such copolymers using RAFT and CROP (pseudo-)living reaction processes are also described herein.

Thermally responsive brush polymers having a copolymer backbone and copolymer arms

A comb copolymer viscosity modifier may be made by polymerization comprising at least, or consisting essentially of, the following monomers: (a) (optionally from 7.0 wt % to 18 wt %, by repeat units, of) a hydrogenated polybutadiene-based (alk)acrylate ester macromonomer; (b) (optionally from 33 wt % to 64 wt %, by repeat units, of) a C-Calkyl (alk)acrylate ester monomer; (c) a C-Calkyl (alk)acrylate ester monomer; and (d) (optionally from 3.0 wt % to 25 wt %, by repeat units, of) H-endcapped, C-Calkyl-endcapped, or C-Caryl-, aralkyl-, or alkaryl-endcapped C-Coxyalkyl or C-Coligo(alkylene glycol)-based (alk)acrylate ester monomer, wherein repeat units based on monomer (c) and/or monomer (d) comprise at least 21.0 wt % (and optionally up to 35.0 wt %) of repeat units of the comb copolymer viscosity modifier. Lubricant compositions comprising the comb copolymer viscosity modifier, as well as uses thereof and methods for modifying viscosity and dispersancy, are also contemplated.

High viscosity index comb polymer viscosity modifiers and methods of modifying lubricant viscosity using same

Lubricating compositions comprising an azole-acrylic adduct formed by contacting an azole compound with an acrylic. The adduct formed has at least one N-alkyl group comprising at least one acyl. The lubricating composition also comprises a thiadiazole. Methods of lubricating a component of a farm tractor, off-highway vehicle or drivetrain comprising contacting the component with the lubricating composition comprising an azole-acrylic adduct formed by mixing an azole compound with an acrylic. Methods of reducing corrosion in a component. The use of an azole-acrylic adduct in a lubricating composition to reduce corrosion in a component.

Azole derivatives as lubricating additives

A comb copolymer viscosity modifier may be made by polymerization comprising at least, or consisting essentially of, the following monomers: (a) a hydrogenated polybutadiene-based (alk)acrylate ester macromonomer (which repeat units may comprise from 7.0 wt % to 18 wt % of the repeat units of the comb copolymer viscosity modifier); (b) a C-Calkyl (alk)acrylate ester monomer (which repeat units may comprise from 40 wt % to 71 wt % or from 45 wt % to 64 wt % of the repeat units of the comb copolymer viscosity modifier); and (c) a C-Calkyl (alk)acrylate ester monomer, wherein repeat units based on the C-Calkyl (alk)acrylate ester monomer comprise at least 21.0 wt % (and optionally up to 35.0 wt %) of repeat units of the comb copolymer viscosity modifier. Lubricant compositions comprising the comb copolymer viscosity modifier, as well as uses thereof and methods for modifying viscosity, are also contemplated herein.

A comb copolymer viscosity modifier may be made by polymerization comprising at least, or consisting essentially of, the following monomers: (a) (optionally from 7.0 wt % to 18 wt %, by repeat units, of) a hydrogenated polybutadiene-based (alk)acrylate ester macromonomer; (b) (optionally from 33 wt % to 64 wt % or from 38 wt % to 58 wt %, by repeat units, of) a C-Calkyl (alk)acrylate ester monomer; (c) (optionally up to 35.0 wt %, by repeat units, of) a C-Calkyl (alk)acrylate ester monomer; and (d) (optionally from 3.0 wt % to 27 wt %, by repeat units, of) a C-Caryl, aralkyl, or alkaryl (alk)acrylate ester monomer, such that a sum of repeat units due to (c) plus (d) constitute at least 21.0 wt % of repeat units of the comb copolymer viscosity modifier. Lubricant compositions comprising the comb copolymer viscosity modifier, as well as uses thereof and methods for modifying viscosity and dispersancy, are also contemplated.

Lubricating compositions comprising an azole-acrylic adduct formed by contacting an azole compound with an acrylic. The adduct formed has at least one nitrogen-alkyl group comprising at least one acyl. The lubricating composition also comprises an antiwear agent and an antioxidant. Methods of lubricating an internal combustion engine comprising contacting the internal combustion engine with the lubricating composition comprising an azole-acrylic adduct formed by contacting an azole compound with an acrylic. Methods of reducing corrosion and/or seal deterioration in an internal combustion engine. The use of an azole-acrylic adduct in a lubricating composition to reduce corrosion and/or seal deterioration in an internal combustion engine.

Lubricating compositions comprising a mercaptoazole-acrylic adduct formed by contacting a mercaptoazole compound with an acrylic. The adduct formed has at least one sulfur-alkyl group comprising at least one acyl, or compounds having at least one nitrogen-alkyl group comprising at least one acyl, or mixtures thereof. The lubricating composition also comprises an antiwear agent and an antioxidant. Methods of lubricating an internal combustion engine comprising contacting the internal combustion engine with the lubricating composition comprising a mercaptoazole-acrylic adduct formed by contacting a mercaptoazole compound with an acrylic. Methods of reducing corrosion and/or seal deterioration in an internal combustion engine. The use of a mercaptoazole-acrylic adduct in a lubricating composition to reduce corrosion and/or seal deterioration in an internal combustion engine.

Mercaptoazole derivatives as lubricating additives

A lubricant composition of an oil of lubricating viscosity and a phosphite ester reaction product of a monomeric phosphorous acid or an ester thereof with a first alkylene diol having two hydroxy groups in a 1,4 or 1,5 or 1,6 relationship and a second, alkyl-substituted, diol being a substituted 1,3-propylene diol, exhibits good wear and frictional performance.

Growing community of inventors

Scotch Plains, NJ, United States of America

Nga H Nguyen