Dow Global Technolgoies LLC

Nelson G Rondan

Mark F Sonnenschein

Steven P Webb

William J Harris

John D Weaver

Drew A Davidock

The invention provides compositions comprising at least one propylene-based polymer, at least one peroxide and at least one coagent. In a preferred example, a composition comprising at least one propylene-based polymer, at least one peroxide, at least one grafting agent, and at least one coagent, and wherein the at least one coagent has a substituted carbon-carbon double bond structure selected from the group consisting of structures (I), (II), (III), (IV) and (V) as follows, including cis and trans isomers wherein D1, D2, D3 and D4 are each, independently, one of the following: (a) a hydrocarbon substituent containing a heteroatom with a nonbonding pair of electrons, and where the heteroatom with the nonbonding pair is directly attached to the carbon-carbon double bond, or (b) a hydrocarbon substituent containing a carbon-carbon pi bonding pair, and where the first carbon of the carbon-carbon pi bonding pair is directly bonded to the carbon-carbon double bond; and wherein the R1, R2 and R3 are each, independently, H, a hydrocarbon substituent, or a substituted hydrocarbon substituent; and wherein R1, R2 and R3, each, independently, does not have the same chemical structure as D1, D2, D3 or D4; and wherein the molar ratio of the 'coagent(s)' to 'free radicals formed from the peroxide(s)' is from 0.5:1 to 5:1; and wherein the coagent selected from structures (I)-(V) does not contain only one phenyl group, or does not contain only one furyl group. 

Functionalized polymers, articles prepared therefrom, and methods for making the same

Amine organoborane complex polymerization initiators and polymerizable compositions

A method of modifying the surface of a low surface energy polymer by contacting the surface with a composition comprising a) an organoborane/amine complex wherein the amine is selected from the group of amines having an amidine structural component; aliphatic heterocycles having at least one nitrogen in the heterocyclic ring; an alicyclic compound having bound to the ring a substituent having an amine moiety; amines which in addition to a primary amine have one or more hydrogen bond accepting groups of an ether, polyether, thioether or halogen wherein there is an alkylene chain of at least two carbon atoms between the primary amine and the hydrogen bond accepting group, and conjugated imines; b) one or more of monomers, oligomers or polymers having olefinic unsaturation; and optionally, c) an effective amount of a compound which causes the complex to disassociate.

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Missouri City, TX, United States of America

Nelson G Rondan