Bio-cide International, Inc.

Cudd Pressure Control, Inc.

Neeraj Khanna

William C Hunt

Bryan D Lowery

Theodore D Head

James P Ringo

Enrique M Proaño

Bobby C Danner

Roberta Reed

Robert Picek

Paul Reeves

Mark A Cochran

Andrew D Kramer

Benjamin J Whyatt

This invention relates to the use of chlorite-based antimicrobials in a manner where the time of biocidal activity is extended for the microbial control in the water used for drilling, completion and remediation of wells. The invention involves mixing of a compatible extender in the form of sodium chlorate with sodium chlorite to form an antimicrobial formulation. This combination is used with an acid on the site to generate chlorine dioxide which is injected into the water used for hydraulic fracturing or remedial workover. The formulation is a much more effective bactericide for the subterranean oil and gas rich formations. The potency and longevity of biocidal activity is controlled by varying the ratios of chlorate and acid which provide different profiles of the antimicrobial activities.

Method for extending time of activity of chlorite-based biocides

A system and method is provided for producing and delivering a product. The system includes a chamber having an inlet end, an outlet end and quenching points positioned therebetween. The inlet end is configured to receive a plurality of precursors and the quenching points are configured to receive water to obtain quenching of the reaction in the chamber thereby providing varying concentration of the resultant product.

Device for quenching reaction at variable time points

An hydraulic proportioning system having a fluid actuated motor with a driven motor shaft, the motor being in fluid communication with and powered by a fluid source. A pump is provided having a drive shaft driven by the driven motor shaft of the fluid actuated motor, and a drive clutch interconnecting the driven motor shaft and the drive shaft of the pump. An injector manifold is in fluid communication with the pump which is connectable to a chemical source. A tube is in fluid communication with the injector manifold and extends into a chamber having fluid communication with the fluid source, the chemical and fluid from the fluid source combining in the chamber and discharged therefrom.

Hydraulic proportioning system

A chemical generator having inlets for receiving multiple reactant and water streams; a dilution chamber; a reaction chamber operably connected to the inlets and to the dilution chamber; an eductor operably receiving the water stream from the one of the inlets and communicating with the reaction chamber for drawing first and second reactant streams into the reaction chamber for mixing. Float control valves interrupt the water stream to the eductor when desired amounts of the first and second reactant streams have entered the reaction chamber, the eductor drawing the activated solution of first and second reactant streams from the reaction chamber into the dilution chamber. The float control valves limit the residence time of the first and second reactants in the reaction chamber and selectively interrupt flow of the water stream into the dilution chamber.

Chemical generator using hydro-logic system

Expanded amorphous aluminum silicate (EAAS) is used as a vehicle for a chlorite salt. This vehicle, when exposed to moisture, will release chlorine dioxide (ClO ) for purposes of deodorization or microbial suppression. Thus, where a particular area or volume is to be deodorized or made less microbially contaminated, the EAAS-chlorite salt (most preferably sodium chlorite) is placed in the area or volume to be treated and moisture is permitted to interact with the material. The result of the moisture is to permit the chemical reaction (presumably acidification) of the chlorite salt to yield dioxide gas. While normal EAAS has some inherent acidity, the inherent acidity is low enough so that, even when a chloride salt is encapsulated in the EAAS and the resultant mixture exposed to moisture, ClO release is very slow and over an extended period.

Prevention of spoilage of produce using acidified expanded amorphous aluminum silicate impregnated with chlorite

The present invention provides a method for the disinfection of seafood. The inventive method includes the steps of (a) preparing a concentrated aqueous solution of a chlorine dioxide liberating compound having a concentration of from about 0.2% to about 25% by weight of the chlorine dioxide liberating compound and having an amount of an acid sufficient to adjust the pH to from about 1.0 to about 5.0; (b) diluting the concentrated aqueous solution to provide a dilute, acidified solution having a concentration of from about 0.00017% to about 0.17% by weight of the chlorine dioxide liberating compound; and (c)contacting the dilute, acidified solution with seafood to disinfect the seafood. Preferably, the chlorine dioxide liberating compound is an alkali metal chlorites, with sodium chlorite and potassium chlorite being particularly preferred. The acid may be any acid generally regarded as safe, as that term is used in the Code of Federal Register, 21 CFR 170.35 and 21 CFR 170.30.

Acidified metal chlorite solution for disinfection of seafood

An important and central aspect of the present invention is the use of expanded amorphous aluminum silicate (EAAS) as a vehicle for a chlorite salt. This vehicle, when exposed to moisture, will release chlorine dioxide (ClO.sub.2) for purposes of deodorization or microbial suppression. Thus, where a particular area or volume is to be deodorized or made less microbally contaminated, the EAAS-chlorite salt (most preferably sodium chlorite) is placed in the area or volume to be treated and moisture is permitted to interact with the material. The result of the moisture is to permit the chemical reaction (presumably acidification) of the chlorite salt to yield chlorine dioxide gas. While normal EAAS has some inherent acidity, the inherent acidity is low enough so that, even when a chloride salt is encapsulated in the EAAS and the resultant mixture exposed to moisture, ClO.sub.2 release is very slow and over an extended period. Under most conditions, a more rapid release of ClO.sub.2 is desired for deodorization and/or sterilization. A more rapid release of chlorine dioxide may be accomplished by first treating the native EAAS with an acid, preferably a protic acid, to acidify chemical groups of the EAAS. After native EAAS is acidified and dried, if necessary, a chlorite salt such as sodium chlorite is incorporated therein.

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Norman, OK, United States of America

Neeraj Khanna