University of Michigan

Nathan Taylor

Jeffrey S Sakamoto

Travis Thompson

Neil P Dasgupta

Eric Kazyak

Asma Sharafi

Michael Wang

A method of and apparatus for sinter forging a precursor powder to form a film may reduce or eliminate the stress in the film and may facilitate processing of continuous length of films such as ceramic films for use in batteries. The precursor powder can be provided on a substrate and is simultaneously heated and pressed in a pressing direction parallel to a thickness of the film so as to sinter and densify the precursor powder to form the film in a sinter forging area. Notably, in a plane perpendicular to the pressing direction, there are no lateral constraints on the sinter forging area or the material received therein.

Rapid-induction sinter forge for roll-to-roll continuous manufacturing of thin films

A method is disclosed for suppressing propagation of a metal in a solid state electrolyte during cycling of an electrochemical device including the solid state electrolyte and an electrode comprising the metal. One method comprises forming the solid state electrolyte such that the solid state electrolyte has a structure comprising a plurality of grains of a metal-ion conductive material and a grain boundary phase located at some or all of grain boundaries between the grains, wherein the grain boundary phase suppresses propagation of the metal in the solid state electrolyte during cycling. Another method comprises forming the solid state electrolyte such that the solid state electrolyte is a single crystal.

Method for suppressing metal propagation in solid electrolytes

Disclosed are electrochemical devices, such as lithium ion battery electrodes, lithium ion conducting solid-state electrolytes, and solid-state lithium ion batteries including these electrodes and solid-state electrolytes. Also disclosed are methods for making such electrochemical devices. Also disclosed are composite electrodes for solid state electrochemical devices. The composite electrodes include one or more separate phases within the electrode that provide electronic and ionic conduction pathways in the electrode active material phase.

Mixed ionic and electronic conductor for solid state battery

Disclosed are electrochemical devices and methods for making electrochemical devices such as metal infiltrated electrodes for solid state lithium ion and lithium metal batteries. In one method for forming an electrode, a metal is infiltrated into the pore space of the active material of the electrode providing improved electronic conductivity to the electrode. The electrode may also include a solid-state ion conducting material providing improved ion conductivity to the electrode. Before infiltration of the metal, a stabilization coating may be applied to the active material and/or the solid-state ion conducting material to the stabilize electrode interfaces by slowing, but not eliminating, the chemical reactions that occur at elevated temperatures during sintering of the active material and/or the solid-state ion conducting material forming the electrode.

Metal infiltrated electrodes for solid state batteries

The present disclosure relates to a method for forming solid-state electrolytes, electrodes, current collectors, and/or conductive additives used in solid-state batteries. In one version, the method includes depositing a stabilization coating on a powdered electrolyte material, or a powdered electrode material, or a powdered conductive additive material and forming a slurry comprising the coated material. The slurry is then cast on a surface to form a layer, and the layer is sintered to form a solid state electrolyte, or an electrode, or an electrode having the conductive additive.

Stabilization coatings for solid state batteries

An article for forming an electrochemical device is disclosed. The article comprises a metallic current collector clad with an ion conducting solid-electrolyte material such that intimate contact between the current collector and the ion conducting solid-electrolyte material is made. A lithium metal anode can be formed in situ between the current collector clad and the ion conducting solid-electrolyte material from lithium ions contained within a cathode material that is placed in contact with the ion conducting solid-electrolyte material. A bipolar electrochemical cell can be constructed from the article.

Current collector clad with lithium ion conducting solid electrolyte

Disclosed are electrochemical devices, such as lithium battery electrodes, lithium ion conducting solid-state electrolytes, and solid-state lithium metal batteries including these electrodes and solid-state electrolytes. In one disclosed method, a solid state electrolyte material including a precursor layer having a first electronic conductivity is provided; and the precursor layer on the solid state electrolyte material is reduced to an interfacial layer having a second electronic conductivity greater than the first electronic conductivity. Also disclosed is a method of forming a solid state electrolyte for an electrochemical device including an anode comprising an electrochemically active metal, wherein the method comprises providing a solid state electrolyte material, and depositing an interfacial layer comprising a first metal on the surface of the solid state electrolyte material, wherein the electrochemically active metal does not form an alloy with the first metal during cycling or formation of the electrochemical device.

Growing community of inventors

Ann Arbor, MI, United States of America

Nathan Taylor