Nathalie Monfreux-Gaillard

Patrick Perrin

Christopher Alan Sawdon

Françoise LaFuma

Fran&ccedil;oise LaFuma

The invention concerns modified hydrophobic polyelectrolytes by amide formation of a hydrophilic skeleton by n-alkylamines whereof the alkyl chain comprises 6 to 22 carbon atoms. Preferably, the amide formation is obtained by di-n-dodecylamine. The hydrophilic skeleton is preferably a sodium polyacrylate or polyacrylic acid corresponding to a statistical acrylate-AMPS copolymer. Said polymers can be used for stabilizing direct or invert emulsions likely to be destabilized or inverted by a modification in the degree of salinity of the aqueous phase or a pH modification. The invention is particularly useful for stabilizing oil drilling fluids or the like in particular drilling, fracturation, acidification or completion fluids.

Reversible emulsions stabilized by amphiphilic polymers

Reversible emulsions stabilized by amphiphilic polymers and application to drilling fluid

The invention concerns modified hydrophobic polyelectrolytes by amide formation of a hydrophilic skeleton by n-alkylamines whereof the alkyl chain comprises 6 to 22 carbon atoms. Preferably, the amide formation is obtained by di-n-dodecylamine. The hydrophilic skeleton is preferably a sodium polyacrylate or polyacrylic acid corresponding to a statistical acrylate-AMPS copolymer. Said polymers can be used for stabilising direct or invert emulsions likely to be destabilised or inverted by a modification in the degree of salinity of the aqueous phase or a pH modification. The invention is particularly useful for stabilising oil drilling fluids or the like in particular drilling, fracturation, acidification or completion fluids.

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Paris, France

Nathalie Monfreux-Gaillard