The Lubrizol Corporation

Naresh Chand Mathur

Mary Galic Raguz

James R Shanklin, Jr

Richard M Lange

Jeffry G Dietz

Richard Yodice

Edward J Konzman

Hyun-Soo Hong

Ichiro Minami

This invention relates to an aqueous composition comprising water, a surfactant or thickener, and at least one metal-free thiophosphorus acid ester, at least one amine salt of the thiophosphorus acid ester, or a mixture thereof, wherein the thiophosphorus acid ester contains at least one hydrocarbyl terminated oxyalkylene group, at least one hydrocarbyl terminated polyoxyalkylene group, or a mixture thereof. The aqueous compositions have improved antiwear/extreme pressure properties and improved antioxidation properties. In these compositions, the thiophosphorus acid esters and their salts act as antiwear agents and rust inhibitors.

Aqueous compositions containing thiophosphorus esters or their salts with a oxyalkylene group, and methods of using the same

Lubricating oil additives

A composition, comprising from about 20% to about 80% by weight of a diluent, prepared by reacting a mixture comprising

This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity and at least one metal-free thiophosphorus acid ester, at least one amine salt of the thiophosphorus acid ester, or a mixture thereof, wherein the thiophosphorus acid ester contains at least one hydrocarbyl terminated oxyalkylene group, at least one hydrocarbyl terminated polyoxyalkylene group, or a mixture thereof. In one embodiment, the thiophosphorus acid ester is a thiophosphorus acid ester represented by the following formula ##STR1## wherein X.sub.1, X.sub.2, and X.sub.3 are oxygen or sulfur, provided that at least one of X.sub.1, X.sub.2, and X.sub.3 is sulfur; R.sub.1 is a hydrocarbyl group; R.sub.2 is an alkylene group; R.sub.3 is hydrogen or a hydrocarbyl group; x is a number from 1 to about 40; and a is 0, 1, or 2, or at least one salt of the thiophosphorus acid ester. The lubricating compositions, functional fluids and greases have improved antiwear/extreme pressure properties and improved antioxidation properties. In functional fluids, the thiophosphorus acid esters and their salts act as antiwear agents and rust inhibitors.

Lubricating compositions, functional fluids and greases containing

A composition of an oil of lubricating viscosity, a phosphorus compound represented by the formula ##STR1## and tautomers thereof, where each X is independently O or S, and an olefin of about 6 to about 30 carbon atoms exhibits improved antiwear performance.

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Highland Heights, OH, United States of America

Naresh Chand Mathur