E.i. Dupont De Nemours and Company

Narayanan Sankara Subramanian

Russell Bertrum Diemer, Jr

Pratibha Laxman Gai

Charles David Musick

Loren D Brake

David A Zimmerman

Stephen William Taylor

Alan Roger Eaton

David D Zhang

George Alan Schurr

Peter Jernakoff

Philipp Martin Niedenzu

Kevin J Leary

Alvin Allen

James Nelson Tilton

Stephen Claude De La Veaux

John Nicholas Birmingham

Yung-Hsing Samson Hsu

Kunle Ogunde

John Steven Gergely

Rajeev Lochan Gorowara

Yunghsing Samson Hsu

Richard P Bernard

Russell Bertrum Diemer

The disclosure provides a melt processible theromoplastic composition, comprising a major proportion of a base polymer comprising a first melt processible thermoplastic polymer having a first Fedor's solubility parameter and a first viscosity; and a combination of a carrier polymer and a surface modifying additive, the carrier polymer comprising a second melt processible thermoplastic polymer which has a second Fedor's solubility parameter that is at least about 2.5 (J/cm)lower than the first Fedor's solubility parameter, and a second viscosity, the carrier polymer being adhered to the surface modifying additive, and wherein the first viscosity is at least about 10 times the second viscosity.

Plastic surfaces having improved surface characteristics

This disclosure relates to process for producing titanium dioxide pigment having reduced chlorides, comprising: a) reacting titanium tetrahalide vapor, rutile-forming agent and at least a stoichiometric amount of oxygen in a reactor to form a gaseous suspension comprising titanium dioxide particles; b) introducing silicon tetrachloride into the reactor at least one point downstream of the point of contact of the titanium tetrahalide, the rutile forming agent and the oxygen, and where at least 97% of the titanium tetrahalide has been converted to titanium dioxide to provide a substantially uniform encapsulation of pyrogenic SiOon the titanium dioxide; c) passing the gaseous suspension to a cooling conduit; d) introducing scouring material, typically selected from the group of calcined titanium dioxide and compressed titanium dioxide, and mixtures thereof, into the cooling conduit; wherein the particles of the scouring material have a diameter in the range of about 0.25 mm to about 12.7 mm and forming a cooled product having a solid and a vapor phase; e) separating the vapor phase from the cooled product to form a powder comprising the titanium dioxide particles, and a content of chlorine-containing material ranging from about 500 to about 3000 ppm of oxychloride, and the scouring material; and f) subjecting the powder to substantially uniform heating at a temperature of about 200&#xb0; C. to about 600&#xb0; C., in the presence of moisture, to reduce the content of chlorine-containing material to less than about 60 ppm oxychloride; wherein the moisture present is in at least a stoichiometric amount with the oxychloride.

Process for producing titanium dioxide particles having reduced chlorides

The present disclosure relates to a process for making treated inorganic particles by vapor phase deposition of surface treatments on the particle surface by reacting inorganic particles, typically titanium dioxide particles, with a composition comprising a sinterable material and a liquid medium at a temperature sufficient to evaporate the medium and release the sinterable material as aerosol particles. The aerosol particles sinter and form a treatment on the surfaces of the inorganic particles.

Process for treating inorganic particles via sintering of sinterable material

One aspect of the invention is to provide a composition comprising a titanium dioxide particle having on the surface of said particle a substantially encapsulating layer comprising a pyrogenically-deposited metal oxide; said substantially encapsulating layer having on its surface at least one organic surface treatment material selected from an organo-silane, an organo-siloxane, a fluoro-silane, an organo-phosphonate, an organo-acid phosphate, an organo-pyrophosphate, an organo-polyphosphate, an organo-metaphosphate, an organo-phosphinate, an organo-sulfonic compound, a hydrocarbon-based carboxylic acid, an associated ester of a hydrocarbon-based carboxylic acid, a derivative of a hydrocarbon-based carboxylic acid, a hydrocarbon-based amide, a low molecular weight hydrocarbon wax, a low molecular weight polyolefin, a co-polymer of a low molecular weight polyolefin, a hydrocarbon-based polyol, a derivative of a hydrocarbon-based polyol, an alkanolamine, a derivative of an alkanolamine, an organic dispersing agent, or a mixture thereof. Another aspect of the invention is to provide processes for producing said composition.

Preparation of organic additive-treated, pyrogenic silica-encapsulated titanium dioxide particles

This disclosure relates to a process for producing titanium dioxide, comprising:

Process for producing titanium dioxide

This disclosure relates to process for producing titanium dioxide (TiO) pigments, comprising the following steps: a) oxidizing a mixture of titanium tetrahalide and a rutile forming agent, such as aluminum halide, present in the vapor phase and in the presence of a nucleant to form a gaseous suspension comprising titanium dioxide particles; b) passing the gaseous suspension to a cooling conduit; c) introducing scouring material into the cooling conduit; wherein the particles of the scouring material have a diameter in the range of about 0.25 mm to about 12.7 mm; d) separating the vapor phase to form a powder comprising the titanium dioxide particles and the scouring material; and e) simultaneously subjecting the powder to substantially uniform heating at a temperature of about 300&#xb0; C. to about 600&#xb0; C. and reducing the size of the titanium dioxide particles and the particles of the scouring material in the powder to a mean particle size of about 50 nm to about 1000 nm, whereby the titanium dioxide pigment has a chloride content of less than about 500 ppm. The so treated powder may have a residual free chlorine content of less than about 1 ppm.

Titanium dioxide finishing process

The present invention relates to a process for making durable titanium dioxide pigment by vapor phase deposition of surface treatments on the titanium dioxide particle surface by reacting titanium tetrachloride vapor, an oxygen containing gas and aluminum chloride in a plug flow reactor to form a product stream containing titanium dioxide particles; and introducing silicon tetrachloride into the reactor at a point down stream of the point where the titanium tetrachloride and oxygen were contacted and where at least 97% of the titanium tetrachloride has been converted to titanium dioxide or where the reaction temperature is no greater than about 1200&#xb0; C., and preferably not more than about 1100&#xb0; C.

Process for making durable rutile titanium dioxide pigment by vapor phase deposition of surface treatment

Process for making durable rutile titanium dioxide pigment by vapor phase deposition of surface treatments

The present invention provides a process for producing titanium dioxide (TiO.sub.2) pigment having a coating comprising silica and a second oxide selected from the group consisting of oxides of boron, phosphorus, magnesium, niobium, germanium, and mixtures thereof, comprising the steps of (a) reacting titanium tetrachloride (TiCl.sub.4) in the vapor phase with an aluminum compound and an oxygen-containing gas in a reactor at a temperature in the range of about 900.degree. C. to about 1600.degree. C. to provide a gaseous suspension comprising TiO.sub.2 particles, (b) contacting the gaseous suspension comprising the TiO.sub.2 particles with a silicon halide and an oxide precursor of boron, phosphorus, magnesium, niobium, germanium, and mixtures thereof, and (c) cooling the gaseous suspension to produce TiO.sub.2 pigment having a coating comprising silica and a second oxide.

Process for producing coated TiO.sub.2 pigment using cooxidation to

This invention relates to an improved process for making titanium dioxide pigment, wherein granular scouring particles (scrubs) comprising specific water-soluble salts (KCl, CsCl, or mixtures thereof) are introduced into a cooling conduit containing a hot gaseous suspension of titanium dioxide particulate. The process provides titanium dioxide pigment having higher carbon black undertone (CBU) levels.

Granular scrubs for use in manufacturing titanium dioxide pigment

Rapid recovery from waste of high molecular weight polyhydroxyacid content by depolymerizing the PHA in acidic water.

Rapid depolymerization of polyhydroxy acids

Recovery of polyhydroxy acids (PHAs) from waste containing high molecular weight polyhydroxy acid polymer by depolymerizing the PHA in water at elevated temperature and pressure.

An improved continuous process for producing random ethylene/acrylate/cure-site copolymers with greater efficiency by copolymerizing therewith a small quantity of certain polyfunctional monomers, such as diallyl maleate.

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Hockessin, DE, United States of America

Narayanan Sankara Subramanian