Sumitomo Electric Industries, Limited

Sumitomo Wiring Systems, Limited

Autonetworks Technologies, Limited

Kyushu University

Eneos Corporation

Naoyuki Oshiumi

Makoto Mizoguchi

Takehiro Hosokawa

Yutaka Takata

Tatsuya Hase

Shigeyuki Tanaka

Kazuhiro Yagishita

Koichi Yoshida

Tetsuya Nakamura

Takuya Yamashita

Yuji Shitara

Hironobu Rachi

Kenichi Komiya

Takashi Arai

Kenji Ito

Kohei Kobayashi

Takashi Takada

Naho Yoshioka

To provide a metal-containing additive and a crosslinkable polymer composition that each contain a β-diketonato metal complex and have excellent storage stability, and provide a crosslinked polymer material, a metal member, and a wire harness that are each produced using such a crosslinkable polymer composition. The metal-containing additive includes the β-diketonato metal complex and a primary alkyl alcohol having 4 to 30 carbon atoms. The crosslinkable polymer composition includes the metal-containing additive and an organic polymer, where the organic polymer has a substituent capable of forming ionic bonds with metal ions released by heat from the metal-containing additive.

Metal-containing additive, crosslinkable polymer composition, crosslinked polymer material, metal member, and wire harness

A crosslinkable polymer composition and a crosslinked polymer material including a metal member and a wiring harness. The crosslinkable polymer composition contains component A from which metal ion is released by heat, component B containing an organic polymer having a substituent capable of ionic bonding with the metal ion released from component A, and component C containing one or more acidic phosphate ester with a carbon number of 4 to 30. Assuming that the metal ion released from component A has a valence of +y and a content of the metal ion is m mol, the substituent contained in component B has a valence of −z and a content of the substituent is n mol, the acidic phosphate constituting component C has a valence of −x and a content of the acidic phosphate esters is 1 mol≥0.1 holds for=()/().

Crosslinkable polymer composition, crosslinked polymer material, metal member, and wiring harness

A metal-crosslinkable polymer composition and a metal crosslinked polymeric material having excellent curing rate and storage stability, and a metal member and a wiring harness to which the metal-crosslinkable polymer composition and the metal crosslinked polymeric material are applied. The metal-crosslinkable polymer composition includes an ingredient A which releases a metal ion when heated, and an ingredient B includes an organic polymer having a substituent group capable of forming an ionic bond with the metal ion released from the ingredient A. The metal-crosslinked polymeric material includes a crosslinked product of the metal-crosslinkable polymer composition. The metal member has a metal base member and a coating member covering a surface of the metal base member, where the coating member includes the metal-crosslinked polymeric material. The wiring harness includes the metal-crosslinked polymeric material.

Metal-crosslinkable polymer composition, metal-crosslinked polymeric material, metal component, and wiring harness

Provided are a surface protection composition which has excellent anticorrosion performance to prevent the metal corrosion, and also has excellent coating properties and heat resistance with suppressing cracks from being occurred even in a cold environment and maintaining anticorrosion performance, and a terminal-fitted electric wire using these. The present protection composition contains: (a) a phosphorus compound represented by the following general formula (1) in an amount of 0.1 to 10 mass % in terms of phosphorus element with respect to the total amount of the composition; (b) a metal-containing compound in an amount of 0.1 to 10 mass % in terms of the metal element with respect to the total amount of the composition or an amine compound in an amount of 0.1 to 5.0 mass % in terms of nitrogen element with respect to the total amount of the composition; (c) a (meth) acrylate having two or more carbon-carbon double bonds and hydrocarbon chains having four or more carbon atoms in an amount of 1.0 to 70 mass % with respect to the total amount of the composition; (d) a mono (meth) acrylate having a hydrocarbon chain having seven or more carbon atoms in an amount of 1.0 to 80 mass % with respect to the total amount of the composition; and (e) at least one of a photopolymerization initiator and a thermal polymerization initiator in an amount of 0.1 to 10 mass % with respect to the total amount of the composition. In the above-presented general formula (1), Rrepresents a hydrogen atom, Rrepresents a hydrocarbon group having 4 to 30 carbon atoms, and Rrepresents a hydrogen atom or a hydrocarbon group having 4 to 30 carbon atoms.

Surface protection composition and terminal fitted electric wire

A surface protection composition contains (a) a phosphorus compound represented by formula (1), wherein Rrepresents a hydrogen atom, Rrepresents a hydrocarbon group having 4 to 30 carbon atoms, and Rrepresents a hydrogen atom or a hydrocarbon group having 4 to 30 carbon atoms, (b-1) a metal-containing compound or (b-2) an amine compound, (c) a (meth)acrylate having a hydrocarbon chain having 4 or more carbon atoms, (d-1) an acylphosphine oxide photopolymerization initiator and (d-2) an α-aminoacetophenone photopolymerization initiator, wherein the composition has the compound (d-1) in an amount of 0.1 to 3.0 mass % with respect to the total amount of the composition, compound (d-2) in an amount of 0.1 to 3.0 mass % with respect to the total amount of the composition and a total amount of the compound (d-I) and (d-2) is less than 5.0 mass % with respect to the total amount of the composition.

A surface protection composition having a compound represented by the formula (1) in an amount of 0.1 to 10 mass % in terms of phosphorus element with respect to the total amount of the composition, the compound (b) the metal-containing compound in an amount of 0.1 to 10 mass % in terms of a metal element with the total amount of the composition or the amine compound in an amount of 0.1 to 5.0 mass % in terms of nitrogen element the total amount of the composition, the compound (c) (meth)acrylate having 2 or more carbon-carbon double bonds and hydrocarbon chains having four or more carbon atoms in an amount of 1.0 to 70 mass % with the total amount of the composition, the compound (d) a photopolymerization initiator in an amount of 0.1 to 10 mass % with the total amount of the composition.

A surface protection composition forms a uniform film, and a terminal fitted electric wire coated with the composition, the composition containing (a) a phosphorus compound represented by the formula (1) in an amount of 0.1 to 10 mass % in terms of phosphorus element, (b) a metal-containing compound in an amount of 0.1 to 10 mass % in terms of metal element or an amine compound in an amount of 0.1 to 5.0 mass % in terms of nitrogen element, (c) a (meth)acrylate compatible with a solvent with a solubility parameter of 8.2 or lower and has a hydrocarbon chain with 4 or higher carbon atoms in an amount of 1.0 to 70 mass %, and (d) at least one of a photopolymerization initiator and a thermal polymerization initiator in an amount of 0.1 to 10 mass %, with respect to the total amount of the composition.

Provided is a surface protection composition excellent in anticorrosion property for preventing metal corrosion as well as excellent in uniform applicability and heat resistance, and a terminal-fitted electric wire treated with the composition. The surface protection composition contains a phosphorus compound (a) represented by the general formula (1) in an amount of 0.1 to 10 mass % in terms of phosphorus element with respect to the total amount of the composition, at least one selected from the group consisting of a phosphorus compound (b1) represented by the general formula (2) and a carboxylic acid compound (b2) represented by the general formula (3) in an amount of 5.0 to 60 mass % with respect to the total amount of the composition, a metal-containing compound (c) in an amount of 0.1 to 10 mass % in terms of metal element with respect to the total amount of the composition, and a lubricant base oil (d).

A surface protection composition which is hard to deform or flow even placed under environments of a large temperature change with an external physical load such as pressure, and which stably protects a metal surface. A terminal fitted electric wire coated with the composition. The surface protection composition contains a high-consistency material (A) containing a lubricant base oil and an amide compound, and a phosphorus composition (B). The phosphorus composition (B) contains a composition (b1) containing one or more compounds represented by the general formulae (1) and (2) and one or more metals and/or one or more amines. The phosphorus composition (B) also contains one or more compounds (b2) represented by the general formula (3).

An anticorrosive agent including: a high-consistency material having a lubricant base oil and an amide compound, a composition of a phosphorus compound comprising one or more compounds represented by the general formulae (1) and (2) and a metal, and at least one kind of resin selected from a rosin-based resin, a terpene resin, a terpene phenol resin, a phenol resin, a coumarone-indene resin, and a petroleum resin, wherein a mass ratio of the high-consistency material and the composition is within a range of 50:50 to 98:2, and a content of resin is 2 to 20 parts by mass with respect to 100 parts by mass of the total of the high-consistency material and the composition.

Anticorrosive agent and terminal fitted electric wire

An anticorrosive agent maintains its anticorrosion property when the agent is applied to the connection part of the terminal-fitted electric wire containing a covering member containing a plasticizer, and is exposed to high temperature. A terminal-fitted electric wire improves in anticorrosion property by using the agent. The anticorrosive agent contains a base oil (A) having a viscosity of 30 mPa&#xb7;s or higher at 100&#xb0; C., and a metal adsorbent (B) containing a phosphorus compound. The mass composition ratio (A):(B) of the base oil (A) and the metal adsorbent (B) is within a range of 50:50 to 98:2. In the terminal-fitted electric wire, an electric connection part between a terminal and an electric conductor is covered with a film of the anticorrosive agent.

Provided is an anticorrosive containing a curable resin composition and that has a high anticorrosive capability and a good adhesion to an oily surface, and a terminal-attached covered electric wire and a wiring harness using the anticorrosive. The terminal-attached covered electric wire has a contact portion where a wire conductor of a covered electric wire and a connection terminal contact each other. The contact portion is covered with the anticorrosive. The wiring harness contains the terminal-attached covered electric wire. The curable resin composition contains 100 parts by mass of a polymer of a (meth)acrylate monomer, the polymer having two or more (meth)acrylate groups, 40 to 90 parts by mass of isobornyl (meth)acrylate, and 1 to 15 part by mass of an alkyl (meth)acrylate represented by formula 1, where R1 is either H or CH3, and R2 is an alkyl group having a carbon number of 8 to 13, 

Anticorrosive, terminal-attached covered electric wire, and wiring harness

A terminal-equipped coated wire having an exposed conductor portion at an end portion of a coated wire in which a conductor is coated with a coating material, a terminal fitting&#x2014;connected to the conductor at the exposed conductor portion, and an anticorrosive agent with which a contact portion between the conductor and the terminal fitting is sealed, wherein an anticorrosive agent which is composed of a cured product of a curable resin and in which the cured product has a crosslink density within a range of 0.6&#xd7;10to 4&#xd7;10(mol/cm) is used as the anticorrosive agent.

Terminal-equipped coated wire

A wire harness includes a terminated covered electric wire. The terminated covered electric wire includes a terminal fitting, an electric wire conductor, and an electrical connection portion in which the terminal fitting and the electric wire conductor are electrically connected to each other. The terminal fitting has a surface to which processing oil adheres, and the electrical connection portion is covered with an anticorrosive agent containing an adhesive resin and an oil-adsorbing organic macromolecule to configure a terminated covered electric wire.

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Yokkaichi, Japan

Naoyuki Oshiumi