Mitsubishi Materials Corporation

The Kansai Electric Power Co., Inc.

Tha Kansai Electrical Power Co., Inc.

Naoya Murakami

Masami Miyake

Wataru Saiki

Kazuki Mizushima

Taner Akbay

Takashi Miyazawa

Takafumi Kotani

Koji Hoshino

Norikazu Komada

Takashi Yamada

Katsuya Hirata

Masaharu Yamada

An apparatus for producing trichlorosilane from raw gas containing silicon tetrachloride and hydrogen, having: a reaction chamber being supplied with the raw gas for generating reacted gas containing trichlorosilane and hydrogen; a plurality of heaters heating the raw gas and having exothermic portions being disposed along a vertical direction in the reaction chamber; a plurality of electrodes being connected to basal portions of the heaters; and a radiation plate being disposed between the exothermic portions of the heaters.

Apparatus for producing trichlorosilane

An apparatus for producing trichlorosilane in which reacted gas including trichlorosilane and hydrogen chloride is produced by heating raw gas including silicon tetrachloride and hydrogen, the apparatus having: a reaction vessel having a substantially cylindrical shape and being provided with a heated wall forming a gas flow-passage along an axis direction; and a heater heating the heated wall, wherein a folding flow-passage is provided at an uppermost stream of the gas flow-passage and has: an inlet flow-passage in which raw gas is introduced; and a turning part connected to a downstream of the inlet flow-passage in which a flow direction of the raw gas is turned at least once in an opposite direction, the turning part is formed between the inlet flow-passage and the heated wall in the folding flow-passage, and a turning length of the folding flow-passage along the axis direction is smaller than a maximum length of the gas flow-passage along the axis direction.

An apparatus for producing trichlorosilane, including: a reaction vessel that has a substantially cylindrical wall body, a top plate, and a bottom plate, where a reaction product gas is produced from a raw gas supplied to the reaction vessel through a gas introducing passage provided to the lower section of the cylindrical wall body; and a plurality of heaters that are disposed inside the reaction vessel to heat the raw gas, wherein each of the heaters has a heating element that is elongated in a vertical direction and generates heat by electrification, and a mount that is fixed to the bottom plate and supports the heating element; a flange is provided to intermediate height of the heating element such that the flange is arranged upper than the gas introducing passage and is elongated in horizontal direction; and a passage of the raw gas formed between adjacent heaters is narrowed by the flange.

Apparatus for producing trichlorosilane and method for producing trichlorosilane

In an apparatus for producing trichlorosilane, an internal space of a reaction chamber is partitioned in a radial direction by first walls running along a circumferential direction, and is partitioned into multiple spaces by second walls which extend in a direction crossing the circumferential direction. Upper portions or lower portions of the first walls and the second walls are formed with a communicating portion which circulates a raw material gas to be introduced, toward a central portion of a reaction chamber while the raw material gas goes through the small spaces sequentially and is turned up and down, heaters are installed in the small spaces, one of small spaces on both sides of the second walls is used as a small space for a upward flow passage, and the other is used as a small space for a downward flow passage, and the small spaces communicate with each other via the communication portion of the second walls.

The present invention is a solid oxide fuel cell configuration which equalizes gas volume distributed into each power generation cell to stabilize fuel cell output and improve the output efficiency. In the present invention, a flat plate laminating type solid oxide fuel cell has a reactant gas supply manifold extending through a fuel cell stack in the laminating direction, for supplying reactant gas to each of power generation cells through gas passages of separators which are communicated with the manifold. The manifold and the passages of the separators are in communication with each other through a gas-flow throttle mechanisms.

Solid oxide fuel cell

A fuel cell has a high heat recovery efficiency for effectively collecting heat discharged from a fuel cell stack. The fuel cell includes a power generating cell and a separator which are alternately laminated to constitute a fuel cell stack. The fuel cell stacks are disposed in the central area of a power generating reaction chamber to form two columns-by-two rows array in a plan view. A cross-shaped fuel reformer is arranged between the opposing sides of the fuel cell stacks.

Fuel cell with cross-shaped reformer

Gas discharge ports are provided in almost the entire area of a layer surface of a separator, and a gas for reaction is discharged like a shower from the separator toward a power generation cell. The separator is constructed by layering plate-shaped members containing iron-base alloy, nickel-base alloy, or chrome-base alloy as the base material. Silver, silver alloy, copper, or copper alloy is plated on both sides or one side of the base material of the plate-shaped member. The construction above can increase durability of a separator and enables the separator and a solid oxide fuel cell to be stably used for a long period.

Growing community of inventors

Naka-gun, Japan

Naoya Murakami