Sumitomo Chemical Company, Limited

Naoto Yoshimura

Satoshi Itoguchi

Masayuki Arakawa

The invention relates to a production method of a heterophasic propylene polymerization material containing a propylene homopolymer (I-1) or a propylene copolymer (I-2), and a propylene copolymer (II), wherein the content of the propylene copolymer component (II) is 30% by weight or more, the production method containing the following steps (1) and (2): Step (1): a step of polymerizing a monomer containing propylene in the presence of a catalyst for propylene polymerization to produce a propylene homopolymer (I-1) or a propylene copolymer (I-2), the step satisfying the formula (A):1100&#x2264;&#x3b1;(1.34&#x3b2;)&#x2003;&#x2003;(A)wherein, &#x3b1; represents the median diameter (unit: &#x3bc;m) of the catalyst for propylene polymerization and &#x3b2; represents the production amount (unit: g/g) of the propylene homopolymer (I-1) or the propylene copolymer (I-2) per 1 g of the catalyst for propylene polymerization in the step (1); Step (2): a step of copolymerizing at least one olefin selected from the group consisting of ethylene and &#x3b1;-olefins having the number of carbon atoms of 4 or more and 12 or less, and propylene in the presence of the propylene homopolymer (I-1) or the propylene copolymer (I-2) obtained in the step (1), using 1 or more gas phase polymerization reactors, to produce a propylene copolymer (II), wherein the concentration of alkanes having the number of carbon atoms of 6 or more in the final gas phase polymerization reactor of the 1 or more gas phase polymerization reactors is 0.01% by volume or more and 0.6% by volume or less.

Method for producing heterophasic propylene polymer material

A method for producing a polyolefin is provided. The method includes steps of polymerizing an olefin in a first gas-phase polymerization tank to obtain polyolefin-containing particles, transferring the polyolefin-containing particles to a second gas-phase polymerization tank through a transfer pipe, and polymerizing an olefin in the presence of the transferred polyolefin-containing particles in the second gas-phase polymerization tank. A connection place between the first gas-phase polymerization tank and the transfer pipe is higher than a connection place between the second gas-phase polymerization tank and the transfer pipe. 130 kPa&#x2265;P&#x2212;P&#x2265;0 is satisfied, where Prepresents the pressure in the first gas-phase polymerization tank and Prepresents the pressure in the second gas-phase polymerization tank.

Method for producing polyolefin

Provided are a system for producing a polyolefin, a method of producing a polyolefin, and a method of producing a heterophasic propylene polymer material, each of which allows (i) a gel, to be contained in a molded product that is made of an obtained polyolefin, to be reduced and (ii) a polyolefin to be continuously produced stably. A polyolefin producing system () includes: a cylindrical member which extends in a vertical direction; diameter decreasing members each of which is provided to the cylindrical member, each of the diameter decreasing members having (i) an inner diameter that decreases as the each of the diameter decreasing members extends downward and (ii) a gas inlet opening at a lower end of the each of the diameter decreasing members; spouted bed type olefin polymerization reaction regions () each of which is surrounded by (a) an inner surface of a corresponding one of the diameter decreasing members and (b) part of an inner surface of the cylindrical member which part extends upward from the corresponding one of the diameter decreasing members, each of the spouted bed type olefin polymerization reaction regions () being a region in which a spouted bed is formed, the number of the spouted bed type olefin polymerization reaction regions () being 3 or more; and at least one fluidized bed type olefin polymerization reaction region which is provided at a stage subsequent to the spouted bed type olefin polymerization reaction regions ().

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Ichihara, Japan

Naoto Yoshimura