Mitsubishi Rayon Company, Limited

Mazda Motor Corporation

Mistubishi Rayon Co., Ltd.

Mrc Techno Co., Ltd.

Naoki Yamamoto

Akira Yanagase

Akira Nakata

Hiroshi Mori

Hiroki Hatakeyama

Isao Sasaki

Atsunori Koshirai

Takuya Ueno

Kazuo Kishida

Misayo Suehiro

Hideyuki Shigemitsu

Suehiro Tayama

Masafumi Hongo

Masaharu Fujimoto

Hiroyuki Watanabe

Kiyotaka Azegami

Yasumasa Sato

Kozi Nishida

Nobuhiro Mukai

Hitoshi Ige

Hitoshi Iwasaki

Seiji Tone

Junko Atarashi

Noriyuki Taziri

Tadashi Iwasaki

Masakazu Itoh

Makoto Uchida

Masao Kobayashi

Masahiro Sugimori

Yutaka Toyooka

Takahiro Yamamoto

Hideyuki Fujii

Masakazu Ito

Yoshiaki Nakaya

Haruko Takeda

Toshiaki Wakabayashi

Toshimi Yanai

Toshihito Narita

Hisaya Yokohama

A rear light is a light disposed in a rear portion of a vehicle, and includes: a light source; a light-transmitting plate that guides incident light from the light source; and a dot portion that is disposed on the light-transmitting plate and reflects incident light to the outside of the vehicle with different reflection intensities depending on positions on the light-transmitting plate.

Vehicle light

Graft copolymer particles obtained by graft-polymerizing one or more kinds of vinyl monomer onto a compound rubber comprising a polyorganosiloxane component and an alkyl (meth)acrylate rubber component, which graft copolymer particle has a number average particle size of 0.01 to 0.07 .mu.m, the volume of particles larger than 0.10 .mu.m being 20% or less of the whole particle volume, a method for producing the above graft copolymer particle, wherein one or more kinds of vinyl monomer are graft-polymerized onto a compound rubber obtained by polymerizing an alkyl (meth)acrylate rubber component comprising alkyl (meth)acrylate and a polyfunctional alkyl (meth)acrylate with a polyorganosiloxane having a number average particle size of 0.003 to 0.06 .mu.m, the volume of particles larger than 0.10 .mu.m being 20% or less of the whole particle volume, and thermoplastic resin compositions comprising the above graft copolymer and various thermoplastic resins. The present invention provides graft copolymer particles and their thermoplastic resin composition which can give molded products having both excellent pigment colorability and extremely high impact resistance.

Graft copolymer particles their production and compositions comprising

Composite composition having high transparency and process for producing

A polyorganosiloxane graft copolymer obtained by graft-polymerizing one or more kinds of monomer which have an ethylenically unsaturated bond and contain at least an epoxy group-containing vinyl monomer onto a compound rubber in which a polyorganosiloxane rubber and a polyalkyl (meth)acrylate rubber have been inseparably united with each other, and in which the component derived from the epoxy group-containing vinyl monomer occupies a proportion of 1 to 30 wt. % of the whole graft copolymer. This polyorganosiloxane graft copolymer is excellent in impact resistance, low-temperature characteristics and weather resistance, and also excellent in the bond strength to paint film applied thereto. This graft copolymer is also useful as adhesives, and particularly it exhibits excellent adhesion performance in depositing aromatic polymers such as polyesters (e.g. polyethylene terephthalate), polyphenylene oxides, polyphenylene sulfides, etc.

Polyorganosiloxane graft copolymers

Disclosed is a composite composition obtained by polymerizing a radical-polymerizable vinyl compound (A) in the presence of a silica polycondensate (B) formed by hydrolysis and polycondensation of at least one alkoxysilane compound in a dispersion system of colloidal silica. This composite composition has high transparency, rigidity, toughness and thermal resistance and is hence useful in applications where inorganic glass has heretofore been used.

A method for preparing a graft copolymer is here disclosed which is characterized by comprising the step of carrying out a living polymerization of at least one (meth)acrylic ester by the use of a polymeric compound as an initiator having one or more units represented by the following formula (I) in a molecular chain substantially in the absence of water in the presence of a Lewis acid or a donor compound of an anion selected from the group consisting of HF.sub.2.sup.-, (CH.sub.3).sub.3 SiF.sub.2.sup.- and F.sup.- : ##STR1## wherein R is hydrogen or an alkyl group having 1 to 6 carbon atoms, and R' is an alkyl group having 1 to 12 carbon atoms.

Method for preparing graft copolymer

A polyester resin composition obtained by melt-mixing a mixture comprising resin components comprising as main resins

Polyester resin compositions

Disclosed is a composite composition obtained by polymerizing a radical-polymerizable vinyl compound (a) in the presence of a silicic acid oligomer (b) and, if desired, colloidal silica (c). This composite composition has high transparency, thermal resistance, rigidity and toughness and is hence useful in applications where inorganic glass has heretofore been used.

Thermoplastic resin compositions

A polyarylene sulfide resin composition obtained by melt-mixing a mixture comprising resin components comprising as main resins

Polyarylene sulfide resin compositions

A polyarylene sulfide resin composition excellent in compatibility between a polyarylene sulfide resin and a polyorganosiloxane graft copolymer is obtained by melt-mixing a composition consisting essentially of 60 to 99 parts by weight of a polyarylene sulfide resin, to 40 parts by weight of a polyorganosiloxane graft copolymer which was obtained by graft-polymerizing one or more kinds of a vinyl monomer onto particles of a compound rubber consisting of a polyorganosiloxane rubber component and a polyalkyl (meth)acrylate rubber component inseparably united with each other, and 0.01 to 10 parts by weight of and organic silane compound having an epoxy group per 100 parts of the mixture.

Thermoplastic resin composition

A polyarylene sulfide resin composition comprising 60-99 parts by weight of a polyarylenesulfide resin (A), 40-1 parts by weight of a polyorganosiloxane graft copolymer (B) prepared by grafting a vinyl monomer on a polyorganosiloxane rubber having a degree of swelling in a range of 3-50 measured using toluene as a solvent and an average particle size in a range of 0.15 .mu.m-0.5 .mu.m and being copolymerized with a graft-linking agent, where the total amount of the (A) component and the (B) component is 100 parts by weight, and 0-150 parts by weight of a reinforcing filler (C). A polyarylene sulfide resin composition according to the present invention is excellent in impact resistance, heat resistance, mechanical strength and moldability and useful for an engineering plastic.

Growing community of inventors

Otake, Japan

Naoki Yamamoto