Kuraray Co., Ltd.

Naoki Kawakami

Tatsuya Oshita

Yukiatsu Komiya

Makoto Suzuki

Shigeki Takada

Goki Uehara

Syuichi Kanao

Satoshi Yamakoshi

Kanenori Ito

Yoshiki Takeda

Nobuhisa Senda

A multilayer structure includes a layer of a resin composition containing an ethylene-vinyl alcohol copolymer and a thermoplastic elastomer, wherein a mass ratio of the ethylene-vinyl alcohol copolymer to the thermoplastic elastomer is from 65/35 to 95/5 and the layer of the resin composition has one surface directly adjacent to a layer of polyolefin with no polar functional group. A multilayer structure is thus provided that is excellent in gas barrier properties, transparency, and flexibility and also has good delamination properties between the layer of the resin composition and the layer of the polyolefin with no polar functional group.

Multilayer structure and use of same

A pelletized resin composition according to the present invention contains an ethylene-vinyl alcohol resin (A), a polyamide (B), and a lower fatty acid magnesium salt (C) each in a specific amount, wherein the polyamide resin (B) is dispersed in the ethylene-vinyl alcohol resin (A) with an average dispersed particle diameter of 1 &#x3bc;m or less as determined using an electron microscope, and the lower fatty acid magnesium salt (C) is dispersed in both the ethylene-vinyl alcohol resin (A) and the polyamide resin (B). Accordingly, a pelletized resin composition that is superior in hue can be obtained. In addition, a film that is superior in thermal stability in the film formation, the appearance immediately after the film formation, and the appearance after the heating treatment is obtained.

Ethylene-vinyl alcohol resin composition pellet

A vinyl alcohol polymer composition (II) is produced by a process of providing a reaction liquid comprising a solution containing a vinyl carboxylate polymer and, a first metal alkoxide (I) having at least one functional group and/or an oligomer (I) having at least one functional group obtained from said metal alkoxide (I); a step of simultaneously effecting (a) saponification of said vinyl carboxylate polymer and (b) reaction in which at least part of the functional groups of said metal alkoxide (I) and/or said oligomer (I) participates, thereby obtaining a vinyl alcohol polymer composition (I); and a step of preparing a solution (A) containing said vinyl alcohol polymer composition (I), followed by adding to the solution (A) a second metal alkoxide (II) and/or an oligomer (II) obtained from the metal alkoxide (II) or another solution (B) containing the metal alkoxide (II) and/or the oligomer (II) derived from the metal alkoxide (II), to prepare an intermediate product solution (C), and then removing the solvent from said solution (C). The vinyl alcohol polymer composition obtained by the above process has excellent gas-barrier properties, in particular excellent gas-barrier properties under high-humidity conditions. The vinyl alcohol polymer composition is suitably usable as a coating agent having good storage stability and little uneven applicability, and as gas-barrier material, in particular laminate having excellent gas-barrier properties under high-humidity conditions.

Process for producing vinyl alcohol polymer compositions

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Kurashiki, Japan

Naoki Kawakami