Nippon Oil Company

Naoki Kataoka

Kazuo Matsuura

Yoshio Tajima

Takashi Seki

Yosuke Numao

Nobuyuki Kuroda

Yutaka Shikatani

Yoshiyuki Shimo

Hiroshi Kobayashi

Akira Sano

Yoshinori Nishikitani

Etsuo Kawamata

Hobuyuki Kuroda

According to the present invention, there are provided a catalyst and a process for the preparation of polyolefins having a relatively wide molecular weight distribution, good particle properties, a narrow composition distribution in copolymerization and a high molecular weight and being less sticky. The catalyst is prepared by contacting the following constituents (1) to (4) with one another:

Olefin polymerization catalyst and process for preparing polyolefins

A catalyst component is disclosed for use in the homo- or copolymerization of olefinic hydrocarbons. The catalyst component is comprised of a first compound of the formula M.sup.1 (OR.sup.1).sub.p R.sup.2.sub.q X.sup.1.sub.4-p-q, M.sup.1 being titanium a second compound of the formula M.sup.2 (OR.sup.3).sub.m R.sup.4.sub.n X.sup.2.sub.z-m-n, with M.sup.2 being a metal of Groups Ia-IIIa or IIb of the Periodic Table, and a third compound which is an organocyclic compound having two or more conjugated double bonds. A process is also disclosed for the production of hydrocarbon polymers in which the above catalyst component is combined with a modified organoaluminum compound to form a catalyst composition capable of providing controlled molecular weight, wide distribution thereof and other desirable qualities in the polymer product.

Catalyst components for polymerization of olefins

A process for the polymerization of olefinic hydrocarbons is carried out in the presence of a catalyst comprising a catalyst component derived from reacting a compound of the formula Me.sup.1 R.sup.1.sub.n X.sup.1.sub.4-n, a compound of the formula Me.sup.2 R.sup.2.sub.m X.sup.2.sub.z-m, an organocyclic compound having two or more conjugated double bonds and a carrier of inorganic or polymeric material, and a modified organoaluminum compound having Al--O--Al bonds, the resulting polyolefins having a relatively wide molecular weight distribution, a relatively narrow composition distribution and increased bulk density.

A catalyst component is disclosed for use in the homo- or copolymerization of olefinic hydrocarbons. The catalyst component is comprised of a first compound of the formula Me.sup.1 (OR.sup.1).sub.p R.sup.2.sub.q X.sup.1.sub.4-p-q and a second compound which is an organocyclic compound having two or more conjugated double bonds. A process is also disclosed for the production of hydrocarbon polymers in which the above catalyst component is combined with a modified organoaluminum compound to form a catalyst composition capable of providing high molecular weight, wide distribution thereof and other desirable qualities in the polymer product.

Process for the polymerization of olefinic hydrocarbons

A catalyst component is disclosed for use in the homo- or copolymerization of olefinic hydrocarbons. The catalyst component is comprised of a first compound of the formula Me.sup.1 (OR.sup.1).sub.p R.sup.2.sub.q X.sup.1.sub.4-p-q and a second compound which is an organocyclic compound having two or more conjugated double bonds. A process is also disclosed for the production of hydrocarbon polymers in which the above catalyst component is combined with a modified or organoaluminum compound to form a catalyst composition capable of providing high molecular weight, wide distribution thereof and other desirable qualities in the polymer product.

Method for polymerization of olefins

A catalyst component is disclosed for use in the homo-or copolymerization of olefinic hydrocarbons. The catalyst component is comprised of a first compound of the formula Me.sup.1 (OR.sup.1).sub.p R.sup.2.sub.q X.sup.1.sub.4-p-q, a second compound of the formula Me.sup.2 (OR.sup.3).sub.m R.sup.4.sub.n X.sup.2.sub.z-m-n and a third compound which is an organocyclic compound having two or more conjugated double bonds. A process is also disclosed for the production of hydrocarbon polymers in which the above catalyst component is combined with a modified organoaluminum compound to form a catalyst composition capable of providing controlled molecular weight, wide distribution thereof and other desirable qualities in the polymer product.

Process for polymerization of olefinic hydrocarbon

A catalyst component is disclosed for use in the homo- or copolymerization of olefinic hydrocarbons. The catalyst component is comprised of a first compound of the formula Me.sup.1 (OR.sup.1).sub.p R.sup.2.sub.q X.sup.1.sub.4-p-q, a second compound of the formula Me.sup.2 (OR.sup.3).sub.m R.sup.4.sub.n X.sup.2.sub.z-m-n and a third compound which is an organocyclic compound having two or more conjugated double bonds. A process is also disclosed for the production of hydrocarbon polymers in which the above catalyst component is combined with a modified organoaluminum compound to form a catalyst composition capable of providing controlled molecular weight, wide distribution thereof and other desirable qualities in the polymer product.

A catalyst component is disclosed for use in the homo-or copolymerization of olefinic hydrocarbons. The catalyst component is comprised of a first compound of the formula Me.sup.1 (OR.sup.1).sub.p R.sup.2.sub.q X.sup.1.sub.4-p-q and a second compound which is an organocyclic compound having two or more conjugated double bonds. A process is also disclosed for the production of hydrocarbon polymers in which the above catalyst component is combined with a modified organoaluminum compound to form a catalyst composition capable of providing high molecular weight, wide distribution thereof and other desirable qualities in the polymer product.

An organic thin film electroluminescent device is composed of an electron transport layer, a hole transport layer and a transparent electrode. The electron transport layer is constituted of an electron conducting polymer represented by the formula (I) ##STR1## wherein R.sup.1 is a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, R.sup.2 is a hydrogen atom, an alkyl or alkoxy group having 1 to 4 carbon atoms, an aryl group, an aryloxy group, a thioether group, an amino group, a halogen atom, an aldehyde group, a cyano group, a nitro group or a hydroxyl group, x is an integer of 1 to 6, on the condition that, if x is an integer of 2 to 6, R.sup.2 may be the same or different, and n is an integer not less than 2.

Organic thin film electroluminescent device

A hole transporting material is constituted by a compound represented by the following general formula (1): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5, which may be the same or different, are each independently hydrogen or a hydrocarbon residue having 1 to 20 carbon atoms; Ar.sup.1 and Ar.sup.2 are each independently a divalent hydrocarbon residue; l is an integer of 0 or more; m is an integer of 1 or more; and n is an integer of 2 or more.

Hole transporting material

An electroactive polymer is obtained by doping a copolymer represented by the following general formula (I): ##STR1## wherein R.sup.1 is hydrogen or a hydrocarbon residue having 1 to 20 carbon atoms; R.sup.2 is hydrogen, a hydrocarbon residue having 1 to 20 carbon atoms, furyl, pyridyl, nitrophenyl, chlorophenyl, or methoxyphenyl; l is an integer not smaller than 2; m is an integer not smaller than 1; and n is an integer not smaller than 2.

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Yokohama, Japan

Naoki Kataoka