Toyoda Gosei Co., Ltd.

Tokyo Institute of Technology

The University of Tokyo

Naoki Iwase

Hideyuki Imai

Akishige Seo

Toshikazu Takata

Yasuhito Koyama

Naoyuki Akahori

Hidekazu Kurimoto

Yusuke Katono

Kohzo Ito

Makoto Ishida

Toyokazu Tsutsuba

Takanori Nakai

Kaori Miura

Rina Maeda

Hideaki Kondo

Morio Yonekawa

Shota Ando

The present invention provides a crosslinked polymer composition exhibiting significantly improved elongation at break over conventional ones, and a polymer composition and a polyrotaxane, each of which can be used as a raw material of the crosslinked polymer composition. The polyrotaxane contains a linear molecule, a cyclic molecule, and a blocking group, wherein the cyclic molecule has a hydrosilyl group. The polymer composition contains the polyrotaxane and a polymer, wherein the polymer has a double bond on at least either a main chain or a side chain. The crosslinked polymer composition is produced by crosslinking of the polymer composition through chemical reaction between the hydrosilyl group of the cyclic molecule and the double bond of the polymer.

Polyrotaxane, polymer composition, crosslinked polymer composition, and production method therefor

A crosslinked rubber composition contains ethylene-propylene-diene copolymer rubber crosslinked with a rotaxane compound having a cyclic molecule and an axial molecule penetrating through the cyclic molecule. In the crosslinked rubber composition, the ethylene-propylene-diene copolymer rubber contains vinylnorbornene, dicyclopentadiene, or tetrahydroindene as a diene component, and the rotaxane compound has a nitrile oxide group on the cyclic molecule and one end of the axial molecule, and the cyclic molecule is crown ether.

Crosslinked rubber composition and production method therefor

A rubber includes 5 parts by mass to 45 parts by mass of an uncross-linked EPM relative to 100 parts by mass of a cross-linked rubber polymer (other than EPM), and an oil in an amount equal to or more than the amount of the EPM. The rubber is foamed and has a specific gravity of more than 0.3 and 0.8 or less. A weather stripand a hoseare formed of the rubber.

Rubber, seal component, and hose

To provide a polymer alloy formed of a non-polar rubber and a polar rubber, and a rubber product, which are improved in ozone resistance (weather resistance) while having oil resistance and can achieve high mechanical strength (in particular, tensile strength), and a production method thereof. A rubber product in which an organic peroxide or other cross-linking agent is used to cross-link a polymer alloy comprising: a modified rubber in which EPDM, NR, or another non-polar rubber having a non-conjugated double bond is modified with 2-methoxy-1-naphthonitrile oxide, 2,6-dimethoxybenzonitrile oxide, or another nitrile oxide of an aromatic nitrile oxide derivative; and nitrile rubber, acrylic rubber, or another polar rubber.

Polymer alloy and rubber product, and production method thereof

The present invention provides a crosslinker used for crosslinking a polymer material having, in the molecule thereof, a multiple bond reactable with a nitrile oxide, the crosslinker including a bifunctional nitrile oxide having an aromatic nitrile oxide derivative structure in which one hydrogen atom of an aromatic ring is substituted with a nitrile oxide group and all hydrogen atoms at an ortho-position of the nitrile oxide group are substituted with a substituent other than a nitrile oxide group, wherein two such aromatic nitrile oxide derivative structures are bonded to either two oxy groups of a di-oxy structure having the two oxy groups or two carbonyl groups of a di-carbonyl structure having the two carbonyl groups.

Crosslinker, crosslinked polymer material, and production method of the crosslinked polymer material

The present invention provides a production method of a crosslinkable polymer material which includes adding 2 -(glycidyloxy)-1-naphthonitrile oxide or 2-[5 -(ethoxycarbonyl)pentyloxy]-1-naphthonitrile oxide by an addition reaction to a polymer material having a multiple bond to which a nitrile oxide is added by an addition reaction so as to introduce a glycidyl group or an ethoxycarbonyl group into the polymer material.

Crosslinkable polymer material, crosslinked polymer material, and production method thereof

The present invention provides a production method of a modified polymer material produced by modifying a polymer material having in a molecule thereof a multiple bond that reacts with a nitrile oxide, includes reacting the polymer material with an aromatic nitrile oxide derivative having a substituent at an ortho-position of a nitrile oxide group of an aromatic nitrile oxide in which the nitrile oxide group is bonded to an aromatic ring.

Growing community of inventors

Kiyosu, Japan

Naoki Iwase