Fuji Photo Film Company, Limited

Naohiko Sugimoto

Tetsuro Kojima

Shingo Ishimaru

Tadashi Ikeda

Masakazu Yoneyama

Yasuo Mukunoki

Yukio Maekawa

Ikutaro Horie

Nobuo Yamamoto

Yasuhiro Nakayama

Masashi Ogawa

Katsumi Ryoke

Shigeki Yokoyama

Hidefumi Sera

Kunio Ishigaki

Shinzo Kishimoto

Yasunori Ichikawa

Takashi Naoi

Kiyotaka Hori

Takayuki Inayama

Kameji Nagao

Daijiro Nishio

Mitsuru Sugihara

Nobuhisa Sekiguchi

Akira Fujita

Elichi Hasegawa

An improvement of a medium for electrophoresis which comprises a support of a plastic material and an aqueous polyacrylamide gel, wherein a resin layer comprises a resin having an oxygen permeability coefficient lower than that of the plastic material of the support is arranged betwen the support and the polyacrylamide gel. The resin preferably shows an oxygen permeability of not more than 15 cc/m.sup.2 .multidot.atm.multidot.day in the form of a resinous layer of 20 .mu.m thick, and exemplified by a vinylidene chloride-vinyl chloride copolymer, polyvinyl alcohol, polyacrylonitrile, polyvinylidene chloride, a vinyl alcohol-ethylene copolymer, a vinylidene chloride-acrylonitrile copolymer, and an acrylonitrile-methyl acrylate-butadiene copolymer.

Medium for electrophoresis

An electrophoresis device comprises a gel membrane disposed within a space formed by a pair of sheets and a pair of spacers. A shark's teeth comb is disposed at an end of the gel membrane such that a plurality of triangular sample-pouring apertures are formed by its saw-like protrusions and the end of the gel membrane. The thickness of the shark's teeth comb d and the thickness of the gel membrane G satisfy the following relation:

Electrophoresis device with shark-toothed comb having a thickness

An element for electrophoresis suitably employable for analysis of biopolymers such as proteins, as well as for determination of base sequence of DNA, RNA, their fragments, and their derivatives, which comprises a plastic film, a layer for electrophoresis comprising an aqueous polyacrylamide gel, an adhesive layer containing gelatin and optionally a film-forming polymer and/or fine particles, and a plastic film.

Element for electrophoresis

In a medium for electrophoresis suitably employable for determination of base sequence of DNA, RNA, their fragments, and their derivatives, which comprises an aqueous polyacrylamide gel formed by crosslinking polymerization of an acrylamide compound and a crosslinking agent in the presence of water and at least one compound having a carbamoyl group, the improvement wherein glycerol is contained in the medium in a small amount ranging from 0.1 to 1.0 wt/v %.

A silver halide photographic material is described, comprising a support having thereon at least one layer containing a cross-linked polymer represented by formula (I) ##STR1## wherein R.sub.1 and R.sub.2 each represents a hydrogen atom or an unsubstituted or substituted alkyl group; R.sub.3 represents a hydrogen atom, an unsubstituted or substituted alkyl group, cycloalkyl group, aryl group, or acyl group; R.sub.4 represents a hydrogen atom or an unsubstituted or substituted alkyl group; or R.sub.3 and R.sub.4 together form a ring; L represents a divalent, trivalent or tetravalent connecting group; l represents 0 or 1; m represents an integer of 1 to 3; n represents an integer of 1 to 10; A represents a polymeric unit formed by copolymerizing an ethylenically unsaturated and copolymerizable monomer; B represents a polymeric unit formed by copolymerizing a copolymerizable cross-linking monomer containing at least two copolymerizable and ethylenically unsaturated groups; M represents a cation; w represetns 10 to 95 mol %; x represents 3 to 88 mol %; y represents 0 to 50 mol %, and z represents 2 to 30 mol %.

Silver halide photographic element containing crosslinked copolymers

In silver halide photographic light-sensitive materials comprising at least one silver halide photographic emulsion layer on one side of a base and an emulsion protective layer thereon, and a hydrophilic colloid backing layer on the other side of the base, the improvement wherein said backing layer contains a polymer matting agent having an average particle size of 3.0 .mu.m or more and said emulsion protective layer contains at least one of a polyoxyethylene type surface active agent, and a silicone type slipping agent.

Silver halide photographic light-sensitive materials

A silver halide photographic light-sensitive material is disclosed. The material is comprised of a support base having positioned thereon a light-sensitive silver halide emulsion layer, a light-insensitive layer and ultraviolet ray absorbing polymer latex of a polymer having a repeating unit derived from a monomer represented by the general formula (I): ##STR1## within general formula (I) the substituents are defined within the specification. The Q represents an ultraviolet ray absorbing group represented by a general formula (II) or (III): ##STR2## The substituents within the general formulae given above are defined in the specification. By including the particular ultraviolet ray absorbing polymer latex of the invention the resulting photographic material has improved antistatic properties and the photographic characteristics of the material are not deteriorated by the presence of the latex.

Silver halide photographic light-sensitive material containing

A silver halide photographic light-sensitive material is disclosed which is comprised of a support base having thereon a light-sensitive silver halide emulsion layer and a light-insensitive layer. The material also includes an ultraviolet ray absorbing polymer latex and a fine grained silver halide having a diameter of 0.2 microns or less. The ultraviolet ray absorbing polymer latex is a polymer or copolymer having a repeating unit derived from a monomer represented by the general formula (I): ##STR1## the substituents are defined within the specification. By utilizing the polymer latex of general formula (I) the occurance of static marks is almost completely prevented without causing undesirable effects on other film properties.

Silver halide photographic light-sensitive material

A silver halide photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer wherein the photographic light-sensitive material contains a compound represented by the following general formula (I): ##STR1## wherein Rf represents a saturated or unsaturated hydrocarbon group having from 3 to 20 carbon atoms wherein all or a part of the hydrogen atoms are substituted with fluorine atoms; A and B each represents a divalent linking group; R.sub.1 represents a hydrogen atom or an alkyl group; R.sub.2, R.sub.3 and R.sub.4 each represents an alkyl group and at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represents an alkyl group substituted with a monovalent group, and X represents an anion. The photographic light-sensitive material containing the compound represented by the general formula (I) provides improved antistatic properties without adversely affecting the photographic properties and can be prepared without problems during coating such as formation of 'comets' and 'repelling'.

Silver halide photographic light-sensitive materials containing

A silver halide photographic light-sensitive material having improved antistatic properties is disclosed. The material is comprised of a support having thereon a light-senstive silver halide emulsion layer and a light-insensitive layer. The material includes (A) a flourine containing cationic surface active agent and (B) an ultraviolet ray absorbing polymer latex which comprises a polymer or a copolymer having a repeating unit derived from a monomer represented by the following general formula (I): ##STR1## within the formula (I) the Q is an ultraviolet ray absorbing group represented by the following general formula (II) or (III): ##STR2## the substituents within the formulae shown are defined within the specification. The ultraviolet ray absorbing polymer latex is present in the material in an amount in the range of 10 to 2,000 mg/m.sup.2 of the material. The material which contains a combination of the ultraviolet ray absorbing polymer latex and the fluorine containing cationic surface active agent has excellent antistatic properties and does not result in the occurrence of pressure marks.

A silver halide photographic light-sensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion and at least one light-insensitive layer is disclosed. One or more of the layers of the material contains an ultraviolet ray absorbing polymer latex which comprises a homopolymer or copolymer having a repeating unit derived from a monomer represented by the general formula (II) in which one or more ultraviolet ray absorbing compounds represented by the general formula (I) is loaded: ##STR1## the substituents within the general formula are defined within the specification. The material has excellent absorption characteristics in the 300 to 400 nm range and does not cause static marks caused by ultraviolet rays or undergo deterioration of color reproduction. In addition, the material has good film strength and reduced layer thickness and provides a color image having improved sharpness which is free from fading or discoloration due to light.

Silver halide photographic light-sensitive material containing a UV

A silver halide photographic light-sensitive material is disclosed. The material is comprised of a support having thereon a light-sensitive silver halide layer and a light-insensitive layer. The material may also contain other layers and one or more layers contains an ultraviolet ray absorbing polymer latex. The polymer latex is comprised of a homopolymer or a copolymer having a repeating unit derived from a monomer represented by the following general formula (I): ##STR1## within the general formula (I) the Q represents an ultraviolet ray absorbing group represented by the general formula (II): ##STR2## the substituents within the general formulae (I) and (II) are defined in a specification. The photographic light-sensitive material has excellent absorbing characteristic in the 300 to 400 nm range and does not cause static marks caused by ultraviolet layer. Furthermore, the material does not undergo discoloration. In addition, the photographic material has good film strength and a reduced layer thickness and provides a color image having an improved sharpness and which is free from fading and discoloration caused by light.

Silver halide photographic elements containing polymers which filter UV

A silver halide photographic light-sensitive material is disclosed. The material is comprised of one or more light-sensitive silver emulsion layers and one or more light-insensitive layers. The silver halide layers or light-insensitive layers contain an ultraviolet ray absorbing polymer latex. The polymer latex is comprised of a homopolymer or copolymer having a repeating unit derived from monomers represented by the following general formula (I): ##STR1## wherein the substituents within a general formula (I) are defined within the specification. The polymer latex (I) contains a substituents Q which represents an ultraviolet ray absorbing group represented by the general formula (II): ##STR2## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 each represents a hydrogen atom, a halogen atom, an alkyl group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an aryloxy group having 6 to 20 carbon atoms, an alkylthio group having 1 to 20 carbon atoms, an arylthio group having 6 to 20 carbon atoms, an amino group, an alkylamino group having 1 to 20 carbon atoms, an arylamino group having 6 to 20 carbon atoms, a hydroxyl group, a cyano group, a nitro group, an acylamino group, a carbamoyl group, a sulfonyl group, a sulfamoyl group, a sulfonamide group, an acyloxy group or an oxycarbonyl group, and R.sub.1 and R.sub.2, R.sub.2 and R.sub.3, R.sub.3 and R.sub.4 or R.sub.4 and R.sub.5 may form a 5 to 6 member ring by ring closure; R.sub.6 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; R.sub.7 represents a cyano group, --COOR.sub.9, --CONHR.sub.9, --COR.sub.9 or --SO.sub.2 R.sub.9 ; and R.sub.8 represents a cyano group, --COOR.sub.10, --CONHR.sub.10, --COR.sub.10 or --SO.sub.2 R.sub.10 ; wherein R.sub.9 and R.sub.10 each represents an alkyl group having 1 to 20 carbon atoms or an aryl group having 6 to 20 carbon atoms; wherein one of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 bonds to the vinyl group through the linking group. The photographic material which includes the polymer latex of the invention has excellent absorption characteristics in the 300 to 400 nm range and does not cause static marks caused by ultraviolet rays. Furthermore, the material does not undergo deterioration of color reproduction and fading or discoloration of color images caused by light.

Silver halide photographic light-sensitive element containing a u.v.

A silver halide photographic sensitive material is described comprising a compound represented by formula (I) ##STR1## wherein Rf represents a saturated or unsaturated hydrocarbon group having from 3 to 20 carbon atoms wherein all or a part of the hydrogen atoms are substituted by fluorine atoms, each of L.sub.1 and L.sub.2 represents a divalent linking group, each of R.sub.1, R.sub.2, and R.sub.3 represents a hydrogen atom, a methyl group, or an ethyl group, each of R.sub.4, R.sub.5, and R.sub.6 represents an alkyl group having from 1 to 6 carbon atoms, X represents an anion, and each of a and b represents 0, 1, or 2.

Silver halide photographic sensitive element containing a fluorine

A silver halide photographic light-sensitive material is described containing

Growing community of inventors

Kanagawa, Japan

Naohiko Sugimoto