Ciba Specialty Chemicals Corporation

Basf Se Corporation

Nancy N Cliff

Ramanathan Ravichandran

James Peter Galbo

Robert E Detlefsen

Peter Solera

Gerald A Capocci

Michael P DiFazio

Christophe Bulliard

David A Yale

Mouhcine Kanouni

Jennifer Jankauskas

Mervin Gale Wood

Joseph Suhadolnik

Walter L Renz

David Bramer

Deanna Rodovsky

Simon Lord

Andrea Roberts

Ece Unur

Eugene Sitzman

Blending an electrically active, anodically coloring, electrochromic polymer with a non-electrochromic, non-electrically conductive binder polymer greatly enhances the performance of the anodically coloring, electrochromic polymer in an electrochromic device over time. In addition to improved physical characteristics of the blend, e.g., film build, durability etc, the coloristic properties, including color space and color strength, of the device comprising the blend are more durable than when using the neat polymer, and in certain instances, the color space and color intensity provided by the blend is superior to that available from the neat polymer.

Electrochromic devices and polymer compositions

Electrically active, cathodically coloring electrochromic polymers are blended with a non-electrochromic, non-electrically conductive binder polymer to provide an electrochomic composition with greatly enhanced performance in an electrochromic device over time. It is also found that blending an electrochromic polymer with a non-coloring electroactive material allows for greater design in preparing electrochromic devices as it enables the use of a higher amount of typically low coloring anodic materials due to increased need for charge balancing.

Devices containing compositions comprising cathodically coloring electrochromic polymers and binder polymers

Disclosed are compositions, which are stabilized against degradation and yellowing during exposure to ultraviolet light by the presence of certain nitroxyl, hydroxyl amine and hydroxyl amine salt additives, a method of stabilizing the compositions by the addition of said additives, to the use of such compositions as media in electroactive devices such as electrochromic and electrophoteric devices, and the electroactive devices comprised of these media.

Stabilized electrochromic media

Disclosed are compositions, which are stabilized against degradation and yellowing during exposure to ultraviolet light by the presence of certain hindered amine additives, a method of stabilizing the compositions by the addition of said additives, to the use of such compositions as media in electroactive devices such as electrochromic and electrophoteric devices, and the electroactive devices comprised of these media.

Photo-curable coating formulations which comprise a durable and/or red-shifted reactable hydroxyphenylbenzotriazole ultraviolet light absorber (UVA) are effectively photocured employing a combination of &#x3b1;-hydroxy ketone and bisacylphosphine oxide photoinitiators. The reactable UVA's are reacted into the coating upon curing. The combination of the photoinitiators bis(2,4,6-trimethylbenzoyl)phenylphosphine oxide and 1-hydroxycyclohexylphenylketone is especially effective for this purpose.

Photo-cured and stabilized coatings

Hindered amines substituted on the N-atom with an &mdash;O&mdash;E&mdash;OH moiety are particularly effective in stabilizing polyolefin and automotive coating compositions against the deleterious effects of oxidative, thermal and actinic radiation where the presence of the OH group on the compounds adds important properties not attainable by the use of normal &mdash;O&mdash;E moieties.

Hydroxy-substituted N-alkoxy hindered amines and compositions stabilized therewith

Hindered amines substituted on the N-atom with an -O-E-OH moiety are particularly effective in stabilizing polyolefin and automotive coating compositions against the deleterious effects of oxidative, thermal and actinic radiation where the presence of the OH group on the compounds adds important properties not attainable by the use of normal -O-E moieties.

Hindered amines substituted on the N-atom with an hydroxy-substituted alkoxy moiety are particularly effective in stabilizing organic polymer compositions against the deleterious effects of oxidative, thermal and actinic radiation where the presence of the OH group on the compounds adds important properties not otherwise attainable.

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Ringwood, NJ, United States of America

Nancy N Cliff