King Fahd University of Petroleum and Minerals

Najam Ul Qadir

Rached Ben Mansour

Syed Ahmed M Said

Shakeel Ahmed

Syed Ahmed Mohammed Said

A solar-powered two-bed adsorption chiller which can operate after sunset when the solar radiation intensity becomes zero. Rechargeable solar-powered batteries (SPBs) are connected to a flat-plate solar collector (FPSC). The photoelectric charges are directed from FPSC to a solar charge controller (SCC) which acts as a charge amplifier thus magnifying the total charge before it is finally collected inside the SPB for future use. The SPB is in turn connected to a resistance heating wire (RHW) which is immersed inside the HWST.

Solar-powered adsorption chiller operable in the absence of sunlight

The composite adsorbent for an adsorption chiller is a composite material formed from multi-walled carbon nanotubes incorporated into a metal organic framework, where the metal organic framework is MIL-101(Cr). The MIL-101 family of metal organic frameworks include terephthalate (benzene 1,4-dicarboxylate) linkers and MO-carboxylate trimers (M=Cr or Fe) with octrahedrally coordinated metal ions binding terminal water molecules. MIL-101 frameworks having a crystal structure with very large pore sizes (29 and 34 Angstroms) and surface area, and are known to have a large water uptake. However, metal organic frameworks have low thermal conductivity due to the presence of organic matter, resulting in lower heat transfer rates and greater cycle time, and are not stable in aqueous media or disintegrate slowly upon recurrent hydrothermal cycling. Composite binding with multi-wall carbon nanotubes improves heat transfer characteristics and thermal stability.

Composite adsorbent for adsorption chiller

The metal organic framework adsorbent for solar adsorption refrigeration is a nanocomposite made from a metal organic framework matrix having carbon nanotubes incorporated therein. Preferably, the metal organic framework is composed of MIL-100(Fe), and the carbon nanotubes are functionalized with carboxyl (COOH) groups. In order to prepare the metal organic framework adsorbent, carbon nanotubes functionalized with carboxyl (COOH) groups are first added to an aqueous solution of a precursor salt, such as ferric trinitrate nonahydrate (Fe(NO).9HO), to form a first mixture. The first mixture is then sonicated and a 1,3,5 benzenetricarboxylic acid ligand is added thereto to form a second mixture. The second mixture is then sonicated and heated, and the metal organic framework nanocomposite is separated therefrom, preferably as a powder.

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Dhahran, Saudi Arabia

Najam Ul Qadir