Sk Innovation Co., Ltd.

Sk Global Chemical Co., Ltd.

Sk Energy Co., Ltd.

Sabic Sk Nexlene Company Pte. Ltd.

Myungahn Ok

Jisu Jeong

Kwangjin Chung

Sujith Sudevan

Anish Cyriac

SungJae Na

Choonsik Shim

Bunyeoul Lee

Daeho Shin

Jaeki Min

Yonggyu Han

Jongsok Hahn

Jieun Yoo

BunYeoul Lee

JongEon Seong

Dongcheol Shin

HyeLim Kim

Hoseong Lee

Sungseok Chae

Sujith S

Minho Jeon

Seungbum Kwon

MoonJung Choi

Seunggweon Hong

JaeYoung Park

SangHwan Lee

Hyeongtaek Ham

Bun Yeoul Lee

Dong-Won Kim

Sun Woong Choi

Seung Gweon Hong

Jaeho Lee

Ho-Seong Lee

Jae Young Park

Dong-cheol Shin

S Sujith

Chang-il Lee

Sudevan Sujith

Hongdae Kim

Kangmin Jung

Kodiyan Varghese Jobi

Young Gyu Han

Youngwook Kim

Byoungtak Yim

Inhun Son

Jaekoo Kim

YeonJeong Choi

Young-Soo Ko

Seungyeol Han

YoungGyu Han

Jangjae Lee

Mingyoo Park

Gyungrok Kim

Seongjun Lee

Gwangbin Moon

Byoungmu Chang

Younghyo Park

Sungjae Na

Provided are a complex prepared from ammonium salt-containing ligands and having such an equilibrium structural formula that the metal center takes a negative charge of 2 or higher, and a method for preparing polycarbonate via copolymerization of an epoxide compound and carbon dioxide using the complex as a catalyst. When the complex is used as a catalyst for copolymerizing an epoxide compound and carbon dioxide, it shows high activity and high selectivity and provides high-molecular weight polycarbonate, and thus easily applicable to commercial processes. In addition, after forming polycarbonate via carbon dioxide/epoxide copolymerization using the complex as a catalyst, the catalyst may be separately recovered from the copolymer.

Process of producing polycarbonate by copolymerization of carbon dioxide and epoxide using the same as catalyst

Provided is a resin composition for paper-coating comprising aliphatic polycarbonate having an average molecular weight of 30,000 to 300,000 obtained by reaction of one or at least two different kinds of epoxide compounds selected from a group consisting of (C2-C10)alkylene oxide substituted or unsubstituted with carbon dioxide, halogen, or alkoxy; (C4-C20)cycloalkylene oxide substituted or unsubstituted with halogen or alkoxy; and (C8-C20)styrene oxide substituted or unsubstituted with halogen, alkoxy, alkyl or aryl, wherein it contains 0 to 40 weight % of polyolefin-based resin such as polyethylene or polypropylene, based on the total amount of the composition. In addition, the present invention relates to a paper coating method of extrusion-coating the resin composition for paper-coating on paper at 130 to 250&#xb0; C. to manufacture a coated paper.

Resin composition for high barrier paper-coating

There is provided a method for preparing a low-molecular weight poly(alkylene carbonate) of which the molecular weight and chain shape are precisely controlled, by introducing a phosphorous compound having a hydroxyl group as a chain transfer agent in order to regulate the molecular weight, in alternating copolymerizing an epoxide compound and carbon dioxide by using trivalent metal complex prepared from a Salen type ligand containing a quaternary ammonium salt, and a polymer prepared by the method. Since poly(alkylene carbonate) prepared according to the present invention includes a phosphate or phosphonate group in the polymer chain, it has flame-retarding property.

Flame-retarding carbon dioxide/epoxide copolymer and method for preparing the same

Provided is a poly(alkylene carbonate) resin composition having superior low-temperature resistance, including: a) a poly(alkylene carbonate) resin prepared by copolymerization of carbon dioxide and at least one epoxide compound selected from the group consisting of (C2-C20)alkyleneoxide substituted or unsubstituted with halogen, (C1-C20)alkyloxy, (C6-C20)aryloxy, or (C6-C20)ar(C1-C20)alkyloxy; (C4-C20)cycloalkyleneoxide substituted or unsubstituted with halogen, (C1-C20)alkyloxy, (C6-C20)aryloxy or (C6-C20)ar(C1-C20)alkyoxy; and (C8-C20)styreneoxide substituted or unsubstituted with halogen, (C1-C20)alkyloxy, (C6-C20)aryloxy, (C6-C20)ar(C1-C20)alkyloxy, or (C1-C20)alkyl; and b) any one or two or more partially aromatic polyesters selected from polyester based on aliphatic and aromatic dicarboxylic acid and an aliphatic dihydroxy compound, and aliphatic polyesters prepared from aliphatic dicarboxylic acid and aliphatic diol.

Aliphatic polycarbonate/polyester polymer resin composition having superior low-temperature resistance

Coordination complexes for producing polycarbonate by copolymerization of carbon dioxide and epoxide using the same as catalyst

Provided is a method for improving thermal stability of polypropylene carbonate and, more particularly, a method of end capping a molecular chain of polypropylene carbonate using a urethane group by adding isocyanates or diisocyanates to a polypropylene carbonate resin, which may optionally be a mixture containing tertiary polyol, so as to delay thermal degradation of the polypropylene carbonate at a high temperature, thereby securing desired thermal stability. Especially, the method capable of being easily applied to reactive extrusion after preparing the polypropylene carbonate has been proposed, thus simplifying production processes and ensuring economical advantages. Moreover, the above method does not deteriorate transparency and specific smoke density characteristics at combustion, which are advantages of the polypropylene carbonate.

Method for improving thermal stability of polypropylene carbonate

Provided is a molded body in which at least one surface layer made of a copolyester polymer is laminated on one surface or both surfaces of a base layer made of aliphatic polycarbonate. When coextruding aliphatic polycarbonate and copolyester polymer, two layers adhere well to each other and are hardly delaminated from each other even without an adhesive and a tie layer, oxygen barrier property and low-temperature heat seal property can be provided as compared with a case where the copolyester polymer alone is used, the cost can be reduced because a separate adhesive or a tie layer is not required, and the manufacturing cost can be significantly reduced because the constitution of layers is simplified.

Multilayer film

This invention relates to a method of preparing poly(alkylene carbonate) that has a molecular weight and polymer chain structure precisely controlled by adding a chain transfer agent composed of a compound having an alcohol or carboxylic acid functional group upon alternating copolymerization of an epoxide compound and carbon dioxide using a catalyst composed of a trivalent metal complex compound synthesized from a quaternary ammonium salt-containing Salen type ligand, and to a polymer compound prepared thereby. According to this invention, the polymer compound having a star-shaped chain as well as the polymer having a linear chain can be prepared. The low-molecular-weight poly(alkylene carbonate) has an &#x2014;OH terminal group and can be used alone as a coating agent, etc., and also in mixtures with an isocyanate compound and thus can be easily utilized to prepare polyurethane.

Precise control of molecular weight and chain shape control in carbon dioxide/epoxide alternating copolymerization and preparation of low molecular weight poly(alkylene carbonate) thereby

The present invention related to a method of manufacturing a polycarbonate including the process of copolymerizing epoxide compound and CO2 using cobalt(III) or chromium(III), where the ligands contains at least 3 ammonium cations, central metal has formal &#x2212;1 charge, and conjugated anions of the two cationic ammonium groups are acid-base homoconjugation, as catalyst. According to the present invention, the initial induction time can be reduced when the said polycarbonate is manufactured and it is possible to improve the activity of the catalyst and the molecular weight of the obtained polymer.

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Disclosed is a polymer electrolyte composition, a gel-type polymer electrolyte obtained by mixing the same at normal temperature, and a dye-sensitized solar cell containing the electrolyte. Since the poly(alkylene carbonate)-based polymer is included, a crosslinking process by radiation of heat or UV is not required when the polymer electrolyte is manufactured, such that a manufacturing process is simple. Accordingly, the polymer electrolyte is useful for mass production of a solar cell and maintained in a uniform state without a phase separation between two components due to excellent affinity between the polymer and the organic solvent included in the electrolyte, and has excellent electrode-electrolyte interface property in the solar cell due to an adhesive property of the gelled polymer electrolyte.

Polymer electrolyte composition and dye-sensitized solar cell containing the same

Provided is a method for preparing poly(alkylene carbonate) containing ether linkages, by the copolymerization of an epoxy compound and carbon dioxide, with a trivalent metal complex prepared from a salen type ligand containing a quaternary ammonium salt, and a double metal cyanide (DMC) catalyst together. The amount of ether linkages can be controlled by regulating the weight ratio of two catalysts and the carbon dioxide pressure.

Method for preparing carbon dioxide/epoxide copolymers containing ether linkages

Coordination complexes and process of producing polycarbonate by copolymerization of carbon dioxide and epoxide using the same as catalyst

Provided is a resin composition based on polyalkylene carbonate for use as an adhesive film composition for glass lamination, and more particularly, to a resin composition in which a plasticizer and isocyanate are added to polypropylene carbonate or polyethylene carbonate as polyalkylene carbonate to introduce a urethane group. As such, the resin composition of the present invention can improve an adhesive strength by addition of isocyanate, and secure flexibility by using the plasticizer. In particular, an adhesive sheet based on polyalkylene carbonate can decompose a polymer laminate layer through simple heat treatment to fully collect glass when defects of glass lamination are generated, thereby reducing the loss of glass due to process failure, be stable to moisture so that transport, storage, and use thereof are not limited, and perform lamination even at a lower process temperature.

Adhesive film composition for glass lamination

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Daejeon, South Korea

Myungahn Ok