Samsung Sdi Co., Inc.

Samsung Electronics Co., Ltd.

Myung-sup Jung

Jin-gyu Lee

Jae-jun Lee

Sang-Kook Mah

Do-yun Kim

Soo-suk Lee

Sung-ouk Jung

A solid acid having a core of calixarene or calix resorcinarene. The solid acid is an ion conducting compound in which at least one of the hydroxyl groups is substituted by an organic group having a cation exchange group at a terminal end, a polymer electrolyte membrane including the same, and a fuel cell using the polymer electrolyte membrane. The polymer electrolyte membrane can provide low methanol crossover and high ionic conductivity. Accordingly, a fuel cell having high efficiency can be obtained by using the polymer electrolyte membrane.

Solid acid, polymer electrolyte membrane including the same, and fuel cell using the polymer electrolyte membrane

Provided herein is a method of manufacturing a gas sensor. The method includes forming electrodes on a surface of a substrate, manufacturing a paste having a complex of CNTs and a metal-ligand complex comprising a metal that has gas adsorption selectivity for specific gases, coating the paste on the substrate to cover the electrodes, patterning the paste by a photolithography process, and reducing the metal-ligand complex included in the patterned paste.

Method of manufacturing gas sensor

Provided is a polymer electrolyte membrane including an inorganic nanoparticle bonded with a proton-conducting group, a solid acid and a proton-conducting polymer. The inorganic nanoparticle bonded with the proton-conducting group may be obtained by reacting a compound including a proton-conducting group with a metal precursor. The polymer electrolyte membrane has significantly enhanced proton conductivity and reduced methanol crossover.

Polymer electrolyte membrane comprising inorganic nanoparticle bonded with proton-conducting group and solid acid, fuel cell including the same, and method of preparing the polymer electrolyte membrane

Provided are a dendrimer solid acid and a polymer electrolyte membrane using the same. The polymer electrolyte membrane includes a macromolecule of a dendrimer solid acid having ionically conductive terminal groups at the surface thereof and a minimum amount of ionically conductive terminal groups required for ionic conduction, thus suppressing swelling and allowing a uniform distribution of the dendrimer solid acid, thereby improving ionic conductivity. Since the number of ionically conductive terminal groups in the polymer electrolyte membrane is minimized and the polymer matrix in which swelling is suppressed is used, methanol crossover and difficulties of outflow due to a large volume may be reduced, and a macromolecule of the dendrimer solid acid having the ionically conductive terminal groups on the surface thereof is uniformly distributed. Accordingly, ionic conductivity is high and thus, the polymer electrolyte membrane shows good ionic conductivity even in non-humidified conditions.

Dendrimer solid acid and polymer electrolyte membrane including the same

A polymer electrolyte membrane, a method of manufacturing the same, and a fuel cell including the polymer electrolyte membrane are provided, wherein the polymer electrolyte forms an interpenetrating polymer network (IPN) of a polymer by simple blending of a hydrophobic polyimide having a reactive terminal group and a hydrophilic aromatic polymer having ion conductivity. The polymer electrolyte membrane has reduced swelling properties due to highly dense crosslinking of polyimide through the reactive terminal group, shows high ion conductivity at low humidity, and has methanol crossover suppressing ability. Accordingly, a fuel cell with improved electric and mechanical properties can be provided.

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Yongin-si, South Korea

Myung-sup Jung