Colgate Palmolive Company

Myriam M Loth

Barbara J Thomas

Myriam M Mondin

Guy J Broze

Ammanuel Mehreteab

Steven T Adamy

Frank J Bala, Jr

Claude A Blanvalet

Baudouin Valange

Thomas F Connors

Fabienne M Jacquet

Marie D DeBrucq

An improvement is described in the liquid crystal composition or the microemulsion compositions which is more environmentally friendly and is especially effective in the removal of oily and greasy soil and having an evidenced grease release effect, contains an anionic detergent, an ethoxylated polyhydric alcohol, a hydrocarbon ingredient, optionally, a dialkyl sulfosuccinate, a fatty acid and water which comprises the use of a water-insoluble odoriferous perfume as the essential hydrocarbon ingredient in a proportion sufficient to form a dilute o/w microemulsion composition containing, by weight, 1% to 20% of an anionic surfactant, 0.1 to 50% of a cosurfactant, 0.1% to 20% of an ethoxylated polyhydric alcohol, 0.4% to 10% of perfume and the balance being water.

Microemulsion all purpose liquid cleaning compositions comprising

An improvement is described in the liquid crystal composition or the microemulsion compositions, which is especially effective in the removal of oily and greasy soil and having an evidenced grease release effect, contains an anionic detergent, an ethoxylated glycerol type compound, a hydrocarbon ingredient, at least one cosurfactant, and water which comprises the use of a water-insoluble odoriferous perfume as the essential hydrocarbon ingredient in a proportion sufficient to form a dilute o/w microemulsion composition containing, by weight, 1% to 20% of an anionic surfactant, 0.1 to 50% of at least one cosurfactant, 0.1% to 20% of an ethoxylated glycerol type compound, 0.4% to 10% of perfume and the balance being water.

Microemulsion liquid crystal cleaning compositions comprising esterified

A stable oil-in-water microemulsion cleaning composition is provided which is essentially effective for the removal of oily and greasy soil from a hard surface and for repelling insects therefrom. The aqueous phase of said microemulsion comprises by weight of the total composition: (A) from about 0.1 to about 25% of a surfactant mixture of (i) an anionic surfactant; (ii) an ethoxylated glycerol-based nonionic surfactant mixture; the weight ratio of (i) and (ii) being from about 1:1 to about 5:1; and (iii) a salt of a multivalent metal cation in an amount sufficient to provide from 0.5 to 1.5 equivalents of cation per equivalent of (i); the anionic surfactant, the nonionic surfactant and amount of multivalent metal cation being selected so as to provide a cloud point of at least about 45.degree. C. in the finished microemulsion composition; (B) from about 0.1% to about 30% of a water-soluble cosurfactant having substantially no ability to dissolve oily or greasy soil; and (C) the balance water. The oil phase of said microemulsion is comprised essentially of an effective amount of an insect repellent compound, and optionally a perfume or water insoluble hydrocarbon, said microemulsion composition being effective for removing oily and greasy soils from a hard surface and repelling insects therefrom by solubilizing such soils in the microemulsion while concomitantly depositing the insect repellent compound upon the hard surface to be cleaned to provide insect repelling properties thereto.

Microemulsion all-purpose liquid cleaning compositions with insect

An improvement is described in the liquid crystal composition or the microemulsion composition, which is especially effective in the removal of oily and greasy soil and having an evidenced grease release effect, contains an anionic detergent, an ethoxylated glycerol type compound, a hydrocarbon ingredient, and water which comprises the use of a water-insoluble odoriferous perfume as the essential hydrocarbon ingredient in a proportion sufficient to form a dilute o/w microemulsion composition containing, by weight, 1% to 20% of an anionic detergent, 0.1 to 50% of a cosurfactant, 0.1% to 10% of the ethoxylated glycerol type compound, 0 to 1.0% of a tri-alkyl citrate, 0.4% to 10% of perfume and the balance being water.

Cleaning composition in microemulsion or liquid crystal form comprising

An improvement is described in the liquid crystal composition or the microemulsion compositions, which is especially effective in the removal of oily and greasy soil and having an evidenced grease release effect, contains an anionic detergent, an ethoxylated polyhydric alcohol, a hydrocarbon ingredient, a fatty acid and water which comprises the use of a water-insoluble odoriferous perfume as the essential hydrocarbon ingredient in a proportion sufficient to form a dilute o/w microemulsion composition containing, by weight, 1% to 20% of an anionic surfactant, 0.1 to 50% of a cosurfactant, 0.1% to 20% of an ethoxylated polyhydric alcohol, 0.4% to 10% of perfume and the balance being water.

Cleaning composition in microemulsion, crystal or aqueous solution form

A stable oil-in-water microemulsion cleaning composition is provided which is essentially effective for the removal of oily and greasy soil from a hard surface and for repelling insects therefrom. The aqueous phase of said microemulsion comprises by weight of the total composition: (A) from about 0.1 to about 25% of a surfactant mixture of (i) an anionic surfactant; (ii) a nonionic surfactant; the weight ratio of (i) and (ii) being from about 1:1 to about 5:1; and (iii) a salt of a multivalent metal cation in an amount sufficient to provide from 0.1 to 1.5 equivalents of cation per equivalent of (i); the anionic surfactant, the nonionic surfactant and amount of multivalent metal cation being selected so as to provide a cloud point of at least about 45.degree. C. in the finished microemulsion composition; (B) from about 0.1% to about 30% of a water-soluble cosurfactant having substantially no ability to dissolve oily or greasy soil; and (C) the balance water. The oil phase of said microemulsion is comprised essentially of an effective amount of an insect repellent compound, and optionally a perfume or water insoluble hydrocarbon, said microemulsion composition being effective for removing oily and greasy soils from a hard surface and repelling insects therefrom by solubilizing such soils in the microemulsion while concomitantly depositing the insect repellent compound upon the hard surface to be cleaned to provide insect repelling properties thereto.

Microemulsion liquid cleaning compositions with insect repellent

An improvement is described in microemulsion compositions which are more friendly to the environment and contain an anionic sulfate surfactant, an esterfied polyethoxyether surfactant, a cosurfactant, at least one hydrocarbon, and water which can comprise the use of a water-insoluble odoriferous perfume as the essential hydrocarbon in a proportion sufficient to form a dilute o/w microemulsion composition preferably containing, by weight, 0.1% to 8% of an anionic sulfate surfactant, 1% to 50% of a cosurfactant, 1% to 20% of an ethoxylated glycerol type compound, 0.4% to 20% of perfume and the balance being water.

Microemulsion all purpose liquid cleaning compositions

An improvement is described in the liquid crystal composition or the microemulsion compositions, which is especially effective in the removal of oily and greasy soil and having an evidenced grease release effect, contains an anionic detergent, an ethoxylated glycerol type compound, a hydrocarbon ingredient, and water which comprises the use of a water-insoluble odoriferous perfume as the essential hydrocarbon ingredient in a proportion sufficient to form a dilute o/w microemulsion composition containing, by weight, 1% to 20% of an anionic surfactant, 0.1 to 50% of a cosurfactant, 0.1% to 20% of an ethoxylated glycerol type compound, 0.4% to 10% of perfume and the balance being water.

Cleaning composition in microemulsion, liquid crystal or aqueous

Low viscosity and high pH disinfecting and bleaching all purpose cleaning compositions in microemulsion form, suitable in both concentrated and diluted forms for applying to surfaces to be cleaned and disinfected or sanitized, include hypochlorite, higher alcohol sulfate and higher paraffin sulfonate detergents, higher fatty acid soap, alkali metal hydroxide, liquid hydrocarbon, perfume, periodate, branched lower alcohol co-surfactant and water. The compositions are of improved lipophilic soil removing capability when diluted with water, are of about equivalent such capability in neat or concentrated form and are of significantly better hypochlorite stability on aging at room and elevated temperatures, compared to other microemulsion cleaners that contain hypochlorite. Their low viscosities facilitate spraying them from squeeze bottles or pump sprayers onto surfaces to be cleaned and disinfected or sanitized, such as floors and walls. The absence of any builder salts allows uses of the compositions, especially in diluted form, to clean surfaces without the need for rinsing (wiping sufficing), and the cleaned surfaces are not objectionably streaky afterward. The concentrated microemulsions are effective removers of mildew from bathroom tub and shower tiles, and other surfaces, but in such cases rinsing is usually desirable. Also described are processes for the manufacture and use of the described cleaning compositions.

Stable microemulsion disinfecting detergent composition

Stable microemulsion cleaning compositions are described which, in the absence of opacifying component, appear clear to the eye, and which are especialy useful for cleaning surfaces having oily or greasy soils thereon, which comprise synthetic organic detergent, water, co-surfactant of a described type, and perfume (or equivalent hydrocarbon). The detergent composition may be concentrated and may be employed as is, or it may be in dilution with water, in the form of a similarly clear and stable microemulsion. In process aspects of the invention both the concentrated and the diluted compositions may be employed to remove oily and greasy stains from substrates, such as normally shiny bathroom fixture and floor and wall surfaces, including tiles, by a 'spray and wipe' process, which leaves the surface shiny, with minimal or no rinsing needed. When the invented compositions are acidic they are also useful for removing lime scale and soap scum from hard surfaces. Also described are processes for manufacturing the invented compositions.

Stable microemulsion cleaning composition

An improvement is described in microemulsion compositions containing an anionic detergent, one of the specified cosurfactants, a hydrocarbon ingredient and water which comprises the use of a water-insoluble odoriferous perfume as the essential hydrocarbon ingredient in a proportion sufficient to form either a dilute o/w microemulsion composition containing, by weight, 1% to 10% of an anionic detergent, 2% to 10% of cosurfactant, 0.4% to 10% of perfume and the balance water or a concentrated microemulsion composition containing, by weight 18% to 65% of anionic and nonionic detergent, 2% to 30% of cosurfactant, 10% to 50% of perfume and the balance water which upon dilution with water will yield said dilute o/w microemulsion composition.

Microemulsion all purpose liquid cleaning composition

A stable microemulsion cleaning composition is described, which, in the absence of opacifying component, appears clear to the eye, and which is especially useful for cleaning surfaces having oily or greasy soils thereon, which comprises synthetic organic detergent, water, co-surfactant of the described type, and perfume, which is the only 'solvent'. The concentrated detergent composition may be employed as is, or may be easily diluted with water to form a similarly clear and stable microemulsion. In process aspects of the invention both the concentrated and the diluted compositions may be employed to remove oily and greasy stains from substrates, such as normally shiny bathroom fixture and floor and wall surfaces, including tiles, by a 'spray and wipe' process, which leaves the surface shiny. When the invented compositions are acidic they are useful for removing lime scale and soap scum from hard surfaces. Also described are processed for manufacturing and diluting the invented compositions.

An improvement is described in microemulsion compositions containing an anionic detergent, one of the specified cosurfactants, a hydrocarbon ingredient and water which comprises the use of a water-insoluble odoriferous perfume as the essential hydrocarbon ingredient in a proportion sufficient to form either a dilute o/w microemulsion composition containing, by weight, 1% to 10% of an anionic detergent, 2% to 10% of cosurfactant, 0.4% to 10% of perfume and the balance water or a concentrated microemulsion composition containing, by weight, 18% to 65% of anionic and nonionic detergent, 2% to 30% of cosurfactant, 10% to 50% of perfume and the balance water which upon dilution with water will yield said dilute o/w microemulsion composition.

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Saint-Nicolas, Belgium

Myriam M Loth