Asahi Kasei Chemicals Corporation

Mitsubishi Gas Chemical Company, Inc.

Mutsumi Maeda

Hiroaki Furukawa

Akira Mitsui

Yuji Takeda

Shigero Yamamoto

Method for producing polyphenylene ether, comprising preparing a polymerization solution of 10-25 parts by mass of a phenolic compound (M) and 75-90 parts by mass of an aromatic solvent (A) with the total of the compound and the solvent being 100 parts by mass, and 0.1-10 parts by mass of a catalyst (C) containing a metal salt; performing oxidative polymerization of the phenolic compound (M) by passing oxygen-containing gas through polymerization solution; stopping polymerization by mixing aqueous chelating agent solution into polymerization solution; subjecting a diphenoquinone compound produced as a by-product to quinone binding process or removal by reduction; and obtaining polyphenylene ether by separating aqueous phase through liquid-liquid separation. In the method for producing a polyphenylene ether, 0.001-0.004 part by weight of an ion catalyst (D) is added into the polymerization solution before the liquid-liquid separation.

Method for producing polyphenylene ether

Disclosed is a method for producing a polyphenylene ether, which comprises a step of preparing a polymerization solution composed of 10-25 parts by mass of a phenolic compound (M) and 75-90 parts by mass of an aromatic solvent (A) with the total of the compound and the solvent being 100 parts by mass, and 0.1-10 parts by mass of a catalyst (C) containing a metal salt; a step of performing an oxidative polymerization of the phenolic compound (M) by passing an oxygen-containing gas through the polymerization solution; a step of stopping the polymerization by mixing an aqueous chelating agent solution into the polymerization solution; a step of subjecting a diphenoquinone compound produced as a by-product to a quinone binding process or removal by reduction; and a step of obtaining a polyphenylene ether by separating the aqueous phase through liquid-liquid separation. In the method for producing a polyphenylene ether, 0.001-0.004 part by weight of an ion catalyst (D) is added into the polymerization solution before the liquid-liquid separation.

A method for producing a conductive polyamide-polyphenylene ether resin composition comprising (A) 10 to 90 parts by mass of a polyphenylene ether resin, (B) 5 to 85 parts by mass of a polyamide having a (terminal amino group)/(terminal carboxyl group) ratio falling within the range from 0.20 to 4.0, (C) 5 to 85 parts by mass of a polyamide having a (terminal amino group)/(terminal carboxyl group) ratio falling within the range from 0.05 to 0.19 and (D) 0.1 to 10 parts by mass of a conductive filler, the method comprising the step of melt-kneading of the component (A), the component (B), a compatibilizer (F) and a master batch (E) obtained by melt-kneading of the component (D) and the component (C) in advance.

Process for production of conductive resin composition

A polyphenylene ether resin composition comprising a polyphenylene ether, wherein the polyphenylene ether has a polymer chain comprising recurring units each represented by the following formula (1): and has the following characteristics (a), (b) and (c):

Composition comprising poly(2,6-dimethylphenylene) ether

Method for precipitating polyphenylene ether which decreases fine particles therein and reduces periodic fluctuations in particle size. Method provides homogeneous polyphenylene ether particles. Polyphenylene ether particles are precipitated using mixed solution comprising good solvent for polyphenylene ether and poor solvent for polyphenylene ether. Method employs precipitation tank equipped with draft tube, stirring blade, baffle(s), solution supply port, poor solvent supply port, and exhaust port. Polyphenylene ether particles and poor solvent are added to mixed solution comprising good solvent and circularly flowed by rotation of stirring blade, polyphenylene ether solution for solution supply port, and poor solvent for poor solvent supply port, thereby precipitating polyphenylene ether particles having desired properties.

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Tokyo, Japan

Mutsumi Maeda