Saudi Arabian Oil Company

William Marsh Rice University

Muhammad M Rahman

Peter James Boul

Pulickel Madhavapanicker Ajayan

Seyed Mohammad Sajadi

Carl Joseph Thaemlitz

Ashok Kumar Meiyazhagan

Hasmukh A Patel

Ali Zein Khater

Chandra Sekhar Tiwary

Ashok Kumar

Carl Thaemltiz

AshokKumar Meiyazhagan

A process for making a layered multi-material structural element having controlled mechanical failure characteristics. The process includes the steps of: supplying a cementitious layer and forming a polymer layer on the cementitious layer by additive manufacture such that the polymer layer has a first thickness and the cementitious layer has a second thickness, wherein the polymer layer comprises a polymer and the cementitious layer comprises a cementitious material; and allowing the polymer from the polymer layer to suffuse into the cementitious layer for a period of time to obtain a suffused zone in the cementitious layer such that the suffused zone has a third thickness that is less than half the second thickness.

Additive manufacture-assisted method for making structural elements having controlled failure characteristics

This document relates to sealant compositions containing a sliding-ring polymer (polyrotaxane) additive and a polymeric matrix material. The sealant materials exhibit enhanced mechanical properties as compared to the same sealant composition that does not contain the additive. This document also relates to 3D-printed sealant compositions containing a sliding-ring polymer (polyrotaxane) additive and a polymeric matrix material.

3D-printed polyrotaxane additives and compositions

This document relates to shape memory compositions containing a sliding-ring polymer (polyrotaxane) additive and a thermally-curable epoxy resin. The shape memory compositions are able to deform and reform in response to external stimuli. This document also relates to 3D-printed shape memory compositions containing a sliding-ring polymer (polyrotaxane) additive and a thermally-curable epoxy resin.

Shape memory behavior of epoxy/sliding-ring polymer composites

This document relates to epoxy compositions containing a sliding-ring polymer (polyrotaxane) additive and a thermally-curable epoxy resin. The epoxy compositions exhibit increased flexural toughness and impact resistance as compared to the same epoxy composition that does not contain the additive. This document also relates to 3D-printed epoxy compositions containing a sliding-ring polymer (polyrotaxane) additive and a thermally-curable epoxy resin.

Epoxy compositions containing polyrotaxane additives having improved impact strength

Methods for fabricating a multi-material composite structure are described. Methods for fabricating a multi-material composite structure include forming a first colloidal ink solution with a first material matrix, water, and a rheology modifying agent; forming a second colloidal ink solution with a second material matrix, water, and a rheology modifying agent; printing a first layer on a substrate using a first printing nozzle carrying the first colloidal ink solution; printing a second layer on top of the first layer using a second printing nozzle carrying the second colloidal ink solution; forming a 3D structure by printing a plurality of layers including the first layer and the second layer printed in an alternating pattern; and sintering the 3D structure to form the multi-material composite structure.

Direct ink printing of multi-material composite structures

Provide is a cement ink for a cement ink for 3D printing (which also includes additive manufacturing) of 3D cement structures and materials. The cement ink includes an American Petroleum Institute (API) Class G cement, a nano-clay, a superplasticizer, a hydroxyethyl cellulose, and a defoamer. The nano-clay may be hydrophilic bentonite. The superplasticizer may be a polycarboxylate ether. The defoamer may be 2-ethyl-1-hexanol. Processes for forming the cement ink and printing 3D cement structures using the cement ink are also provided.

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Houston, TX, United States of America

Muhammad M Rahman