King Abdulaziz City for Science and Technology

Mohamed Mokhtar Mohamed Mostafa

Abdulaziz Bagabas

Abdulrahman A Al-Rabiah

Vagif Melik Akhmedov

Zeid A Al-Othman

Mohamed F Aboud

Vagif Malik Akhmedov

Emad Addurihem

Ahmed S Alshammari

Musaed A Alangari

A simple, room-temperature method of producing CuO-doped zinc oxide nanoparticles was established by reacting zinc nitrate hexahydrate, copper nitrate trihydrate and cyclohexylamine (CHA) at room temperature. These nanoparticles may be used for photocatalytic degradation of cyanide in aqueous solutions. The degradation of cyanide is effective because electrons transfer from the p-type copper oxide to the n-type zinc oxide.

Synthesis of copper oxide-doped zinc-oxide nanoparticles and their use

Isopropyl alcohol is a very useful chemical that is widely used in the industry as a solvent. Economical and easy process to make ispopropyl alcohol using novel composite catalyst is described in the instant application. Production of isopropyl alcohol (IPA) from dimehtyl ketone (DMK) and hydrogen (H) in gas-phase using a ruthenium nano-particle-supported on activated charcoal/nano-zinc oxide composite catalyst is described. Gas phase production of isopropyl alcohol using DMK and hydrogen is also described using optimal time on stream, temperature, catalyst ratio and DMK/Hratio. Ruthenium nano-zinc oxide composite catalyst is formulated using different ratios of ruthenium activated charcoal and n-ZnO is described. CAT-IV is shown to be the best performer for the efficient production of isopropyl alcohol.

Composite catalyst and using the same for making isopropyl alcohol

Ruthenium/activated charcoal (Ru/AC) treated with synthesized nano-ZnO (n-ZnO) is used for the first time as a novel composite catalyst in one-step self-condensation of acetone (DMK) to methyl isobutyl ketone in the gas phase. The DMK self-condensation was performed under atmospheric pressure, in a tubular glass fixed-bed microreactor, under DMK and Hcontinuous flow at temperature in the range of 523 to 648 K. Addition of n-ZnO to Ru/AC resulted in a pronounced increase in the degree of dispersion of Ru and in the acidic/basic sites concentration ratio. For the one-step synthesis of MIBK at 623 K, the composite catalyst with 2.5 wt % Ru loading was an active and selective bi-functional composite catalyst with balanced acid/base and hydrogenation properties. At 523 K, isopropyl alcohol, product of DMK-direct hydrogenation, was produced in high selectivity for instantly investigated composite catalyst. The catalytic performance depended on the composite catalyst identity, DMK flow rate, Hflow rate, and reaction temperature.

Synthesizing and utilizing novel ruthenium nanoparticle-activated charcoal-nano-zinc oxide composite catalyst

Several metal-supported catalyst compositions based on nano-crystalline zinc oxide were synthesized and characterized by X-ray powder diffraction (XRD), Carbon dioxide temperature programmed desorption (COTPD), and nitrogen adsorption at &#x2212;196&#xb0; C. The Pd-supported nano-ZnO mixed with different oxides such as CrO, CrO, MgO, and &#x3b3;-AlOshowed high catalytic activity in acetone condensation in gas-phase process under hydrogen flow. This reaction involves the base-acid coupling of acetone to form mesityl oxide, followed by its hydrogenation to methyl isobutyl ketone (MIBK). The novel catalyst 1% wt. n-Pd/n-ZnCrOwas utilized during gas-phase reaction during production of MIBK. MIBK selectivity was 70-72% at 66-77% acetone conversion at 300-350&#xb0; C. Diisobutyl ketone (DIBK) was the main by-product, with a total MIBK+DIBK selectivity up to 88%. The prepared catalysts showed stable activity and may be used repeatedly and for a longer period of time.

Growing community of inventors

Cairo, Egypt

Mohamed Mokhtar Mohamed Mostafa