Dic Corporation

Dainippon Ink and Chemicals, Incorporated

Mitsuru Kitada

Sadamu Nagahama

Kazuo Kuba

Ryuichi Matsuoka

Chisato Kuriyama

Hiroki Tanaka

Yutaka Hashimoto

Kenji Nagao

Toshifumi Tamaki

Hiroaki Matsubara

Yoshitaka Satoh

Takeo Ikeda

Kiyomi Nagano

Tomokazu Higeshiro

Provided is an aqueous resin composition in which a vinyl ester resin and a urethane resin having an aromatic ring are dispersed in an aqueous medium, in which the vinyl ester resin is obtained by allowing at least one epoxy resin selected from the group consisting of a novolak type epoxy resin and a bisphenol type epoxy resin to react with a compound having an acid group and a polymerizable unsaturated group, and the urethane resin is obtained by allowing polyol containing polyol having an aromatic ring and polyol having a hydrophilic group to react with a polyisocyanate. A primer using the aqueous resin composition is able to considerably improve adhesiveness between a substrate and a cured coating film of an active energy ray curable composition, even when the substrate is a sparingly adhesive substrate.

Aqueous resin composition, laminate produced using same, and image display device

The present invention provides an ink jet recording medium which is capable of uniform coating with an ink-receiving agent without a surface treatment step for a usual plastic film used as a base material, and which, due to excellent adhesion , does not cause the problem of peeling after ink jet printing, and does not cause the problem of ink binning, fading, dropout, or peeling or peeling of an ink-receiving layer and an over-coating layer, and also provides a printed material formed by ink jet printing on the ink jet recording medium. The ink jet recording medium including a first layer containing a polyolefin resin as a main component, a second layer containing an acid-modified olefin resin, and an ink-receiving layer is used, the ink-receiving layer being formed by applying an ink-receiving agent on the second layer after the first and second layers are laminated by a coextrusion laminating method.

Inkjet recording medium, printed material, method for producing same, and package

It is an object of the present invention to provide a water-based composite resin composition which has an excellent long-term storage stability and which enables formation of a coating film having an excellent water resistance and solvent resistance. The present invention relates to a water-based composite resin composition and a coating agent; the water-based composite resin composition containing composite resin particles (A) and an aqueous medium (B), the composite resin particles (A) containing polyester resin (a1) particles having a sulfonate group and an epoxy resin (a2) of which some or all parts are encapsulated in the polyester resin (a1) particles, wherein a mass ratio [(a1)/(a2)] of the polyester resin (a1) to the epoxy resin (a2) in the composite resin particles (A) is in the range of 95/5 to 30/70.

Water-based composite resin composition and an article comprising the same

A problem to be solved by the present invention is to provide a polyurethane film that offers both soft texture and high strength. The present invention relates to a polyurethane film obtained by solidifying a polyurethane (A) obtained by reacting a polyol (a1) including an aliphatic polyester polyol having an anionic group (a1-1), and a polyester polyol (a1-2) other than the aliphatic polyester polyol (a1-1) with a polyisocyanate (a2), using a metal salt, in which the polyurethane (A) has an aromatic structure in the range of 500 mmol/kg to 2,000 mmol/kg with respect to the entire polyurethane (A).

Polyurethane film and processed film produced using same

It is an object of the present invention to provide a binder for ink-jet printing ink that can form printed images having excellent scratch resistance and good alcohol resistance without impairing good discharge stability of ink. The present invention relates to a binder for ink-jet printing ink including a polyurethane (A) that has a hydroxyl group at a molecular terminal, has a weight-average molecular weight of 30,000 to 70,000, and is obtained by causing a reaction of a polyisocyanate and a polyol (a2) containing a particular polyether polyol so that the equivalent ratio [isocyanate group [X]/hydroxyl group [Y]] of an isocyanate group [X] in the polyisocyanate (a1) to a hydroxyl group [Y] in the polyol (a2) is in the range of 0.930 to 0.995 and an aqueous medium (B). The hydroxyl group present at the molecular terminal of the polyurethane (A) is a hydroxyl group derived from the polyether polyol.

Binder for ink-jet printing ink, ink-jet printing ink containing the same, and printed matter

An object to be achieved by the present invention is to provide a binder for an ink-jet printing ink, the binder being capable of forming a printed image having excellent durability such as rubfastness and alkali resistance without impairing good ejection stability, storage stability, etc. of an ink, and an ink-jet printing ink containing the binder. The present invention relates to a binder for an ink-jet printing ink, the binder containing an aqueous medium (D); and a polyurethane (C) obtained by reacting a polyol (A) containing a vinyl polymer (a1) having two hydroxyl groups at one end and at least one polyol (a2) selected from the group consisting of polyether polyols, polyester polyols, polyester ether polyols, and polycarbonate polyols with a polyisocyanate (B), the polyurethane (C) having a structure derived from the vinyl polymer (a1) in a side chain thereof and being dispersed in the aqueous medium (D), and printed matter.

Binder for inkjet printing ink, inkjet printing ink containing the binder, and printed product

An object of the present invention is to provide a method for producing a binder for inks and for use in producing an inkjet printing ink that has both good ink dischargeability and blend stability. A method for producing a binder for inkjet printing inks, the binder containing a hydrophilic-group-containing urethane resin (A), an acetylene compound (B), and an aqueous medium (C), includes step (1) of allowing Ga polyol (a1) containing a hydrophilic-group-containing polyol to react with a polyisocyanate (a2) in an organic solvent or in the absence of a solvent and feeding the organic solvent as needed to prepare an organic solvent solution [I], step (2) of mixing the organic solvent solution [I] with the acetylene compound (B) and the aqueous medium (C) to prepare a mixture [II], and step (3) of removing the organic solvent contained in the mixture [II].

Method for producing binder for inkjet printing ink, inkjet printing ink, and printed material

Disclosed is an aqueous coating agent comprising a water dispersion (C) prepared by dispersing resin particles containing a water-dispersible polyurethane resin (A) and at least one compound selected from a hydrophobic polyester polyol (B-1) and a hydrophobic polyether polyol (B-2) in water, and a crosslinking agent (D) capable of reacting with a hydroxyl group, wherein the water-dispersible polyurethane resin (A) is obtained by reacting a polyester polyol (a-1), which is obtained by condensing a dicarboxylic acid containing an aromatic dicarboxylic acid as a main component with a polyol, with a polyisocyanate, and also contains 15 to 35% by weight of an aromatic cyclic structural unit, and wherein the hydrophobic polyester polyol (B-1) and/or the hydrophobic polyether polyol (B-2) are liquid at normal temperature and contain 20 to 50% by weight of an aromatic cyclic structural unit.

Water-base coating material

An aqueous urethane resin dispersion for bonding can be used in wet lamination and dry lamination and can be reactivated easily at a low temperature of about 50 to 70&#xb0; C. after drying, and is also superior in coatability, adhesive strength, and heat resistance. The aqueous dispersion of a polyurethane resin is superior in contact adhesiveness immediately after lamination and also has good permeability and good coatability not only on bases having smooth surfaces such as plastics and metals, but also on porous bases such as fibers, papers, and buffed leathers; an aqueous adhesive using the aqueous dispersion; and an article to which it is applied. The aqueous polyurethane resin dispersion has at least one of a sulfonate group and a carboxylate group, wherein an average particle diameter of the polyurethane resin is 0.05 to 0.30 &#x3bc;m and a surface tension of the aqueous dispersion (A) is 40 mN/m or less.

Aqueous polyurethane resin dispersion and aqueous adhesive

An aqueous dispersion of a polyurethane resin obtainable from compounds including: (A) an organic polyisocyanate; (B) a polyester polyol containing an aromatic metal sulfonate group; (C) an aliphatic polyol being free from aromatic metal sulfonate and having a hydroxyl value of from 10 to 350; and (D) at least one of a polyamine and a polyol each having a molecular weight of 300 or lower, wherein the content of said aliphatic polyol unit (C) amounts to at least 55% by weight based on the solid content of said polyurethane resin. Also disclosed is an aqueous adhesive comprising the polyurethane resin aqueous dispersion.

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Osaka, Japan

Mitsuru Kitada