Basf Se Corporation

Basf Se (reitstÖtter, Kinzebach & Partner)

Miriam Bru Roig

Ralf Pelzer

Florian Garlichs

Manuel Danz

Stefan Rüdenauer

Wolfgang Siegel

Stephan Maurer

Christoph Stock

Albert Werner

Ulrich Mueller

Andrei-Nicolae Parvulescu

Stephan Andreas Schunk

Michael Limbach

Melanie Weingarten

Volker Hickmann

Michael Ludwik Lejkowski

Alvaro Gordillo

Ronald Lindner

Nuria Huguet Subiela

Stefan Ruedenauer

Joaquim Henrique Teles

Rolf Pinkos

Andreas Keller

Joachim Pfeffinger

Roman Dostalek

Shrirang Bhikaji Hindalekar

Veit Stegmann

Bernhard Brunner

Vijay Narayanan Swaminathan

Thomas Fenlon

Andreas Ernst

Stephanie Renz

Nicolas Marion

Nitin Gupte

Ivana Jevtovikj

Anja Vinckier

Helmut Kronemayer

Margarethe Klos

Prachin Kolambkar

Michael Ludwig Lejkowski

Silke Weyland

Alexander Duefert

Roland Minges

Takeharu Kageyama

Regina-Margareta Berg

Sabine Chantal Eileen Stieber

Shrirang Hindalekar

Ulrich MÜLLER

Margerethe Klos

Michael Lejkowski

Vijay Swaminathan

The present invention relates to substituted 4-methylene-tetrahydropyrans, 4-methyl-dihydropyrans and 4-methyl-tetrahydropyrans of formula (I), where the variables are as defined in the claims and description, to a stereoisomer thereof, to a mixture of stereoisomers thereof, to a mixture of different di- and tetrahydropyrans (I) and to a mixture containing at least one di- or tetrahydropyran (I) and at least one cyclic acetal which is a 1,3-dioxan carrying in 2-position an isobutanol-2-yl-(derived) substituent and in 4,4- or 5,5-position two methyl substituents. The invention also relates to the use of such compounds as an aroma chemical and/or for modifying and/or enhancing the aroma of a composition, to compositions comprising such compounds, to methods for preparing such compounds and to a product obtainable by these methods.

Substituted 4-methylene-tetrahydropyrans, 4-methyl-dihydropyrans and 4-methyl-tetrahydropyrans and use thereof as aroma chemicals

The presently claimed invention is directed to the use of 1-alkoxyethyl-4-isobutyl-benzene of formula (I) to impart an aroma impression to a composition. The presently claimed invention also relates to a method of imparting such aroma impression. The present invention is further directed to compositions comprising the compound of formula (I) and at least one aroma chemical as well as to compositions comprising the compound of formula (I) and at least one further component selected from the group consisting of aroma chemicals, surfactants, oil components, anti-oxidants, deodorant-active agents and solvents. The present invention also relates to a compound of formula (I').

1-alkoxyethyl-4-isobutyl-benzene as aroma ingredients

The present invention relates to the use of an ether or an ester of a tertiary alkanol or of mixtures of two or more ethers or esters of tertiary alkanols or of a stereoisomer thereof or of a mixture of two or more stereoisomers thereof as aromachemicals; to the use thereof for modifying the scent character of a fragranced composition; to an aroma chemical composition containing an ether or an ester of tertiary alkanol or of mixtures of two or more ethers or esters of tertiary alkanols or of a stereoisomer thereof or of a mixture of two or more stereoisomers thereof; and to a method of preparing a fragranced composition or for modifying the scent character of a fragranced composition. The invention further relates to specific ethers or esters of tertiary alkanols.

Ethers and esters of tertiary alkanols for use as aroma chemicals

The present invention relates to the use of 2-furyl- and 2-thienyl-substituted di- and tetrahydropyrans of the formula (I) wherein the variables are as defined in the claims and the description, as aroma chemicals; to aroma chemical compositions comprising at least one 2-furyl- or 2-thienyl-substituted di- or tetrahydropyran and to a method for preparing an aroma chemical composition. The present invention further relates to specific 2-furyl- and 2-thienyl-substituted di- and tetrahydropyrans and to a method for their preparation.

2-furyl- and 2-thienyl-substituted di- and tetrahydropyrans for use as aroma chemicals

The present invention relates to the use of an ether or an ester of a 1-substituted cycloalkanol or of mixtures of two or more ethers or esters of 1-substituted cycloalkanols or of a stereoisomer thereof or of a mixture of two or more stereoisomers thereof as aroma chemicals; to the use thereof for modifying the scent character of a fragranced composition; to an aroma chemical composition containing an ether or an ester of a 1-substituted cycloalkanol or of mixtures of two or more ethers or esters of 1-substituted cycloalkanols or of a stereoisomer thereof or of a mixture of two or more stereoisomers thereof; and to a method of preparing a fragranced composition or for modifying the scent character of a fragranced composition. The invention further relates to specific ethers or esters of 1-substituted cycloalkanols.

Ethers and esters of 1-substituted cycloalkanols for use as aroma chemicals

The present invention relates to aroma chemical compositions containing 3,5-diethyl-2-propyl-tetrahydropyran, a 3,5-diethyl-2-propyl-dihydropyran or a 3,5-diethyl-2-propyl-pyran, a mixture of such compounds, a stereoisomer of one of these compounds, or a mixture of stereoisomers of one or more of these compounds. The invention further relates to a method for preparing such compounds, stereoisomers or mixtures thereof, to the composition obtainable by this method, to the use of such compounds as an aroma chemical or for modifying the scent character of a fragranced composition; and to a method for preparing a fragranced composition or for modifying the scent character of a fragranced composition using said compounds. Moreover, the invention relates to 3,5-diethyl-2-propyl-tetrahydropyran, to its stereoisomers and to mixtures of these stereoisomers.

Aroma chemical compositions containing 3,5-diethyl-2-propyl-tetrahydropyran and/or unsaturated derivatives thereof

The present invention relates to the use of an &#x3b1;,&#x3b1;-disubstituted carboxylic acid ester of the general formula (I) wherein the variables are as defined in the claims and the description, or of mixtures of two or more of these &#x3b1;,&#x3b1;-disubstituted carboxylic acid esters or of a stereoisomer thereof or of a mixture of two or more stereoisomers thereof as aroma chemicals; to the use thereof for modifying the scent character of a fragranced composition; to an aroma chemical composition containing an &#x3b1;,&#x3b1;-disubstituted carboxylic acid ester of the general formula (I) or a mixture of two or more of said &#x3b1;,&#x3b1;-disubstituted carboxylic acid esters or of a stereoisomer thereof or of a mixture of two or more stereoisomers thereof; and to a method of preparing a fragranced composition or for modifying the scent character of a fragranced composition. The invention further relates to specific mixtures of &#x3b1;,&#x3b1;-disubstituted carboxylic acid esters of the general formula (I). 

&#x3b1;, &#x3b1;-disubstituted carboxylic acid esters for use as aroma chemicals

The present invention relates to dodeca-4,8,11-trien-1-ol and a method of preparing same, to the use of dodeca-4,8,11-trien-1-ol as aroma chemical; to the use of dodeca-4,8,11-trien-1-ol for preparing an aroma chemical composition or for modifying the aroma character of an aroma chemical composition; to an aroma chemical composition containing dodeca-4,8,11-trien-1-ol; and to a method of preparing an aromatized composition or for modifying the aroma character of an aromatized composition.

Dodeca-4,8,11-trien-1-ol and its use as aroma chemical

The present invention relates to a process for recovering 3-methylbut-3-en-1-ol from a feed stream F1 comprising 3-methylbut-3-en-1-ol, one or more solvents, water, and isobutene, wherein 3-methylbut-3-en-1-ol, the one or more solvents and water are separated from isobutene by distillation, the process comprising subjecting the feed stream F1 to distillation conditions in a distillation unit, obtaining a bottoms stream B1 which is enriched in -methylbut-3-en-1-ol, in the one or more solvents and in water compared to the feed stream F1 subject The present invention relates to a process for recovering 3-methylbut-3-en-1-ol from a feed stream F1 comprising 3-methylbut-3-en-1-ol, one or more solvents, water, and isobutene, wherein 3-methylbut-3-en-1-ol, the one or more solvents and water are separated from isobutene by distillation, the process comprising subjecting the feed stream F1 to distillation conditions in a distillation unit, obtaining a bottoms stream B1 which is enriched in -methylbut-3-en-1-ol, in the one or more solvents and in water compared to the feed stream F1 subjected to distillation conditions, and a top stream T1 which is enriched in isobutene, further subjecting the bottoms stream B1 to distillation conditions in a second distillation unit and obtaining a bottoms stream B2 which is enriched in 3-methylbut-3-en-1-ol compared to the bottoms stream B1 and a top stream T2 which is enriched in water compared to the bottoms stream B1, further subjecting the bottoms stream B2 to distillation conditions in a third distillation unit and obtaining a top stream T3 which is enriched in 3-methylbut-3-en-1-ol compared to the bottoms stream B2 and a bottoms stream B3. ted to distillation conditions, and a top stream T1 which is enriched in isobutene, further subjecting the bottoms stream B1 to distillation conditions in a second distillation unit and obtaining a bottoms stream B2 which is enriched in 3-methylbut-3-en-1-ol compared to the bottoms stream B1 and a top stream T2 which is enriched in water compared to the bottoms stream B1, further subjecting the bottoms stream B2 to distillation conditions in a third distillation unit and obtaining a top stream T3 which is enriched in 3-methylbut-3-en-1-ol compared to the bottoms stream B2 and a bottoms stream B3.

Process for recovering 3-methylbut-3-en-1-ol

The present invention relates to a method for preparing 14-methyl-16-oxabicyclo-[10.3.1]pentadecenesin a two-step synthesis from 3-methyl-1,5-cyclopentadecane-dione as starting material.

Preparation of 14-methyl-16-oxabicyclo[10.3.1]pentadecenes from 3-methyl-1,5-cyclopentadecanedione

The present invention relates to a process for preparing an unsaturated alcohol, preferably 3,7-dimethyl-2,6-octadienal, by contacting an alkene, preferably isobutene, with formaldehyde in the presence a condensation catalyst comprising a zeolitic material comprising the framework structure of which comprises a tetravalent element Y other than Si.

Process for preparing an unsaturated alcohol

The present invention relates to a method for preparing compounds having a 16-oxabicyclo[10.3.1]pentadecene skeleton, specifically 14-methyl-16-oxabicyclo[10.3.1]pentadecenes, and conversion products thereof.

Method for the preparation of compounds having a 16-oxabicyclo[10.3.1]pentadecene scaffold and the subsequent products thereof

The present invention relates to a process for preparing 3-methylcyclopentadecane-1,5-diol (I) by hydrogenolysis of 14-methyl-16,17,18-trioxatricyclo[10.3.2.1]octadecane (II). The invention further relates to a process for preparing 3-methylcyclopentadecane-1,5-diol is a macrocyclic diol that can serve as precursor for a macrocyclic odorant, such as muscone and muscenone.

Process for preparing 3-methylcyclopentadecane-1,5-diol

The present invention relates to a process for producing 3-methylcyclopentadecane-1,5-dione of formula (I), which comprises the oxidation of 14-methyl-bicyclo[10.3.0]pentadecen[1 (12)] of formula (II) with an oxidizing agent, where the oxidation is performed by using a mixture of formic acid with HOas sole oxidizing agent in the presence of water and where the amount of HOis at least 1.1 mol HOper mol of the compound of formula (II). 

Process for preparing 3-methylcyclopentadecane-1,5-dione

The present invention relates to a process for preparing a macrocyclic diketone compound of the formula (I), which comprises the oxidation of a bicycloolefine compound of the formula (II) with an oxidizing agent, formulae (I) (II) where in formulae (I) and (II) A is (CH)with n being an integer from 2 to 12, where two hydrogen atoms may be replaced by C-C-alkyl, in particular methyl, or two hydrogen atoms, which are bound to adjacent carbon atoms may be replaced by a fused 5- or 6-membered saturated carbocycle; B is (CH)with m being 1 or 2, where 1 or 2 hydrogen atoms may be replaced by C-C-alkyl, in particular methyl. 

Process for preparing a macrocyclic diketone

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Heidelberg, Germany

Miriam Bru Roig