Massachusetts Institute of Technology

Automobili Lamborghini S.p.a.

Mircea Dinca

Casey R Wade

Michael Glenn Campbell

Lei Sun

Dennis Sheberla

Constanze Neumann

Yuri Tulchinsky

Adam J Rieth

Jinhu Dou

Yuriy Román-Leshkov

Harish Banda

Ivo Stassen

Riccardo Parenti

Hoyoung Park

Eric D Metzger

Carl K Brozek

Robert J Comito

Minyuan Li

Michal Borysiewicz

Compositions and methods of use related to metal organic frameworks (MOFs) and/or nanoparticles are generally described. In some embodiments, methods and compositions for the catalytic upgrading of alcohols using MOFs and/or nanoparticles associated with MOFs are generally described. In some embodiments, a catalytic MOF composition is provided, wherein the MOF composition comprises a MOF compound and a plurality of metal catalytic compounds. In some embodiments, an alcohol may be exposed to the MOF composition and/or a plurality of nanoparticles associated with the MOF composition such that the alcohol is converted to a higher order alcohol. Advantageously, in some embodiments, the alcohol conversion occurs at a relatively high turnover frequency and/or with a relatively high selectivity as compared to traditional methods for converting alcohols.

Methods and compositions for the catalytic upgrading of alcohols

Methods of sensing carbon dioxide, sensors, and related articles and systems are generally described.

Compositions and methods for carbon dioxide sensing

Compositions and methods comprising metal organic frameworks (MOFs) and related uses are generally provided. In some embodiments, a MOF comprises a plurality of metal ions, each coordinated with at least one ligand comprising at least two sets of ortho-diimine groups arranged about an organic core.

Compositions and methods comprising conductive metal organic frameworks and uses thereof

Metal-organic frameworks, supercapacitor electrodes, and supercapacitors are generally provided. Some metal-organic frameworks described herein may be suitable for use in supercapacitor electrodes, some supercapacitor electrodes described herein may comprise a metal-organic framework described herein, and some supercapacitors described herein may comprise the supercapacitor electrodes described herein.

Metal-organic frameworks for supercapacitor electrodes

Compositions comprising metal organic frameworks and related methods and uses are generally provided, including use in selective carbonylation of heterocyclic compounds.

Compositions and methods for selective carbonylation of heterocyclic compounds

Compositions and methods for adsorption of a species (e.g., ammonia, water, a halogen) comprising metal organic frameworks (MOFs) are generally provided. In some embodiments, a MOF comprises a plurality of metal ions, each coordinated with at least one ligand comprising at least two unsaturated N-heterocyclic aromatic groups arranged about an organic core.

Compositions comprising metal organic frameworks for the uptake of compounds and related methods

Compositions and methods for selective olefin (e.g., ethylene) oligomerization comprising metal organic frameworks (MOFs) are generally provided In some embodiments, a MOF comprises a plurality of metal ions, each coordinated with at least one ligand comprising at least two unsaturated N-heterocyclic aromatic groups arranged about an organic core.

Compositions and methods for selective olefin oligomerization comprising metal organic frameworks

Compositions and methods for selective olefin (e.g., ethylene) polymerization comprising metal organic frameworks (MOFs) are generally provided. In some embodiments, a MOF comprises a plurality of metal ions, each coordinated with at least one ligand comprising at least two unsaturated N-heterocyclic aromatic groups arranged about an organic core.

Compositions and methods for olefin polymerization comprising metal organic frameworks

Compositions and methods comprising metal organic frameworks (MOFs) and related uses are generally provided. In some embodiments, an MOF comprises a plurality of metal ions, each coordinated with at least one ligand comprising at least two unsaturated N-heterocyclic aromatic groups arranged about an organic core. In some embodiments, an MOF may be used in applications related to water adsorption.

Compositions and methods comprising porous metal organic frameworks and related uses

Embodiments of the invention relate to a method for preparing crystalline metal-organic frameworks (MOFs). The method includes the steps of providing an electrolyte solution in contact with a conductive surface, and applying a current or potential to the conductive surface in contact with the electrolyte solution. The electrolyte solution includes a protonated organic ligand, a metal ion, and a probase. Application of the reductive current or potential to the conductive surface produces the crystalline metal-organic framework (MOF) deposited on the conductive surface. The MOFs produced by the method may be incorporated into a gas separation membrane, a purification filter, and/or a sensor.

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Belmont, MA, United States of America

Mircea Dinca