Okura Kogyo Kabushiki Kaisha

Okura Industrial Co., Ltd.

Minoru Ueda

Hideaki Matsuda

Koichi Murakami

Hideki Mori

Yutaka Matsumoto

Masanori Hara

Yuki Yamaguchi

A raw material composition for an extrusion moldable polyolefin resin composition including (a) a polypropylene resin, (b) a polyethylene resin, (c) an esterified cellulose material obtained by esterifying a cellulose material with a polybasic acid anhydride and having a content of the polybasic acid anhydride bonded thereto of 0.5-20% based on the weight of the cellulose material, and (d) an organic peroxide compound, wherein the weight ratio of (a) to (b) ranges from 30:70 to 80:20, wherein the weight ratio of a total of (a)&plus;(b) to (c) ranges from 30:70 to 70:30, and wherein (d) is present in an amount of 0.001 to 0.1% based on a total weight of (a)&plus;(b)&plus;(c). By kneading the raw material composition at 150-200&deg; C. for 0.5 to 30 minutes, a polyolefin composition for extrusion molding is obtained.

Polyolefin resin composition for extrusion molding and raw material composition therefor

The invention relates to a process of producing a surface hardened woody decorative sheet by reacting a cellulose material such as a wood flour, a wood chip, a chaff, etc., with a dibasic acid anhydride and a monoepoxy compound having a polymerizable double bond to form a setting composition mainly composed of an oligoesterified cellulose material having a polymerizable double bond and an oligomer having a polymerizable double bond, placing in layer the setting composition on a woody sheet, and hot-pressing them to integrate the setting composition and the woody sheet in a body.

Process of producing surface hardened woody decorative sheets

An industrially advantageous woody molding is produced by adding a dibasic acid anhydride to a woody material such as a wood meal in the presence or absence of a catalyst such as sodium carbonate, whereby the dibasic acid anhydride is bonded to the hydroxy group of the woody material to form an esterified woody material, adding thereto a compound having at least two epoxy groups in the molecule thereof, kneading well the mixture, and then heat and press molding the kneaded mixture at a temperature higher than 120.degree. C. and a pressure greater than 60 kg/cm.sup.2. The product thus obtained by the process of this invention has a smooth and lustrous surface, has good water resistance and dimensional stability, and also is excellent in mechanical strength and hardness.

Process for producing woody moldings

The process for producing a plastic-like cured woody molding, which comprises applying a pressure necessary for plasticizing at least a woody component at temperature of from 120.degree. C. to 180.degree. C. to a composition comprising (A) an oligoesterified woody material obtained by alternately adding a polybasic acid anhydride and a monoepoxy compound having unsaturated double bond to the hydroxy groups of a woody material and (B) an oligomer obtained from a polybasic acid anhydride and a monoepoxy compound having unsaturated double bond with the addition of (C) a radical polymerization initiator to simultaneously perform the plasticization and crosslinking by the polymerization of the unsaturated double bonds. The plastic-like cured woody moldings thus obtained have dense and glossy surfaces and are particularly excellent in dimensional stability, mechanical properties and heat distortion temperature.

Process for producing plastic-like woody moldings from dibasic acid

A process of producing modified wood by impregnating dried wood with a mixed solution composed of phthalic anhydride as a polybasic acid anhydride and epichlorohydrin as an epoxy compound at a mol ratio of 1:1 to 1:30 by dipping the wood in the mixed solution, withdrawing the impregnated wood from the mixed solution, and heating the wood to a temperature of from 60.degree. C. to 180.degree. C. to simultaneously adding phthalic anhydride and epichlorohydrin to the hydroxyl groups of the wood. By the process of this invention, excellent dimensional stability and weather resistance can be imparted to the wood while retaining the properties specific to the wood.

Growing community of inventors

Kagawa, Japan

Minoru Ueda