Research Institute of Petroleum Processing, Sinopec

China Petroleum Chemical Corporation

China Petrochemical Corporation

Mingfeng Li

Hong Nie

Runqiang Zhang

Guofu Xia

Yahua Shi

Dadong Li

Yichao Mao

Xiangyun Long

Jian Li

Haitao Huang

Yang Zhao

Le Zhang

Enze Min

Zhihai Hu

Qinghe Yang

Mei Zhu

Zhiping Tao

Guangle Zhao

Guopeng Ran

Yunjian Hu

Zhiqiang Wang

Hongwei Li

Jie Gao

Pengfei Wang

Wenbin Chen

Yang Chu

Xiaoli Wei

Xuefen Liu

Huifeng Li

Yulin Shi

Liang Zou

Honghui Li

Qinghe Liu

Qingzhou Guo

Wenxiu Fang

Luqiang Wang

Hongbao Li

Guici Pang

Shi Ding

Zhishan Wang

Shuqing Wang

Jili Hou

Run Xu

Yuanbing Xi

Xueyan Ju

Yunfei Bi

Weiguo Huang

A method and system for pretreating waste plastics and a method and system for producing an automotive fuel from waste plastics are provided. The method for pretreating waste plastics includes the steps of: 1) contacting a waste plastic with a pretreating agent and a solvent oil for impurity removal; and 2) subjecting the effluent from step 1) to solid-liquid separation to obtain an insoluble material and an impurity-removed plastic-containing solution. The impurity-removed plastic-containing solution obtained by the method and system for pretreating waste plastics has very low metal content, chlorine content and silicon content.

Method and system for treating waste plastic material

Disclosed are a phosphorus-containing high-silica molecular sieve, its preparation and application thereof, wherein the molecular sieve comprises about 86.5-99.8 wt % of silicon, about 0.1-13.5 wt % of aluminum and about 0.01-6 wt % of phosphorus, calculated as oxides and based on the dry weight of the molecular sieve, the molecular sieve has an XRD pattern with at least three diffraction peaks, the first strong peak is present at a diffraction angle of about 5.9-6.9°, the second strong peak is present at a diffraction angle of about 10.0-11.0°, and the third strong peak is present at a diffraction angle of about 15.6-16.7°. The phosphorus-containing high-silica molecular sieve shows an improved hydrocracking activity in the presence of nitrogen-containing species when used in the preparation of hydrocracking catalysts.

Phosphorus-containing high-silica molecular sieve, its preparation and application thereof

A molecular sieve has a silica/alumina molar ratio of 100-300, and has a mesopore structure. One closed hysteresis loop appears in the range of P/P=0.4-0.99 in the low temperature nitrogen gas adsorption-desorption curve, and the starting location of the closed hysteresis loop is in the range of P/P=0.4-0.7. The catalyst formed from the molecular sieve as a solid acid not only has a good capacity of isomerization to reduce the freezing point, but also can produce a high yield of the product with a lower pour point. The process for preparing the catalyst involves steps including crystallization, filtration, calcination, and hydrothermal treatment.

Molecular sieve having mesopores, preparation method therefor, and application thereof

A phosphorus-containing molecular sieve has a phosphorus content of about 0.3-5 wt %, a pore volume of about 0.2-0.95 ml/g, and a ratio of B acid content to L acid content of about 2-10. The molecular sieve has a specific combination of characteristics, including a high ratio of B acid content to L acid content, thereby exhibiting higher hydrocracking activity and ring-opening selectivity when used in the preparation of a hydrocracking catalyst.

Phosphorus-containing molecular sieve, its preparation and application thereof

Disclosed is a hydrofining catalyst comprising: an inorganic refractory component comprising a first hydrodesulfurization catalytically active component in a mixture with at least one oxide selected from the group consisting of alumina, silica, magnesia, calcium oxide, zirconia and titania; a second hydrodesulfurization catalytically active component; and an organic component comprising a carboxylic acid and optionally an alcohol. The hydrofining catalyst of the present application shows improved performance in the hydrofining of distillate oils. Also disclosed are a hydrofining catalyst system comprising the hydrofining catalyst, a method for preparing the catalyst and catalyst system, and a process for the hydrofining of distillate oils using the catalyst or catalyst system.

Hydrofining catalyst, its preparation and application thereof

The present application relates to a hydrogenation catalyst, a process for producing the same and application thereof in the hydrotreatment of feedstock oil. The process comprises at least the following steps: (1) contacting a first active metal component and a first organic complexing agent with a carrier to obtain a composite carrier; (2) calcining the composite carrier to obtain a calcined composite carrier having a total carbon content of 1% by weight or less; and (3) contacting a second organic complexing agent with the calcined composite carrier to obtain the hydrogenation catalyst. The hydrogenation catalyst has both excellent hydrodesulfurization activity and hydrodenitrogenation activity, and exhibits a significantly prolonged service life.

Hydrogenation catalyst, its production and application thereof

A hydrocracking catalyst comprises a support, at least one of VIII Group metal components, and at least one of VIB Group metal components. The support comprises an acidic silica-alumina component and alumina derived from a pseudo-boehmite component, wherein the content of the acidic silica-alumina component is 3-80 wt %, the content of alumina derived from the pseudo-boehmite component is 20-95 wt %, based on the support. The support is obtained by mixing, molding, drying and calcining the acidic silica-alumina component with the pseudo-boehmite component, wherein said pseudo-boehmite component comprises pseudo-boehmite PB1 and pseudo-boehmite PB2, wherein the content of PB1 is 10-90 wt % and the content of PB2 is 0-60 wt % on a dry basis and based on the support.

Hydrocracking catalyst and use of the same

A catalyst for the selective hydrogenation of olefins especially dienes, its preparation and use, said catalyst comprising an alumina support and cobalt and/or nickel selected from Group VIII, molybdenum and/or tungsten from Group VIB and alkali metal components supported on said support, characterized in that the catalyst contains 0.5-8% by weight of cobalt and/or nickel selected from Group VIII, 2-15% by weight of molybdenum and/or tungsten from Group VIB, over 2-8% by weight of alkali metals, and a balanced amount of alumina support calculated for oxides and based on the catalyst. Compared to the prior catalysts, the activity and selectivity for olefins especially dienes of the catalyst are higher when used in the hydrogenation of a gasoline distillate.

Catalyst for selective hydrogenation of olefins and its preparation as well as use

Disclosed is a process for reducing sulfur and olefin contents in gasoline, comprising contacting gasoline feedstock and hydrogen with a hydrorefining catalyst and an paraffin-modification catalyst. The effluent of the process is separated to obtain a hydrotreated gasoline fraction free of mercaptan and having a low content of sulfur, e.g. less than 200 ppm, a low content of olefins, e.g. less than 20% by volume, and little octane loss. The hydrotreated gasoline fraction can be used as blending component of a final gasoline product.

Process for reducing sulfur and olefin contents in gasoline

A conversion process of hydrocarbon oils comprises at least a hydrodemercaptanization process, wherein said hydrodemercaptanization process comprises contacting a feedstock with a hydrofining catalyst containing a tungsten oxide and/or a molybdenum oxide, a nickel oxide and a cobalt oxide supported on an alumina under the conditions of hydrodemercaptanization, in which the content of said tungsten oxide and/or molybdenum oxide is from 4 wt % to less than 10 wt %, the nickel oxide content is 1-5 wt %, the cobalt oxide content is 0.01-1 wt % based on the catalyst, and the ratio of total atom number of nickel and cobalt to total atom number of nickel, cobalt, tungsten and/or molybdenum is 0.3-0.9. Said process can be carried out at a lower temperature and a lower H/oil volume ratio.

Conversion process of hydrocarbon oils

A hydrotreating catalyst containing molybdenum and/or tungsten for light oil distillates, said catalyst contains tungsten oxide and/or moybdenum oxide, nickel oxide and cobalt oxide supported on an alumina carrier, the content of said tungsten oxide and/or molybdenum oxide is from 4 wt % to less than 10 wt %, the content of nickel oxide 1.about.5 wt %, the content of cobalt oxide 0.01.about.1 wt %, the atom ratio of nickel-cobalt to nickel, cobalt-tungsten and/or molybdenum is 0.3.about.0.9. Compared with the prior art, the catalyst has lower metal content, but higher activity at low-temperature. The catalyst is especially suitable for use in the hydrodemercaptanization process of light oil distillates.

Catalyst containing molybdenum and/or tungsten for hydrotreating light

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Beijing, China

Mingfeng Li