Intematix Corporation

Kabushiki Kaisha Toshiba

Mina Farag

Yi-Qun Li

Shinji Aoki

Tsuyoshi Kobayashi

Yoshihiko Nakano

Wu Mei

Taishi Fukazawa

Itsuko Mizutani

Chris Bajorek

A membrane electrode assembly for a solid electrolyte fuel cell comprises: an electrode having a layer of nano-structured material on one of its faces, an electrocatalyst deposited on the nano-structured material and an electrolyte deposited on the electrocatalyst/nano-structured material. The nano-structured material can comprise carbon, silicon, graphite, boron, titanium and be in the form of multi-walled nano-tubes (MWNTs), single-walled nano-tubes (SWNTs), nano-fibers, nano-rods or a combination thereof. The nano-structured material can be grown or deposited on one face of an electrode of the cell or on a substrate such as a flexible sheet material of carbon fibers using chemical vapor deposition. The electrocatalyst and electrolyte can be incorporated in the nano structured material using physical vapor deposition (PVD), ion beam sputtering or molecular beam epitaxy (MBE).

Solid electrolyte fuel cell comprising an electrocatalyst/electrolyte assembly supported by a nano-structured material

A methanol oxidation catalyst comprises a material of composition:PtMTain which Pt is platinum, Ta is tantalum, M is an element includes at least one selected from the group consisting of V (vanadium), W (tungsten), Ni (nickel) and Mo (molybdenum), x is 40 to 98 at. %, z is 1.5 to 55 at. %, and u is 0.5 to 40 at. %. To maximize catalytic activity the material is preferably in the form of nanoparticles. The values of x, z and u are selected such that the element exhibits X-ray photoelectron spectroscopy peaks derived from an oxygen bond and a metal bond in which a peak area derived from the oxygen bond is twice or less of a peak area derived from the metal bond.

Methanol oxidation catalyst

A methanol oxidation catalyst is provided, which includes nanoparticles having a composition represented by the following formula 1:PtRuTQ&#x2003;&#x2003;formula 1 In the formula 1, the T-element is at least one selected from a group consisting of Mo, W and V and the Q-element is at least one selected from a group consisting of Nb, Cr, Zr and Ti, x is 40 to 90 at. %, y is 0 to 9.9 at. %, z is 3 to 70 at. % and u is 0.5 to 40 at. %. The area of the peak derived from oxygen bond of T-element is 80% or less of the area of the peak derived from metal bond of T-element in a spectrum measured by an X-ray photoelectron spectral method.

A methanol oxidation catalyst is provided, which includes nanoparticles having a composition represented by the following formula (1):PtRuMoT&#x2003;&#x2003;(1) In the formula (1), the T-element is at least one selected from the group consisting of W and V, x is 20 to 80 at. %, y is 10 to 60 at. %, z is 1 to 30 at. % and u is 1 to 30 at. %. The area of the peak derived from oxygen bond of T-element is 80% or less of the area of the peak derived from metal bond of T-element in a spectrum measured by an X-ray photoelectron spectral method.

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Fremont, CA, United States of America

Mina Farag