Btr New Material Group Co., Ltd.

Shenzhen Btr New Energy Materials Inc.

Yanyi New Energy Technology Co., Ltd.

Shenzhen Brt New Energy Materials Inc.

Shenzhen Yanyi New Materials Co., Ltd.

Min Yue

Jianguo Ren

Youyuan Huang

Chunlei Pang

Peng He

Xueqin He

Zhiqiang Deng

Lijuan Qu

Haihui Zhou

Dongdong Li

Eming Guo

Tengyu Liang

Jun Liu

Sheng Li

Yan Liang

Bo Liu

Lin Cheng

Kai Yang

Chao Qian

Jingwei Wang

Chengkun Zhou

Shunyi Yang

Dexin Yu

Xingyang Liu

Miaomiao Li

Shi-Qi Zhang

Huiqing Yan

Xiao-Fei Zhang

Minghua Deng

Wei-Jing Feng

Xiujun Pan

A negative electrode material includes a composite matrix material and a carbon coating coated on the composite matrix material. The composite matrix material includes lithium silicate, silicon oxide, an activator, and silicon embedded in the lithium silicate and the silicon oxide.

Negative electrode material, and preparation method therefor and use thereof

Provided are a preparation method of a long-cycle modified graphite-based composite material and a lithium ion battery containing the material. The method including: (1) mixing a graphite material and a coating modifier; (2) placing the mixture into a self-pressurized reaction device, then placing the device in a heating apparatus to perform a self-pressurized impregnation experiment, during which temperature is controlled to increase in such a manner that the coating modifier is gradually liquefied after reaching a softening point, to completely impregnate the graphite material under self-pressurizing and to be distributed on a surface of the graphite material; (3) cooling; and (4) performing a heat treatment in an inert atmosphere to obtain the modified graphite-based composite material.

Preparation method for long-cycle modified graphite-based composite material and lithium ion battery comprising the material

A preparation method obtains silicon oxide/carbon composite negative electrode material and a lithium-ion battery. The silicon oxide/carbon composite negative electrode material is a secondary particle, and mainly consists of a SiOx/C material. The SiOx/C material includes SiOx particles and a carbon layer with which the surfaces of the SiOx particles are coated. The SiOx particles include Si crystallites. The preparation method includes: 1) synthesizing a silicon oxide bulk; 2) performing crushing to obtain micro-level or nano-level SiOx particles; 3) mixing with a carbon binder; 4) granulating; 5) modification and carbonization; and 6) post-processing.

Silicon oxide/carbon composite negative electrode material and preparation method therefor, and lithium-ion battery

The present invention relates to a method and device for preparing an ultrathin metal lithium foil. With regard to the problems of lithium preparation processes in the prior art having a high lithium preparation reaction temperature, a low lithium recovery rate, low purity in collected lithium foils, a complicated process operation, etc., the present invention provides a method for preparing an ultrathin metal lithium foil, wherein firstly, a complex lithium salt is prepared, the complex lithium salt and a reducing agent are then subjected to a vacuum thermal reduction reaction so as to generate a metal vapor, the metal vapor is then subjected to vacuum distillation, and finally, vacuum evaporation is used to prepare the ultrathin metal lithium foil of the present invention. In the present invention, by precisely regulating and controlling conditions such as the formulation of the complex lithium salt, the thermal reduction reaction temperature, the temperature of a distillation device, the vacuum degree, materials and the reducing agent, vacuum reduction, vacuum distillation and vacuum evaporation are continuously performed, and lithium preparation, distillation purification, and evaporation can thus be continuously performed, thereby improving the efficiency of the production of the ultrathin metal lithium foil and saving on preparation costs.

Method and device for preparing ultrathin metal lithium foil

Provided is a negative electrode material of a lithium ion secondary battery. The negative electrode material includes a carbon coating layer and a core layer. The core layer includes lithium polysilicate and silicon oxide, and silicon is uniformly embedded in the lithium polysilicate and/or in the silicon oxide. The negative electrode material has high first coulomb efficiency, long cycle performance, excellent rate performance and high safety.

Negative electrode material of lithium ion secondary battery, preparation method thereof and use thereof

Disclosed are a lithium ion battery negative electrode material and a preparation method therefor. The negative electrode material comprises SiO(0.2<y<0.9) and an M compound, wherein M is a metal. The method of the present application comprises: subjecting a raw material comprising a SiOmaterial and the metal M to a redox reaction, wherein the O/Si ratio, i.e. x, of the SiO(0.5<x<1.5) material is adjusted to y (0.2<y<0.9), and at the same time, the metal M is oxidized to obtain the M compound.

Lithium ion battery negative electrode material and preparation method therefor

Disclosed in the present application is a compound, comprising nano silicon, a lithium-containing compound and a carbon coating, or comprising nano silicon, silicon oxide, a lithium-containing compound, and a carbon coating. The method comprises: (1) solid-phase mixing of carbon coated silicon oxide with a lithium source; and (2) preforming heat-treatment of the pre-lithium precursor obtained in step () in a vacuum or non-oxidising atmosphere to obtain a compound. The method is simple, and has low equipment requirements and low costs; the obtained compound has a stable structure and the structure and properties do not deteriorate during long-term storage, a battery made of cathode material containing said compound exhibits high delithiation capacity, high initial coulombic efficiency, and good recycling properties, the charging capacity is over 1920 mAh/g, the discharging capacity is over 1768 mAh/g, and the initial capacity is over 90.2%.

Compound, preparation method therefore, and use in lithium ion secondary battery

The present application provides a composite negative electrode material of a lithium ion battery, a preparation method thereof and the use thereof in a lithium ion battery. The composite negative electrode material includes a SiO-based active material and a polycarbonate coating layer coated on a surface of the SiO-based active material. The method includes: (1) preparing a monomer solution of unsaturated carbonate; (2) polymerizing the monomer in presence of a polymerization catalyst to obtain a polymer solution; and (3) adding a SiO-based active material, water and a polymer catalyst to the polymer solution, and further polymerizing to coat the SiO-based active material, to obtain the composite negative electrode material.

Composite negative electrode material for lithium ion battery, preparation method thereof, and use thereof in lithium ion battery

Disclosed is a composite silicon negative electrode material. The composite silicon negative electrode material comprises a nano silicon (), a nano composite layer () coated on the surface of the nano silicon, and a conductive carbon layer () uniformly coated outside the nano composite layer (). The nano composite layer () is a silicon oxide () and a metal alloy (). In the composite silicon negative electrode material with a three-layer structure, the nano composite layer (), composed of the silicon oxide () and the metal alloy () coated on the surface of the silicon oxide (), effectively reduces the volume expansion of the nano silicon (), maintains the characteristic of high conductivity of the silicon material, improves the mobility of lithium ions, prevents direct contact between a silicon negative electrode and an electrolyte, and can form a hard SEI film on the surface of the composite silicon negative electrode material, thereby allowing the cycle performance of the material to be greatly enhanced. The composite silicon negative electrode material has the characteristics of a high capacity, long cycle life and high conductivity. A preparation process for the silicon negative electrode material is simple, easily controllable, and suitable for industrial production.

Composite silicon negative electrode material, preparation method and use

A carbon matrix composite material, a preparation method therefor and a battery comprising the same. The carbon matrix composite material comprises micron-sized soft carbon, micron-sized hard carbon, a nano-active material, a first carbon coating layer and a second carbon coating layer, wherein the first carbon coating layer is coated on a surface of the nano-active material to form composite particles; the composite particles are dispersed on the surfaces of the soft carbon and the hard carbon, and in the second carbon coating layer; and the second carbon coating layer coats soft carbon, the hard carbon and the composite particles.

Carbon matrix composite material, preparation method therefor and lithium ion battery comprising same

A natural graphite-based modified composite material, a preparation method therefor, and a lithium ion battery comprising the modified composite material. The natural graphite-based modified composite material comprises natural graphite and non-graphitized carbon coated on the inner and outer surfaces of the natural graphite. The preparation method comprises: (1) subjecting spherical natural graphite to isotropic treatment; (2) performing granularity control and shaping treatment; (3) subjecting the inner surface and the outer surface of the material obtained in step (2) to simultaneous modification; and (4) performing carbonization, so as to obtain a natural graphite-based modified composite material.

Natural graphite-based modified composite material, preparation method therefor, and lithium ion battery comprising modified composite material

A silicon-based negative electrode material, a preparation method therefor and a use thereof in a lithium-ion battery. The silicon-based negative electrode material comprises a silicon-based active material and a composite layer that coats the surface of the silicon-based active material and composes a flexible polymer, flake graphite and a conductive material. The method comprises: 1) dissolving the flexible polymer in a solvent; 2) adding the flake graphite and the conductive material into the flexible polymer solution obtained in step 1) while stirring; 3) adding an anti-solvent to the mixed coating solution obtained in step 2) and stirring; 4) adding the silicon-based active material to the supersaturated mixed coating solution obtained in step 3) while stirring, and then stirring and separating; and 5) carrying out thermal treatment to obtain the silicon-based negative electrode material.

Silicon-based negative electrode material, preparation method therefor and use thereof in lithium-ion battery

An aqueous binder for a lithium ion battery, a preparation method and a use thereof. The binder is an inorganic-organic composite emulsion, comprising a dispersing agent, inorganic nanoparticles, (methyl)acrylate monomers, unsaturated carboxylic acid monomers, vinyl hydrocarbon monomers and optionally copolymers of other copolymerizable monomers, wherein the dispersing agent is a water-soluble cellulose grafted amphiphilic copolymer. When the water-soluble cellulose grafted amphiphilic copolymer is used as the dispersing agent, the agglomeration of the nanoparticles when the binder is formed into a film can be avoided, and at the same time, the effects of toughening and improving the binding strength can be achieved. Meanwhile, the water-soluble cellulose has certain strengthening and toughening properties so that the aqueous binder has an excellent anti-tensile performance. The aqueous binder for a lithium ion battery can be used for lithium ion batteries.

Aqueous binder for lithium ion battery, preparation method therefor and use thereof

The present invention discloses an equipment and process for preparing silicon oxides, and relates to the field of chemical equipments. Said equipment comprises at least one tank having opening(s) at at least one end thereof and comprising a reaction unit and a collection unit, wherein the reaction unit is used for placing raw materials therein; and the collection unit is used for placing a collector therein which is placed at the opening end of the tank; and the reaction unit is placed away from the opening end of the tank and placed inside a heating furnace; the collection unit and opening(s) are both placed outside the heating furnace; the tank is vacuumized via a port; and a tank lid is used for opening or closing the opening(s) of the tank. The preparation process uses such equipment. The present invention solves the problems of great energy consumption and low efficiency caused by the fact that the previous equipment and process for preparing silicon oxides are unable to achieve continuous production.

Equipment and process for preparing silicon oxides

A multiple-element composite material for negative electrodes, a preparation method therefor, and a lithium-ion battery using the negative electrode material. The lithium-ion battery uses multiple-element composite material for negative electrodes has a core-shell structure containing multiple shell layers. The inner core consists of graphite and nano-active matter coating the surface of the graphite. The outer layers of the inner core are in order: the first shell layer is of an electrically conductive carbon material, the second shell layer is of a nano-active matter, and the third shell layer is an electrically conductive carbon material coating layer. The multiple-element composite material for negative electrodes of the present invention combines coating processing technology with surface composite modification and coating modification technology to successfully prepare a multiple-element composite material for negative electrodes having a core-shell structure containing multiple shell layers, and allows for high load and high dispersion for the nano-active matter, thereby substantially enhancing the material specific capacity, cycle performance, and initial efficiency. Additionally, the multiple-element composite material for negative electrodes of the present invention has high compacted density and good processing performance. The negative electrode material has simple preparation technique and low raw material cost, is environmentally friendly, and causes no pollution.

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Guangdong, China

Min Yue