Daelim Industrial Co., Ltd.

Dl Chemical Co., Ltd.

Min Sup Park

Myeong Seok Kim

Se Hyun Lee

Hyung Jae Seo

Kyong Ju Na

Kyoung Tae Min

Sang Uk Jung

Seung Bin Ryu

Jae Hoon Lee

Jin Wook Lee

Myoung Gi Cho

Seong Mu Oh

Disclosed is a modified polyisobutylene polymer for rubber compounding. The modified polyisobutylene polymer is prepared by reacting reactants including a polyisobutylene in which the main chain is isobutylene, an unsaturated dicarboxylic anhydride, and an amino group-containing silane compound. The modified polyisobutylene polymer includes a diamide structure. When the modified polyisobutylene polymer is used as an additive for rubber compounding, the processability of the rubber is increased, the dispersibility of fillers is significantly improved, and the effect of obtaining excellent grip performance and improved rolling resistance can be achieved.

Modified polyisobutylene polymer for rubber compounding and rubber composition including same

Disclosed is a polybutene derivative for rubber compounding. The polybutene derivative includes 30% to 98% by weight of polyisobutylene, 1% to 35% by weight of unsaturated dicarboxylic anhydride, and 1% to 50% by weight of at least one selected from among alkanolamines, amine-based compounds, and polyhydric alcohols. When the polybutene derivative is added as an additive for rubber, the polybutene derivative dramatically improves the dispersibility of a filler and improves both the grip performance and the rolling resistance at the same time.

Polybutene derivative for rubber compounding and rubber composition including same

The present invention relates to a modified polyisobutylene polymer for rubber compounding including polyisobutylene having isobutylene as a main chain, unsaturated dicarboxylic anhydride, and a silane compound, and more particularly, 20 to 80 wt % of polyisobutylene having isobutylene as a main chain, 1 to 20 wt % of unsaturated dicarboxylic anhydride, and 1 to 60 wt % of a silane compound. In particular, when the polyisobutylene polymer of the present invention is used as an additive for rubber, the dispersibility of a filler can be significantly increased and both grip performance and rolling resistance can be improved.

Modified polyisobutylene polymer for rubber compounding and rubber composition comprising same

A method for preparing polybutene by polymerization of a raw material of a carbon number 4 (C4) compounds having an isobutene amount of 50 to 75% by weight, is disclosed. The raw material of C4 compounds is selected from the group consisting of (a) C4 compound material obtained by adding high purity isobutene to C4 raffinate-1; (b) C4 compound material obtained by adding high amount isobutene mixture which is generated in an olefin conversion unit (OCU) process to C4 raffinate-1; (c) C4 compound material obtained by adding high purity to butane-butene oil (B-B oil); (d) C4 compound material obtained by adding high amount isobutene mixture which is generated in an olefin conversion unit (OCU) process to butane-butene oil (B-B oil); (e) C4 compound material obtained by adding a dilute solvent to high purity isobutene; (f) C4 compound material obtained by adding a dilute solvent to high amount isobutene mixture which is generated in an olefin conversion unit (OCU) process; (g) C4 compound material obtained by adding high purity isobutene to a mixture generated in dehydrogenation reaction that converts isobutane to isobutene; and (h) C4 compound material obtained by adding high amount isobutene mixture which is generated in an olefin conversion unit (OCU) process to a mixture generated in dehydrogenation reaction that converts isobutane to isobutene.

Method for producing highly reactive polybutene

A method for preparing polybutene includes the steps of: supplying a C4 mixture to an isomerization reactor in which (i) 1-butene is isomerized into 2-butene by a hydrogen isomerization reaction using an isomerization catalyst in an isomerization zone of the isomerization reactor and (ii) iso-butene and 2-butene are separated by fractional distillation in a fractional distillation zone; supplying a C4 mixture containing 2-butene which is separated in the isomerization reactor to a skeletal isomerization reactor, in which a part of normal-butene is skeletal isomerized into iso-butene by a skeletal isomerization reaction using a skeletal isomerization catalyst, and the obtained skeletal isomerization mixture is supplied and recycled to the isomerization reactor; and supplying (i) a raw material containing the iso-butene of high concentration and which is separated from the isomerization reactor and (ii) a polymerization catalyst to a polybutene polymerization reactor and thereby producing polybutene by a polymerization reaction.

Polybutene preparation method

There are disclosed an apparatus and a method for selectively preparing a high reactivity polybutene, a midrange reactivity polybutene and a non-reactive polybutene in a single plant. The apparatus for selectively preparing a reactive polybutene and a non-reactive polybutene, comprises: a reactive polybutene polymerization catalyst feeder for polymerization of the reactive polybutene; a non-reactive polybutene polymerization catalyst feeder for polymerization of the non-reactive polybutene; and a reactor for polymerizing a reactant including isobutene into polybutene, wherein the reactive polybutene polymerization catalyst feeder provides a catalyst to yield the reactive polybutene; and the non-reactive polybutene polymerization catalyst feeder provides a catalyst to yield the non-reactive polybutene.

Apparatus and method for selectively preparing reactive polybutene and nonreactive polybutene

Disclosed a method for preparing polybutene by using a catalyst including normal propanol, wherein the polybutene has 40 to 70% of vinylidene content and 10% or more of tetra-substituted double bond content by using a complex catalyst including normal propanol as a cocatalyst and a main catalyst such as boron trifluoride. The method comprises: introducing, to a raw reaction material including 10 wt % or more of isobutene, a complex catalyst including normal propanol as a cocatalyst and boron trifluoride as a main catalyst; and polymerizing the raw reaction material at a reaction temperature of &#x2212;33 to 33&#xb0; C. under a reaction pressure of 3 to 50 kg/cm, wherein the vinylidene content is adjusted by adjusting the reaction temperature.

Method for preparing polybutene by using catalyst containing N-propanol

A method for removing the fluorine component from waste water which is produced during the manufacturing process of highly reactive polybutene and contains high concentration of fluorine component, is disclosed. The method comprises a step of adding to the waste water a treating agent selected from a group of Al compound, Ca compound and mixture thereof at temperature of 50 to 300&#xb0; C. for reaction, whereby boron trifluoride neutralized salt is decomposed to form Al salt or Ca salt of fluorine component so that the fluorine component is removed in the form of the Al salt or the Ca salt of fluorine component.

Method for treating waste water containing fluorine component

Disclosed are an apparatus and method for preparing polybutene having various molecular weights by using complex catalysts of different molar ratios. The apparatus for preparing polybutene having various molecular weights, comprises: a complex catalyst preparing device for preparing a high-activity complex catalyst and a low-activity complex catalyst to form highly reactive polybutene through polymerization; a high-molar ratio complex catalyst system for controlling the storage and supply of the high-activity complex catalyst; a low-molar ratio complex catalyst system for controlling the storage and supply of the low-activity complex catalyst; and a reactor to which reaction raw materials including the high-activity complex catalyst, the low-activity complex catalyst, and isobutene are supplied to be polymerized into highly reactive polybutene.

Apparatus and method for preparing polybutene having various molecular weights

Disclosed are an apparatus and a method for removing halogens generated during the preparation of polybutene, which are capable of improving the utilization of polybutene and light polymers by removing halogen components contained in the polybutene and the light polymers. The method for removing halogens generated during the preparation of polybutene comprises the steps of: preparing a reaction product by supplying a catalyst and a reaction raw material to a reactor and polymerizing; removing a catalyst component from the reaction product and neutralizing; separating the reaction product into an organic compound and impurities comprising the catalyst component; heating the organic compound to distill an unreacted material; and removing a halogen component in a remaining polymerization mixture after the distillation using a halogen removing catalyst, or removing a halogen component in polybutene and light polymers obtained from the polymerization mixture using the halogen removing catalyst.

Apparatus and method for removing halogens generated during preparation of polybutene

Disclosed is a method for preparing a highly reactive polybutene of high quality having low fluorine content and high vinylidene content at high mileage of catalyst with economy. The method for preparing a polybutene includes: performing a selective hydrogenation reaction of diolefin among C4 hydrocarbon components produced from petroleum refineries or naphtha cracking centers, which involve cracking of crude oils, and simultaneously an isomerization reaction of 1-butene to 2-butene and then isolating an isobutene feedstock through fractional distillation; and polymerizing the isobutene feedstock obtained by the fractional distillation.

Method for preparing polybutene

Disclosed are a device and a method for continuously polymerizing polybutene by removing halogen acid, which is included in a reaction raw material, by adsorbing the halogen acid using an adsorbent and then re-supplying the reaction raw material into a reactor. The device for re-circulating the raw material when manufacturing polybutene comprises a reactor, into which a catalyst and a reaction raw material (diluted with an inactive organic solvent) are supplied and polymerized to produce a reaction product; a neutralizing/washing tank for removing the catalyst from the reaction product and neutralizing the reaction product; a separation tank for separating the reaction product into organic compounds and water; a C4 distillation column for distilling an unreacted raw material and the inactive organic solvent from the organic compounds; and an impurity adsorption column for removing halogen acid from the distilled unreacted raw material and the inactive organic solvent using an adsorbent.

Growing community of inventors

Daejeon, South Korea

Min Sup Park