P. R. Mallory Co.

Duracell Inc.

Milton Kallianidis

Gerhart P Klein

G Stephen Kelsey

Jesse R Rea

Dennis R Henderson

Paul J Christiansen

A completely solid state high temperature storage cell comprised of a solid rechargeable cathode such as TiS.sub.2, a solid electrolyte which remains solid at the high temperature operating conditions of the cell and which exhibits high ionic conductivity at such elevated temperatures such as an electrolyte comprised of lithium iodide, and a solid lithium or other alkali metal alloy anode (such as a lithium-silicon alloy) with 5-50% by weight of said anode being comprised of said solid electrolyte.

High temperature solid state storage cell

An intermediate precoat layer is provided for encapsulated electrical devices such as solid electrolyte tantalum capacitors. The intermediate precoat layer contains a resin material selected from the group of acrylic, styrene, cellulose acetate, polyvinyl chloride and certain epoxy type materials. The intermediate precoat layer of the present invention helps to stabilize electrical characteristics in the electrical devices such as reducing the DC leakage current in solid electrolyte tantalum capacitors after encapsulation by a protective layer.

Intermediate precoat layer of resin material for stabilizing

A protective layer containing polytetrafluoroethylene (PTFE) is provided over the riser of an anode having a porous film-forming metal anode body to render the riser non-wetting to a solution of manganese nitrate and thereby help prevent the formation of MnO.sub.2 on the riser during the subsequent pyrolysis step in the process of making a capacitor. The protective layer also helps to prevent mechanical damage to the anode during assembly of the capacitor. The protective layer over the anode riser may be applied by means such as dipping a wetted anode in a suspension containing particulate PTFE or by masking the anode body with a liquid and then spraying the riser with binderless material containing PTFE. The preferred embodiment employs high pressure spraying of the material containing PTFE over the anode riser.

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Brockton, MA, United States of America

Milton Kallianidis