Nec Corporation

University of Tsukuba

Midori Shimura

Masahiro Suguro

Daisuke Kawasaki

Kazuaki Matsumoto

Yoko Hashizume

Masatoshi Iji

Shukichi Tanaka

Kiyohiko Toyama

Kazuhiko Inoue

Toshie Miyamoto

Mina Shimizu

Kentaro Nakahara

Noriyuki Tamura

A paramylon-based resin having a weight-average molecular weight of paramylon in a range of 70000 to 140000, and formed by substituting hydrogen atoms of hydroxy groups of a paramylon with a long-chain component being a linear saturated aliphatic acyl group having 14 or more carbon atoms and a short-chain component being an acyl group (acetyl group or/and propionyl group) having 2 or 3 carbon atoms, wherein a degree of substitution with the long-chain component (DS) and a degree of substitution with the short-chain component (DS) satisfy the following conditional expressions (1) and (2), Izod impact strength is 5.0 kJ/mor more, and an MFR (melt flow rate at 210° C. and under a load of 5 kg) is 2 g/10 min or more. To provide a paramylon-based resin excellent in mechanical characteristics and thermoplasticity2.2≤≤2.8  (1)5≤≤25  (2).

Paramylon-based resin, molding material, molded body, and method for producing paramylon-based resin

A cellulose resin wherein a hydrogen atom of a hydroxy group of cellulose is substituted with a long-chain component which is a linear saturated aliphatic acyl group having 14 or more carbon atoms and a short-chain component which is an acyl group (propionyl group) having 3 carbon atoms, the degree of substitution with the long-chain component (DS) and the degree of substitution with the short-chain component (DS) satisfy the following conditional expressions (1) and (2):&#x2265;2.1&#x2003;&#x2003;(1)4&#x2264;&#x2264;12&#x2003;&#x2003;(2),the Izod impact strength is 5.0 kJ/mor more, and the MFR (melt flow rate at 200&#xb0; C. and under a load of 5 kg) is 10 g/10 min or more.

Cellulose resin, molding material, molded body, and method for producing cellulose resin

A cellulose resin composition comprising a cellulose derivative and a lubricant, wherein the cellulose derivative is an acylated cellulose obtained by substituting at least a part of hydrogen atoms of hydroxy groups of a cellulose with an acyl group having 2 to 4 carbon atoms, and the content of the lubricant is in the range of 0.1 to 10% by mass. A cellulose resin composition capable of forming a molded body having a high-quality appearance and scratch resistance is provided.

Cellulose resin composition, molded body and product using same

A cellulose resin composition comprising a cellulose derivative (A) and a lubricant (B), wherein the cellulose derivative (A) is a cellulose derivative obtained by substituting at least a part of hydrogen atoms of hydroxyl groups of a cellulose with a short-chain organic group having 2 to 4 carbon atoms and a long-chain organic group having 8 to 30 carbon atoms with specific degrees of substitution; the lubricant (B) is at least one selected from the group consisting of a urea compound (B1) having a urea group (&#x2014;NH&#x2014;C(&#x2550;O)&#x2014;NH&#x2014;) and an acyclic aliphatic group having 6 to 33 carbon atoms, an amide compound (B2) having an amide group (&#x2014;C(&#x2550;O)&#x2014;NH&#x2014;) and an acyclic aliphatic group having 6 to 33 carbon atoms, a fatty acid metal salt (B3), and a silicone-based lubricant (B4); and a content of the lubricant (B) is in a range of 0.1 to 10% by mass. A cellulose resin composition capable of forming a molded body having a high-quality appearance and scratch resistance is provided.

Cellulose resin composition, molded body and product using same, and a method for producing cellulose resin composition

A cellulose derivative obtained by substituting at least part of hydrogen atoms of hydroxy groups of a cellulose with an acyl group having 2 to 4 carbon atoms, a long-chain organic group having 7 or more carbon atoms and a high refractive-index organic group.

Cellulose derivative, cellulose resin composition, molded body and product using same

To provide a cellulose derivative excellent in thermoplasticity, water resistance and strength (elastic modulus, impact strength), a cellulose derivative, which is obtained by introducing a short-chain organic group (acetyl group), a medium-chain organic group having 3 to 5 carbon atoms and a long-chain organic group having 6 to 30 carbon atoms at the following substitution degrees DSs into a cellulose, is used: Short-chain organic group: 0.7&#x2264;DS&#x2264;1.5; Medium-chain organic group: 0.5&#x2264;DS&#x2264;2.0; Long-chain organic group: 0.1&#x2264;DS&#x3c;0.5; and 2.4&#x2264;DS+DS+DS&#x2264;3.

Cellulose derivative and use thereof

A cellulose resin formed by substituting hydrogen atoms of hydroxy groups of a cellulose with a long-chain component being a linear saturated aliphatic acyl group having 14 or more carbon atoms and a short-chain component being an acyl group having 2 or 3 carbon atoms, in which a degree of substitution with the long-chain component (DS) and a degree of substitution with the short-chain component (DS) satisfy conditional expressions (1) and (2) shown below:DS+DS&#x2265;2.1&#x2003;&#x2003;(1)4&#x2264;DS/DS&#x2264;12&#x2003;&#x2003;(2).

Cellulose resin, material for molding, molded body and process for producing cellulose resin

The present invention relates to a negative electrode for a lithium ion secondary battery comprising an oxetane compound represented by a predetermined formula in an amount within a range of 0.001% by mass or more and 5.0% by mass or less based on the amount of a negative electrode active material, and a lithium ion secondary battery using the same.

Negative electrode for secondary battery, method for manufacturing same, and secondary battery using same

An exemplary embodiment of the present invention is a secondary battery which comprises a negative electrode and a battery electrolyte liquid comprising a supporting salt and a non-aqueous electrolyte solvent; wherein the negative electrode is obtained by pre-forming a SEI coating film on a negative electrode structure which is formed by binding a negative electrode active substance comprising a metal (a). that can be alloyed with lithium, a metal oxide (b) that can absorb and desorb lithium ion and a carbon material (c) that can absorb and desorb lithium ion, to a negative electrode current collector with a negative electrode binder, and wherein the non-aqueous electrolyte solvent contains at least an ionic liquid.

Secondary battery and method for manufacturing same

An object of the present invention is to provide a high-capacity, long-life lithium secondary cell suppressing a reduction in capacity particularly with respect to use under a high-temperature environment, and having improved cycle properties. The lithium secondary cell comprises a positive electrode active material layer containing a positive electrode active material, a negative electrode active material layer containing a silicon-based material as a negative electrode active material, and an electrolytic solution in which the positive electrode active material layer and the negative electrode active material layer are immersed, the electrolytic solution contains one or more of specific cyclic acid anhydrides.

Lithium secondary cell including an electrolytic solution including cyclic acid anhydrides

The present invention relates to a secondary battery, comprising an electrode element in which a positive electrode and a negative electrode are opposed to each other, and an electrolyte solution, wherein the negative electrode active material comprises a metal alloyable with lithium and/or a metal oxide capable of intercalating/deintercalating lithium ions, and the electrolyte solution is a nonaqueous electrolyte solution comprising an electrolyte salt dissolved in a nonaqueous solvent, and comprises a carbonyl compound represented by the following formula (1): wherein two Rs may be the same or different from each other, and each independently represents hydrogen atom, substituted or unsubstituted alkyl group, cycloalkyl group, alkenyl group, alkynyl group, substituted or unsubstituted aromatic group, oxyalkylene group, substituted or unsubstituted alkoxy group, cycloalkyloxy group, alkenyloxy group, alkynyloxy group, substituted or unsubstituted aromatic oxy group, or oxyalkyleneoxy group.

Secondary battery

An objection is to provide a high performance secondary battery having good flame retardancy and cycle properties. The present exemplary embodiment provides a secondary battery comprising an electrode assembly in which a positive electrode and a negative electrode are arranged to face each other, an electrolyte liquid and a package accommodating the electrode assembly and the electrolyte liquid, wherein the negative electrode is formed by binding a negative electrode active substance comprising a metal (a) capable of being alloyed with lithium, a metal oxide (b) capable of occluding and releasing lithium ions and a carbon material (c) capable of occluding and releasing lithium ions, to a negative electrode current collector, with a negative electrode binder, and the electrolyte liquid comprises a supporting salt and an electrolytic solvent, the electrolytic solvent comprising at least one phosphate ester compound selected from phosphite esters, phosphonate esters and bisphosphonate esters.

An object of the present invention is to provide a secondary battery in which the decomposition of an electrolyte liquid is suppressed and the generation of a gas is reduced, even in the case of using a laminate film as a package. The present exemplary embodiment is a secondary battery of a stacked laminate type comprising an electrode assembly in which a positive electrode and a negative electrode are arranged to face each other, an electrolyte liquid, and a package accommodating the electrode assembly and the electrolyte liquid, wherein the negative electrode is made by binding a negative electrode active substance containing a metal (a) capable of being alloyed with lithium, a metal oxide (b) capable of occluding and releasing lithium ions, and a carbon material (c) capable of occluding and releasing lithium ions, to a negative electrode current collector, with at least one selected from polyimides and polyamideimides; and the electrolyte liquid comprises acrylonitrile or an acrylonitrile compound being an acrylonitrile derivative.

The object is to provide a secondary battery with higher performance, and especially to provide a secondary battery having low impedance. An exemplary embodiment of the invention is a secondary battery, comprising an electrode assembly in which a positive electrode and a negative electrode are oppositely disposed, an electrolyte liquid, and a package which encloses the electrode assembly and the electrolyte liquid inside; wherein the negative electrode is formed by binding a negative electrode active substance to a negative electrode collector with a negative electrode binder; and wherein the electrolyte liquid comprises a fluorine-containing cyclic ether compound.

Provided is a secondary battery having a good battery property at a high temperature. A secondary battery according to an exemplary embodiment of the invention comprises a negative electrode and an electrolyte liquid; wherein the negative electrode is formed by binding a negative electrode active substance on a negative electrode collector with a negative electrode binder; and wherein the electrolyte liquid comprises a compound (A) having a C&#x2550;S bond. In this embodiment, the negative electrode active substance is formed by covering at least one of a metal (a) that can be alloyed with lithium and a metal oxide (b) that can absorb and desorb a lithium ion with a carbon material (c). Alternatively, the negative electrode active substance comprises a metal (a) that can be alloyed with lithium and the negative electrode binder negative electrode is a polyimide or a polyamide-imide.

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Tokyo, Japan

Midori Shimura