Sumitomo Chemical Company, Limited

Michio Yamamoto

Gohfu Suzukamo

Makoto Itagaki

Masaru Ishino

Seimei Yasui

Makoto Yako

Takanobu Noguchi

Koji Hagiya

Hiroshi Sato

Motoo Hazama

Masashi Komatsu

Takuo Hibi

Kotohiro Nomura

Masami Fukao

Masahiko Mizuno

Atsushi Furutani

Masashi Kamitamari

Yoshiharu Yagi

Kazuo Hayatsu

Fumisato Goto

Minoru Hino

Takao Oshima

Shigefumi Tokumasu

Kazuhiro Tada

Kazuyuki Tanaka

Hirotsugu Kano

Masato Kawamura

Tetsuro Yonemoto

A method for producing an alkoxycarbonyl compound wherein the method comprises reacting carbon monoxide and an alcohol compound with methylacetylene in the presence of a catalyst containing a Group 10 metal compound, a proton acid and a phosphine compound, the propadiene content of the methylacetylene is 50 ppm or less, the phosphine compound is used at greater than 0.000020 mol with respect to 1 mol of methylacetylene, and the carbon monoxide and the alcohol compound are reacted with 200000 mol or more of methylacetylene with respect to 1 mol of the Group 10 metal compound.

Process for production of alkoxycarbonyl compound

There is disclosed a process for producing an olefin oxide characterized by contacting an olefin and oxygen, in the presence of water and a halogen compound, with a silver catalyst, wherein the silver catalyst is a silver catalyst that is obtainable by contacting metal silver, a silver compound or a mixture of both with an alkaline earth metal carbonate and that has an alkali metal content of 1,500 ppm or less based on the total weight of the silver catalyst.

Process for producing olefin oxide

There is disclosed a process for producing an olefin oxide, which is characterized by reacting an olefin with oxygen in the presence of a silver catalyst and 0.2 mole or more of water per mol of the olefin.

There is disclosed an optically active salicylideneaminoalcohol compound of formula (1):wherein Rrepresents an alkyl group or the like, Rrepresents

Chiral copper complex and production processes thereof and using the same

Disclosed is an asymmetric copper catalyst composition comprising, as components, (a) an optically active bisoxazoline compound of formula (1):wherein

Asymmetric copper complex and cyclopropanation reaction using the same

Chiral copper complex catalyst composition and asymmetric production process using the same

Process for producing alkenyl-substituted aromatic hydrocarbons

Method for producing of 2,3-dimethylbutene-1 and 2,3-dimethylbutene-2

There is provided a process for producing an alkenyl-substituted pyridine derivative using, a solid base catalyst which is obtained by heating a metal oxide selected from the group consisting of alumina, an alkaline earth metal oxide and a hydrotalcite with

Process for producing alkenyl--substituted pyridine derivative

2,3-Dimethyl-2-butene is prepared by isomerizing 2,3-dimethyl-1-butene using at least one acid selected from the group consisting of sulfuric acid and sulfonic acids. By this process, 2,3-dimethyl-2-butene is effectively prepared from 2,3-dimethyl-1-butene using an inexpensive catalyst such as sulfonic acid or the sulfonic acids. Further, a dimerization reaction product of propene can also be used in the isomerization step without removing the dimerization catalyst from the reaction product.

Process for preparing 2,3-dimethyl-2-butene

A process is disclosed for producing an amine by carrying out a reductive amination of a cyclic ketone or by carrying out a reduction of an imino derivative of a cyclic ketone to the corresponding amine which process is characterized in using a cobalt catalyst containing a carbonate of an alkaline earth metal and/or lanthanum oxide.

Process for producing amines

Amines are produced in high yield by the process which comprises allowing a cyclic ketone to react with ammonia in the presence of active carbon to produce imino derivatives and then, allowing the imino derivatives to react with hydrogen in the presence of a hydrogenating catalyst.

A process for preparing a dimer of a lower .alpha.-olefin in the presence of Catalyst (A) containing a nickel compound, a trialkylaluminum, a halogenated phenol, a phosphorus compound and a sulfur compound, Catalyst (B) containing a nickel compound, a trialkylaluminum, a fluorinated isopropyl alcohol, a phosphorus compound, a sulfonic acid and water, or Catalyst (C) containing a nickel compound, a trialkylaluminum, a halogenated phenol, a phosphorus compound, a sulfonic acid and water, by which method, the dimer of the lower .alpha.-olefin is prepared in a high yield and high selectivity.

Dimerization of low .alpha.-olefins

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Otsu, Japan

Michio Yamamoto