Nitto-denko Corporation

Michio Umeda

Kenichi Okada

Tomonari Naito

Masao Abe

Akiko Takahashi

Akira Ohtani

Hiroyuki Higuchi

Keiji Nakamoto

Shinya Akizuki

Toshitaka Takahashi

Minoru Ezoe

Mika Kanamaru

Yasuhiro Umemoto

Keiko Mochizuki

Hiroshi Wada

Masahiro Ohura

Kazuhisa Maeda

Koichi Ikeda

Akiko Miyano

A pressure-sensitive adhesive sheet contains at least a pressure-sensitive adhesive layer containing an acrylic pressure-sensitive adhesive containing an acrylic polymer composition containing an acrylic polymer as a main component and a tackifier containing a tackifying resin as a main component, wherein reflection rate and attached amount in the fogging test in accordance with German Industrial Standard DIN 75201 are 70% or more and 2.0 mg or less, respectively. In the acrylic pressure-sensitive adhesive which forms the pressure-sensitive adhesive layer, a ratio of components having a molecular weight of 300 or less is preferably 4.2% by weight or less based on the total amount of solid matter of the acrylic pressure-sensitive adhesive. Furthermore, in the tackifying resin in the tackifier, a ratio of components having a molecular weight of 300 or less is suitably 4.2% by weight or less based on the total amount of solid matter of the tackifying resin.

Pressure-sensitive adhesive sheet

To provide an adhesive composition which shows high adhesion with a glass substrate and has excellent heat resistance, moisture resistance and moist heat resistance, an adhesive optical film comprising an adhesive layer made of the adhesive composition, which shows high adhesion between the adhesive layer and an optical film and effectively suppresses the occurrence of adhesive residue and lack of adhesive and also has excellent heat resistance, moisture resistance and moist heat resistance, and an image display device comprising the adhesive optical film, the adhesive optical film comprises an optical film, an adhesive layermade of a water dispersible adhesive composition comprising, as raw monomers, an alkyl (meth)acrylate ester whose alkyl group has 4 to 18 carbon atoms, a carboxyl group-containing vinyl monomer, a phosphoric acid group-containing vinyl monomer, and a copolymerizable vinyl monomer which is optionally copolymerizable with the above monomers, wherein a carboxyl group concentration is from 0.05 to 1.50 mmol/g and a phosphoric acid group concentration is from 0.01 to 0.45 mmol/g in the raw monomers, an under coat layercontaining an oxazoline group-containing polymer, and being interposed between the optical filmand the adhesive layer, and the adhesive optical film is applied onto an image display device.

Adhesive composition, adhesive optical film and image display device

Provided is an acrylic pressure sensitive adhesive composition excellent in pressure sensitive adhesive characteristics and removability and a pressure sensitive adhesive tape using the acrylic pressure sensitive adhesive composition. An acrylic pressure sensitive adhesive composition containing an acrylic polymer obtained by at least copolymerizing a (meth) acrylic acid alkyl ester with an alkyl group having 2 to 14 carbon atoms and a carboxyl group containing unsaturated monomer copolymerizable with the (meth) acrylic acid alkyl ester, and tackifier resins, wherein the tackifier resins are respective resins each containing a natural product as a raw material, include at least 4 kinds of the resins different in a molecular structure from one another and a content of each of the tackifier resins is in the range of 5 parts by weight or more and 20 parts by weight or less relative to 100 parts by weight of the acrylic polymer.

Acrylic pressure sensitive adhesive composition and pressure sensitive adhesive tape

An aqueous dispersion type pressure-sensitive adhesive composition which has a small increase of a peel force to a release liner having a silicone release agent applied thereto or back coating layer, and pressure-sensitive adhesive sheets comprising the composition. The aqueous dispersion type pressure-sensitive adhesive composition comprises an aqueous dispersion of a polymer obtained by copolymerizing a monomer mixture comprising one or more alkyl (meth)acrylates as the main component and at least one silane monomer, and an organic compound capable of bonding to the silane monomer.

Aqueous dispersion type pressure-sensitive adhesive composition, and pressure-sensitive adhesive sheet

An aqueous dispersion type pressure-sensitive adhesive composition which is excellent in adhesion to foams and unsusceptibility to edge peeling and retains stable adhesive force over long, a pressure-sensitive adhesive sheet including a substrate and, disposed on one or both sides thereof, a pressure-sensitive adhesive layer comprising the aqueous dispersion type pressure-sensitive adhesive composition, and a pressure-sensitive adhesive rubber foam sheet comprising a rubber foam and, disposed on one or both sides thereof, the pressure-sensitive adhesive layer or pressure-sensitive adhesive sheet. The aqueous dispersion type pressure-sensitive adhesive composition comprises an aqueous dispersion of a polymer obtained by copolymerizing a monomer mixture comprising one or more alkyl (meth)acrylates as the main component and at least one silane monomer, and a tackifier having a phenolic skeleton, added to the aqueous dispersion.

Aqueous dispersion type pressure-sensitive adhesive composition, pressure-sensitive adhesive sheet, and pressure-sensitive adhesive rubber foam sheet using the sheet

This invention relates to a conducting organic polymer formed by doping an organic polymer with a protonic acid having a dissociation constant value pKa of less than 4.8, wherein the organic polymer has, as the main repeating unit, a compound represented by the general formula: ##STR1## wherein, m and n, respectively, show the molar fraction of the quinonediimine structural unit and phenylenediamine structural unit in the repeating unit, and 0&lt;m&lt;1, 0&lt;n&lt;1, and m+n=1; and the organic polymer is soluble in an organic solvent in the undoped state, and has an intrinsic viscosity �.eta.! of more than 0.4 dl/g measured in N-methyl-2-pyrrolidone at 30.degree. C. This invention also relates to a film formed of the conducting organic polymer and a conducting organic polymer composition.

Organic polymer, conducting organic polymer, production methods and uses

This invention relates to an organic polymer having, as the main repeating unit, the compound represented by the general formula: ##STR1## (wherein, m and n respectively show the molar fraction of quinonediimine structure unit and phenylenediamine structure unit in the repeating unit, and 0&lt;m&lt;1, 0&lt;n&lt;1, and m+n=1.), and soluble in an organic solvent in an undoped state, and having the intrinsic viscocity [.eta.] of more than 0.4 dl/g measured in N-methyl-2-pyrrolidone at 30.degree. C., and a conducting organic polymer formed by doping a protonic acid to such a polymer.

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Ibaraki, Japan

Michio Umeda