Exxon Research and Engineering Company

Michael T Melchior

Guido Sartori

George E Milliman

Chang J Kim

David William Savage

George R Chludzinski

Acidic gases containing carbon dioxide are removed from a normally gaseous mixture by absorbing CO.sub.2 from the gaseous mixture with an aqueous solution comprising a basic alkali metal salt or hydroxide and an activator or promoter system for the salt or hydroxide which contains (i) at least one non-sterically hindered diamine defined as having both a primary and a tertiary amino moiety wherein the primary amino moiety is attached to a primary carbon atom, and (ii) an amino acid, and desorbing at least partially the absorbed CO.sub.2 from the aqueous solution.

Process for removing acid gases using a basic salt activated with a

Antifoaming agents for use in acid gas scrubbing processes comprising 1-secondary or 1-tertiary alkyl- or 1-cycloalkyl-hexahydro-2-pyrimidinones and 1-secondary or 1-tertiary alkyl- or 1-cycloalkyl-2-imidazolidinones are disclosed.

1-Secondary or 1-tertiary alkyl or cycloalkyl-hexahydro-2-pyrimidinones

Acidic gases such as carbon dioxide are removed from a gaseous mixture including the acidic component by contacting the gaseous mixture in a scrubbing system with an acid absorbing solution comprising a basic alkali metal compound and an activator, during which process at least a portion of the activator is converted to cyclic urea. At least a portion of the scrubbing solution is transferred to a thermal conversion zone wherein at least a portion of the cyclic urea is converted back to the activator afterwhich the scrubbing solution is returned to the scrubbing system from the thermal conversion zone.

Process for converting cyclic urea to corresponding diamine in a gas

Antifoaming agents for use in acid gas scrubbing processes comprising 1-secondary or 1-tertiaryalkyl- or 1-cycloalkyl-hexahydro-2-pyrimidinones and 1-secondary or 1-tertiary alkyl- or 1-cycloaklyl-2-imidazolidinones are disclosed.

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Scotch Plains, NJ, United States of America

Michael T Melchior