The Dow Chemical Company

Michael T Holbrook

A Dale Harley

Larry N Ito

Lawrence A Hebert

David D Smith

Craig B Murchison

Mark D Cisneros

Stephen W Najmy

Reimer Hasche

Ernest F Stine, Jr

Timothy J Juhlke

Thomas E Morris

David H West

Katherine A Pividal

Roger L Bowlin

Celio Lume Pereira

A saturation process for essentially completely saturating unsaturated halogenated hydrocarbonaceous materials in a feedstock containing such unsaturated materials, employing a first recycle reactor for accomplishing the bulk of the saturation and a second, single pass, plug flow-type polishing reactor in combination.

Process for the complete saturation of halogenated hydrocarbon streams

A novel, improved process and catalyst are provided for the catalytic hydrodechlorination of a chlorinated alkane to its corresponding less-chlorinated and preferably non-chlorinated alkane, for example the hydrodechlorination of 1,2-dichloropropane to propane, the catalyst comprising a mixture of active Group VIII hydrogenating metals in elemental or compound form on a support.

Hydrodechlorination process and catalyst for use therein

A process for converting a chlorinated alkene feedstock including two or more chlorines to reaction products including a less-chlorinated alkene in a commercially substantial proportion, comprising reacting the chlorinated alkene feedstock with hydrogen in the presence of a catalyst consisting essentially of a Group VIII metal other than rhodium, palladium or ruthenium and a Group IB metal on a support.

Processes for converting chlorinated alkenes to useful, less chlorinated

A process for the catalytic conversion of various chlorinated hydrocarbon byproducts and waste products especially to less chlorinated, useful or salable products, in which a chlorinated hydrocarbon feedstock containing two or more chlorines is reacted with hydrogen in the presence of a catalyst consisting essentially of an active hydrogenating metal component such as platinum in elemental or compound form, and a surface segregating metal component such as copper in elemental or compound form on a support.

Processes for converting chlorinated byproducts and waste products to

A hydrodehalogenation process, comprising the step of reacting a saturated halohydrocarbon (e.g., 1,2-dichloropropane) with hydrogen or a hydrogen donor in the gas phase in the presence of a catalytically effective amount of ruthenium on a support, and at temperatures of at least about 100 degrees Celsius, to produce reaction products including a corresponding non-halogenated, unsaturated hydrocarbon (e.g., propylene).

Hydrodehalogenation process and catalyst for use therein

A process for hydrohalogenating methanol with a hydrogen halide using a catalyst having an initial zone of lower activity and subsequent zones of higher activity so that coke formation and pressure drop are decreased and catalyst life is increased while overall high catalyst activity is maintained. One example of such a process uses a low surface area amorphous alumina in an initial zone and then progressively higher surface area alumina in subsequent zones.

Catalyst for hydrohalogenation of hydrocarbons

Process and catalyst for hydrohalogenation of hydrocarbons

A process for the hydrodechlorination of carbon tetrachloride to produce chloroform and methylene chloride utilizes a supported platinum catalyst that is subjected to chloride pre-treatment. The platinum catalyst may be promoted with small amounts of metals such as tin. By-product production is decreased and duration of catalyst activity is improved by the process of this invention.

Vapor phase hydrogenation of carbon tetrachloride

Methyl chloride is produced by contacting methanol and hydrogen chloride in the vapor phase in the presence of KZnCl.sub.3 supported on silica. The process produces methyl chloride in good yield with minimal formation of dimethyl ether as a by-product.

Catalyst for hydrochlorination of hydrocarbons

An adiabatic vapor phase chlorination of methylene chloride, methyl chloride or a mixture thereof is improved by the injection of a portion of the methylene chloride, methyl chloride or mixture thereof into the reactor in the liquid state under conditions such that the temperature throughout the reaction zone is maintained at less than about 500.degree. C.

Liquid feed injection in a chloromethanes process

This invention relates to a process for continuously producing halogenated hydrocarbons by: (1) flowing a feed mixture containing CO, H2 and a halogen source into a reaction zone containing a catalyst bed; (2) removing from the reaction zone the resultant reaction product which contains the desired halogenated hydrocarbons; and (3) maintaining the halogen source content in the feed mixture at from about the stoichiometric amount to about twice the stoichiometric amount needed to produce the halogenated hydrocarbons.

Process for the production of halogenated hydrocarbons

Process and catalyst for hydrochlorination of hydrocarbons

This invention relates to an improved liquid phase chlorination process for the chlorination of methyl chloride to preferentially produce methylene chloride. The chlorine is provided to the reaction mixture in a mole percent, based upon the total moles of chlorine and methyl chloride in the mix, which ranges from about 16 mole percent to about 2 mole percent.

Growing community of inventors

Baton Rouge, LA, United States of America

Michael T Holbrook