US Government As Represented by the Secretary of the Army

University of Akron

Michael S Sennett

Lynne Ann Samuelson

Jayant Kumar

Ferdinando F Bruno

Ramaswamy Nagarajan

Heidi Schreuder-Gibson

Kris Senecal

Daniel J Smith

Darrell H Reneker

Charlene M Mello

Albert T McManus

Elizabeth A Welsh

Jean M Herbert

Phillip M Cunniff

A transparent, reinforced, composite polymeric fiber that has a polymeric body portion made from a first thermoplastic polymer that is transparent to visible light. The fiber includes polymeric reinforcement elements embedded within the polymeric body portion. The polymeric body portion extends between and about the polymeric reinforcement elements. Each polymeric reinforcement element is formed from a second thermoplastic polymer that is transparent to visible light. The peripheral portion and outer surface of the polymeric body portion defines a peripheral portion and outer surface, respectively, of the transparent, reinforced, composite polymeric fiber. A plurality of the fibers are formed into an array that is processed with a consolidation process to form a transparent, reinforced, composite structure.

Transparent, reinforced, composite fiber and articles made therefrom

An assembled hematin is formed by depositing hematin on an electrically charged substrate in one or more layers alternating with one or more layers of polyelectrolyte, preferably a cationic polymer. In a method for polymerizing an aromatic monomer, the assembled hematin is contacted with the monomer and a template, preferably an anionic polymer. In a method for polymerizing aniline, the aniline, sulfonated multi walled carbon nano tubes, PEG hematin and a reaction initiator are dispersed in water.

Assembled hematin, method for forming same and method for polymerizing aromatic monomers using same

A conductive (electrical, ionic, and photoelectric) polymer membrane article, comprising a non-woven membrane of polymer fibers, wherein at least some of the fibers have diameters of less than one micron; and wherein the membrane has an electrical conductivity of at least about 10S/cm. Also disclosed is the method of making such an article, comprising electrostatically spinning a spin dope comprising a polymer carrier and/or a conductive polymer or conductive nanoparticles, to provide inherent conductivity in the article.

Conductive (electrical, ionic, and photoelectric) polymer membrane articles, and method for producing same

A conductive (electrical, ionic, and photoelectric) polymer membrane article, comprising a non-woven membrane of polymer fibers, wherein at least some of the fibers have diameters of less than one micron; and wherein the membrane has an electrical conductivity of at least about 10 S/cm. Also disclosed is the method of making such an article, comprising electrostatically spinning a spin dope comprising a polymer carrier and/or a conductive polymer or conductive nanoparticles, to provide inherent conductivity in the article.

Conductive (electrical, ionic and photoelectric) membrane articlers, and method for producing same

A novel fiber comprising a substantially homogeneous mixture of a hydrophilic polymer and a polymer which is at least weakly hydrophobic is disclosed. The fiber optionally contains a pH adjusting compound. A method of making the fiber comprises electrospinning fibers of the substantially homogeneous polymer solution. A method of treating a wound or other area of a patient requiring protection from contamination comprises electrospinning the substantially homogeneous polymer solution to form a dressing. An apparatus for electrospinning a wound dressing is discosed.

Electrospun fibers and an apparatus therefor

The invention is a continuous polymerization process for producing high molecular weight linear poly(dichlorophosphazene) polymers in dilute solution. Substantially pure cyclic oligomers represented by the formula (NPCl.sub.2).sub.n are polymerized in dilute solution in an inert solvent at a temperature in the range from 150 degrees Celsius to 300 degrees Celsius for a period of time sufficient to convert a predetermined percentage of oligomer to polymer. The polymer solution may be added to a fresh solution of oligomer, solvent and catalyst to obtain polymers of greater molecular weight. This step may be repeated as many times as necessary to obtain a particular molecular weight. This invention provides a significant improvement in the attainable molecular weight in dilute solution polymerization, with a very high conversion rate of oligomer. The viscosity of the solution during the continuous reaction process is maintained at a level which may be easily handled.

Growing community of inventors

Maynard, MA, United States of America

Michael S Sennett