Smartpolymer Gmbh

Zimmer Aktiengesellschaft

Thueringisches Institut Fuer Textil-und Kunststoff-forschung E.v.

Thuringishces Institut Fur Textil Und Kunststoff-forschung E.v.

Thuringisches Institut Fur Textil Und Kunststoff-forschung E. V.

Michael Mooz

Ralf-Uwe Bauer

Sabine Riede

Marcus Krieg

Frank Meister

Frank-Günter Niemz

Christoph Michels

Birgit Kosan

Holger Gunkel

Markus Krieg

Martin Sellin

Methods for producing cellulose articles having controlled release of active ingredient include dispersing pulp in aqueous direct solvent for cellulose to form a slurry. Organically modified or ion-exchange-activated phyllosilicate is homogenized in a direct solvent for cellulose with exfoliation by shearing, then mixed with the slurried pulp. A mixture of active ingredient and a lipophilic matrix material or a water-in-oil ('W/O') emulsion containing active ingredient is stabilized with thickener, converted into a gel-like paste, and mixed with the slurried pulp. Water is stripped from the mixture until all cellulose is dissolved, the mixture is formed into shaped articles, and dried. Exemplary active ingredients include cosmetic active ingredients, fat-soluble vitamins or apolar plant extracts. Domains of active ingredient and matrix material or emulsion containing active ingredient are present as fine divisions within the inventive articles. Exemplary shaped articles include functional fibers in knitted, woven and nonwoven fabrics; paper; foils and membranes.

Method for producing shaped functional cellulose articles with targeted release of active ingredients

The invention relates to molded cellulose bodies, in particular fibers, filaments, directly spun nonwovens, films, or foams which have flame-resistant properties. The fibers and filaments can be further processed as textiles into yarns, wovens, knitted fabrics, and nonwovens. The molded bodies are produced from solutions of cellulose and melamine cyanurate or cellulose and crosslinked or partially crosslinked melamine resin particles in an organic solvent. The melamine cyanurate or the melamine resin particles provide the molded cellulose bodies with flame-retardant properties. The molded cellulose bodies made of cellulose and melamine cyanurate or melamine resin particles can further contain flame retardants, in particular flame retardants which act synergistically, in a particulate form. The obtained textile fibers and nonwoven materials have a soft touch and can be processed or finished as filaments or yarns on conventional textile machines.

Flame-resistant molded cellulose bodies produced according to a direct dissolving method

Shaped lyocell cellulose articles are provided for binding heavy metal ions and radioactive isotopes thereof. The shaped articles include one or more hexacyanoferrates that are incorporated in a cellulosic matrix and uniformly distributed therein. The shaped articles can be fibers, fibrids, fibrous nonwoven webs, granules, beads, self-supporting films, tubular films, filaments, sponges, foams or bristles. They are useful for water treatment and water decontamination, for metal beneficiation, for treatment of wound with wound dressings, for air and gas filtration and in protective apparel.

Formed lyocell articles for selective binding of monovalent heavy metal ions, especially thallium and cesium ions and radioactive isotopes thereof

Process for producing formed cellulosic articles, such as fibers, filaments, sheetings, membranes or tubes, comprising a) extruding a solution of cellulose in an aqueous amine oxide, particularly N-methylmorpholine N-oxide, through an extrusion die via an air gap and coagulating the formed article in an aqueous precipitation bath containing amine oxide, and b) passing the formed article through at least one washing stage for removing residual amine oxide from the article, characterized in that the liquor of the precipitation bath in the precipitation stage and/or the washing liquor of the washing stage(s) is treated with ultra-violet radiation. In this manner the formation and growth of coatings, films and slime deposits caused by microorganisms is avoided on parts of the plant which come into contact with said liquors containing the amine oxide.

Method for producing cellulosic forms

The invention relates to a method for producing a cellulose solution in an aqueous amine oxide, preferably N-methyl-morpholine-N-oxide, for processing to form cellulosed moulded bodies according to the Lyocell method, whereby said solution has an increased thermal stability. Cellulose is suspended in an aqueous amine oxide and the suspension is converted into the cellulose solution. The inventive method is characterised in that the base use of the cellulose used for producing the solution and of the optionally used additives is detected in a dispersion in aqueous amine oxide solution and in that the cellulose solution is formed by adding a base quantity which matches the detected own consumption of the cellulose and optionally the additives. Cellulose solutions having a stability which is essentially independent from the provenance of the used cellulose can he formed.

Method for producing a cellulose solution in an aqueous amine oxide, said solution having an increased thermal stability

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Saalfelder Höhe, Germany

Michael Mooz