The Goodyear & Tire Rubber Company

Zeon Chemicals L.p.

Michael M Gozdiff

Valerie Anne Hill

Edmee Files

David D H Tao

Ernest W DeMarse

The present invention discloses a process for hydrogenating a latex of a low molecular weight functionalized, unsaturated elastomer to produce a latex of a hydrogenated, low molecular weight, low gel, functionalized elastomer, said process comprising hydrogenating the low molecular weight, functionalized, unsaturated elastomer in the presence of (1) an oxidant selected from the group consisting of oxygen and hydroperoxides, (2) a reducing agent selected from the group consisting of hydrazine and hydrazine hydrates, and (3) a metal ion activator, wherein a hydroxylamine is added to the latex of the low molecular weight, functionalized, unsaturated elastomer or to the latex of the hydrogenated, low molecular weight, functionalized elastomer prior, during, or subsequent to the hydrogenation to produce the latex of the hydrogenated low molecular weight, low gel, functionalized elastomer. This process can be used to make low molecular weight, hydrogenated, nitrile rubber latex which is comprised of water, an emulsifier, and the low molecular weight, hydrogenated, nitrile rubber, wherein the low molecular weight, hydrogenated, nitrile rubber has a molecular weight which is within the range of 500 to 20,000, wherein the low molecular weight, hydrogenated, nitrile rubber has a gel content of less than 10%, and wherein the low molecular weight, hydrogenated, nitrile rubber has a saturation level of at least about 80%.

Process for preventing gel formation in lattices of hydrogenated, low molecular weight, functionalized elastomers

The present invention discloses a process for hydrogenating a latex of a low molecular weight functionalized, unsaturated elastomer to produce a latex of a hydrogenated, low molecular weight, low gel, functionalized elastomer, said process comprising hydrogenating the low molecular weight, functionalized, unsaturated elastomer in the presence of (1) an oxidant selected from the group consisting of oxygen and hydroperoxides, (2) a reducing agent selected from the group consisting of hydrazine and hydrazine hydrates, and (3) a metal ion activator, wherein a hydroxylamine is added to the latex of the low molecular weight, functionalized, unsaturated elastomer or to the latex of the hydrogenated, low molecular weight, functionalized elastomer prior, during, or subsequent to the hydrogenation to produce the latex of the hydrogenated low molecular weight, low gel, functionalized elastomer.

This invention discloses a polymeric magnet composition that is particularly useful for extrusion into thermoplastic magnetic tubing, said polymeric magnet composition being comprised of (1) from 2 to 8 parts by weight of a rubbery polymer which is comprised of repeat units which are comprised of (a) butyl acrylate, (b) at least one member selected from the group consisting of methyl methacrylate, ethyl methacrylate, methyl acrylate and ethyl acrylate, (c) acrylonitrile, (d) styrene, (e) a surfactant selected from the group consisting of sulfonates and sulfate derivatives, (f) a dispersant selected from the group consisting of aromatic formaldehyde condensation products and polycarboxylates and (g) a crosslinking agent; (2) from 2 to 8 parts by weight of a styrene-butadiene resin; (3) from 80 to 90 parts by weight of a magnetic powder; and (4) from 1 to 8 parts by weight of an internal lubricant.

Magnetic thermoplastic tubing

This invention relates to a polymeric composition having ultraviolet light and heat resistance that can be molded into rubbery articles that can be magnetized. For instance, the rubbery compositions of this invention can be molded into magnetic seals for refrigerator or freezer doors. In such applications, the magnetic composition acts as a combination airtight gasket and magnetic closure device for the refrigerator or freezer. These polymeric magnetic compositions offer the advantage of being thermoplastic materials rather than thermosets. By virtue of being thermoplastics, they can be injection-molded into the desired form without the need for a curing step. Thus, rubbery magnetic compositions can be manufactured by a simpler, less costly process by utilizing the compositions of this invention. This invention more specifically discloses a polymeric magnet composition which is comprised of (1) from 5 to 19 parts by weight of a rubbery polymer which is comprised of repeat units which are comprised of (a) butyl acrylate, (b) at least one member selected from the group consisting of methyl methacrylate, ethyl methacrylate, methyl acrylate and ethyl acrylate, (c) acrylonitrile, (d) styrene, (e) a crosslinking agent; (2) from 80 to 90 parts by weight of a magnetic powder; and (3) from 1 to 10 parts by weight of an internal lubricant.

Polymeric magnet compound

This invention supplies an insulating conveying belt composed of a belt carcass having at least one embedded reinforcing ply, a pulley cover and a top cover, said top cover having a heat resistant member adhered to said top cover, said heat resistant member being selected from the class consisting of fibers of aramid, glass, ceramic or mixtures thereof. This member may be woven or non-woven such as a punched felt mat. Preferably the fibers of the heat resistant member are woven rather than being of the non-woven type. The elastomer preferably is EPDM or blends of EPDM and silicone rubber with carbon black or silica filler.

Heat resistant belt

A plurality of lengths of at least one flattened flexible polymeric tube disposed in superposed relation. Each length in cross section includes enlarged folded edge portions with a flat center portion between the edge portions. Means such as a separator or spacer having substantial thickness is inserted between or within the tube lengths to support the weight of at least a substantial part of the center portion of each length to prevent the formation of edge creases longitudinally along the edges of the tube lengths. The invention is particularly useful in the processing of uncured or unvulcanized rubber tubes either in a stacked or rolled condition.

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North Canton, OH, United States of America

Michael M Gozdiff