Crayola Llc.

Rohm and Haas Company

Michael Louis Spera

Andrew T Daly

Michael G Moskal

Casmir S Ilenda

David E Rowan

Eric Gustave Lundquist

Robert H Gore

Ethan S Simon

Wayne Devonport

Gordon L Tullos

Paul Francis Reeve

Leena Vadaketh

Jie Li

Grant E Schlegel

Eric Alexander Boschi

Jenifer Lyn Machleder, Legal Representative

Eric Michael Machleder, Legal Representative

Anthony C Drago, Iii

Cindy Nguyen

James Broe Fitzpatrick

James R Lesniak

David Rowan

A non- or low-boron putty base includes a crosslinked reaction product of at least one polydiorganosiloxane that has at least two reactive functional groups and at least one crosslinker capable of reacting with the reactive functional groups to form the crosslinked reaction product. The putty base is dilatant and may include 0 to 0.1 weight percent of a boron-containing compound. Dilatant putties made from the putty base and fillers are also provided. A method of making a dilatant putty includes: providing at least one polydiorganosiloxane including at least two reactive functional groups; providing an additive; providing at least one crosslinker capable of reacting with the reactive functional groups; and combining the polydiorganosiloxane, the filler, and the crosslinker to form the dilatant putty having less than 0.1 wt % boron.

Putty and putty base compounds and methods of making thereof

A non- or low-boron putty base includes a crosslinked reaction product of at least one polydiorganosiloxane that has at least two reactive functional groups and at least one crosslinker capable of reacting with the reactive functional groups to form the crosslinked reaction product. The putty base is dilatant and comprises 0 to 0.1 weight percent of a boron-containing compound. Dilatant putties made from the putty base and fillers are also provided. A method of making a dilatant putty includes: providing at least one polydiorganosiloxane comprising at least two reactive functional groups; providing an additive; providing at least one crosslinker capable of reacting with the reactive functional groups; and combining the polydiorganosiloxane, the filler, and the crosslinker to form the dilatant putty having less than 0.1 wt % boron.

The present invention provides moldable compositions that are capable of resisting slumping and cracking when allowed to dry and harden. Embodiments of the moldable composition comprise water, fillers including arrowroot and kaolin clay, at least one polar polymeric resin (e.g., polyvinyl alcohol), at least one thickening agent (e.g., ammonium pentaborate tetrahydrate), one or more pH adjusters (e.g., triethanolamine, sodium bicarbonate), a humectant (e.g., propylene glycol, glycerin), optionally at least one releasing agent (e.g., mineral oil), and optionally at least one additive.

Moldable compositions and methods of using thereof

The present invention provides moldable compositions that are capable of drying and hardening if left in open air at room temperature for a period of time. Embodiments of the moldable compositions comprise water, at least one polar polymeric resin (e.g., polyvinyl alcohol), at least one thickening agent (e.g., boric acid, borate salt, or hydrate of a borate salt), at least one humectant (e.g., glycerin, propylene glycol, etc.), at least one filler (e.g., corn starch, tapioca, or arrowroot), optionally at least one releasing agent (e.g., mineral oil) and optionally at least one additive.

Moldable compositions and methods of using the same

The present invention relates to moldable sand compositions, methods for making the moldable sand compositions, and methods for using the moldable sand compositions. In a particular embodiment, the moldable sand composition comprises between about 70% to about 95% sand, between about 5% to about 30% water, a polar polymeric resin, a crosslinking agent, and a humectant. In an exemplary embodiment, the composition contains no oils, waxes, glycols, or rubbers. The composition is capable of becoming hardened over time in order to maintain the achieved shape, and can be re-wetted and molded again after becoming hardened.

Moldable sand compositions and methods for making the same

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The present invention provides smooth and even ultraviolet (UV) cured powder coatings for wood comprising one, two or three layers of one or more waterborne stains, or clear or tinted waterborne basecoat coatings and one or more topcoat layers of clear or tinted clear powder coatings made from one or more than one free radical UV curing resin, one or more than one photoinitiator, and one or more than one post-blend dry flow additive, such as fumed alumina. The coatings of the present invention have a natural wood appearance, are foam free and fully coat substrates at powder coating thicknesses ranging from 0.5 mil (12.7 &#x3bc;m) to 2.0 mil (50.8 &#x3bc;m). Accordingly, the coatings will fully and evenly coat uneven, beveled and/or routered substrate surfaces, including open grain natural wood substrates, such as oak. In addition, the present invention provides a method for making coatings comprising applying one or more waterborne stain to the wood to form a stain layer, drying or curing the said stain layer, sanding or grinding to de-nibb the said stain layer, applying clear or tinted UV curing coating powder to the stained substrate, flowing out the applied coating powder to form a continuous film, and UV curing the film formed from the powder.

Ultraviolet radiation cured powder coatings for stained wood

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A method for imparting damage resistance to a coating, film or article of manufacture comprising adding crosslinked polymeric nanoparticles having a size range of 1-100 nm in diameter to said coating, film or article of manufacture.

Damage resistant coatings, films and articles of manufacture containing crosslinked nanoparticles

The present invention, a powder composition for making powder coatings comprising one or more than one curable polymer or resin and an agglomerate of a core-shell polymer, wherein the agglomerate of a core-shell polymer has an average particle size of from 5 to 190 microns, preferably from 10 to 127 microns. The powders in accordance with the present invention provide a cured powder coating that is flexible, smooth, and which may be applied in a thickness of only from 0.3 to 8 mils. In a preferred embodiment of making a powder in accordance with the present invention, the agglomerate is cryoground to form a reduced agglomerate prior to adding it into a powder as a post-blend or a powder-forming mixture as a preblend. The preferred core-shell polymer for use in accordance with the present invention comprises an acrylic impact modifier having a poly(methyl methacrylate) shell and a poly(butyl acrylate) core. Further, the preferred curable polymer or resin powder is an epoxy resin, wherein the powder composition is a low temperature curing one component powder composition which cures at from 107 to 149 degrees C.

Smooth, flexible powder coatings

Growing community of inventors

Mohnton, PA, United States of America

Michael Louis Spera