Signa Chemistry, Inc.

Michigan State University

Intelligent Energy Inc.

Laboratoire De Chimie Des Polymeres Organiques

Cyanco Corporation

Laboratoire De Chimie Des Polymeres Organiques, Enscpb-cnrs

Michael Lefenfeld

James L Dye

Andrew Wallace

John Melack

Paul H Krumrine

James S Falcone, Jr

Robert Hoch

James E Jackson

Robert Raja

Matthew Edward Potter

Gregory Arthur Romney

Muhammad Imran

James S Falcone

Alain Deffieux

Stéphane Carlotti

Alexander James Paterson

Kelvin Dean Knorr

Partha Nandi

Ralph George Jonasson

Mana Ito

Si Kai Tan

Justin Manganaro

Roy Norcross

Andrew P Wallace

Stephane Carlotti

This disclosure relates to improved methods for alkali metal cyanide production, particularly to improved methods for sodium cyanide production. The improved method of producing sodium cyanide involves the step of contacting hydrogen cyanide with an aqueous solution of sodium carbonate or of a mixture of sodium carbonate and sodium bicarbonate to produce a sodium cyanide solution.

Alkali metal cyanide production

Methods of stimulating enhanced oil recovery from a post-cold heavy oil production with sand ('CHOPS') oil-bearing formation are disclosed. The invention relates to a method of stimulating oil recovery from a post-cold heavy oil production with sand (CHOPS) oil-bearing formation. The method optionally flushes a wellbore in a post-CHOPS oil-bearing formation having at least one worm hole to expel water from the wellbore and near wellbore region; then injects a alkali metal silicide into the post-oil-bearing formation via a wellbore to introduce the alkali metal silicide into at least one worm hole within the post-oil-bearing formation. The injection step is followed by reacting the injected alkali metal silicide to stimulate oil flow within the post-CHOPS oil-bearing formation; and recovering oil from the post-CHOPS oil-bearing formation. The alkali metal silicide dispersion can also be injected into the formation in a cyclic mode of alternating injection, soak, and production periods.

Use of alkali metal silicides in post-chops oilfield recovery operations

A process for altering a wettability characteristic of a carbonate formation to stimulate oil production includes selecting an oil bearing carbonate formation, injecting a silicide dispersion into the carbonate formation, and reacting the injected silicide dispersion with water. The reaction alters the wettability characteristic of the carbonate formation toward water wettability. The silicide dispersion can include an alkali metal silicide, such as sodium silicide. The reaction generates hydrogen, silicate, and heat that pressurizes the carbonate formation with the generated hydrogen, heats the carbonate formation with the generated heat, and reduces the viscosity of the hydrocarbons in the carbonate formation with the generated silicate. The reaction re-mineralizes the surfaces in the carbonate formation and alters the wettability characteristics of the carbonate formation as a calcium-silicon phase is formed. The hydrocarbons are recovered from the carbonate formation with a production well.

Alkali metal silicides for high temperature wettability improvement in carbonate reservoirs

A method of hydraulic fracturing is provided which uses metal silicides to generate significant pressure inside a wellbore. The method comprises injecting a fracturing fluid and an aqueous or reacting fluid into the wellbore to react with the fracturing fluid. The fracturing fluid comprises metal silicide, which may be uncoated or coated, and hydrocarbon fluid. The reacting fluid comprises water or a solvent. A method of removing buildup in pipelines such as subsea pipelines which uses metal silicides to generate heat and pressure inside the pipeline is also provided. The method comprises injecting an organic slug and an aqueous slug. The organic slug comprises metal silicide and hydrocarbon fluid. The aqueous slug comprises water. Alternatively, there is also provided a method for purifying flowback water produced from a hydraulic fracturing process comprising adding metal silicide to the flowback water produced from a hydraulic fracturing process.

Use of metal silicides in hydrocarbon production and transportation

Systems, devices, and methods combine thermally stable reactant materials and aqueous solutions to generate hydrogen and a non-toxic liquid by-product. The reactant materials can sodium silicide or sodium silica gel. The hydrogen generation devices are used in fuels cells and other industrial applications. One system combines cooling, pumping, water storage, and other devices to sense and control reactions between reactant materials and aqueous solutions to generate hydrogen. Springs and other pressurization mechanisms pressurize and deliver an aqueous solution to the reaction. A check valve and other pressure regulation mechanisms regulate the pressure of the aqueous solution delivered to the reactant fuel material in the reactor based upon characteristics of the pressurization mechanisms and can regulate the pressure of the delivered aqueous solution as a steady decay associated with the pressurization force. The pressure regulation mechanism can also prevent hydrogen gas from deflecting the pressure regulation mechanism.

Hydrogen generation systems and methods utilizing sodium silicide and sodium silica gel materials

A method of hydraulic fracturing is provided which uses metal silicides to generate significant pressure inside a wellbore. The method comprises injecting a fracturing fluid and an aqueous or reacting fluid into the wellbore to react with the fracturing fluid. The fracturing fluid comprises metal silicide, which may be uncoated or coated, and hydrocarbon fluid. The aqueous fluid comprises water. The reacting fluid comprises water or a solvent. A method of removing buildup in pipelines such as subsea pipelines which uses metal silicides to generate heat and pressure inside the pipeline is also provided. The method comprises injecting an organic slug and an aqueous slug. The organic slug comprises metal silicide and hydrocarbon fluid. The aqueous slug comprises water. Alternatively, there is also provided a method for purifying flowback water produced from a hydraulic fracturing process comprising adding metal silicide to the flowback water produced from a hydraulic fracturing process. The metal silicide in any of these methods may be alkali metal silicide or another metal silicide.

Systems, devices, and methods combine reactant materials and aqueous solutions to generate hydrogen. The reactant materials can sodium silicide or sodium silica gel. The hydrogen generation devices are used in fuels cells and other industrial applications. One system combines cooling, pumping, water storage, and other devices to sense and control reactions between reactant materials and aqueous solutions to generate hydrogen. Multiple inlets of varied placement geometries deliver aqueous solution to the reaction. The reactant materials and aqueous solution are churned to control the state of the reaction. The aqueous solution can be recycled and returned to the reaction. One system operates over a range of temperatures and pressures and includes a hydrogen separator, a heat removal mechanism, and state of reaction control devices. The systems, devices, and methods of generating hydrogen provide thermally stable solids, near-instant reaction with the aqueous solutions, and a non-toxic liquid by-product.

Hydrogen generation systems utilizing sodium silicide and sodium silica gel materials

Enhanced oil recovery techniques include introduction of alkali metal silicides into subterranean reservoirs to generate hydrogen gas, heat, and alkali metal silicate solutions in situ upon contact with water. The alkali metal silicides, such as sodium silicide, are used to recover hydrocarbons, including heavier crudes where viscosity and low reservoir pressure are limiting factors. Hydrogen, which is miscible with the crude oil and can beneficiate the heavier fractions into lighter fractions naturally or with addition of catalytic materials, is generated in-situ. It. Heat is also generated at the reaction site to reduce viscosity and promote crude beneficiation. The resulting alkaline silicate solution saponifies acidic crude components to form surfactants which emulsify the crude to improve mobility toward a production well. The silicate promotes profile modification passively via consumptive reactions or actively via addition of acidic gelling agents.

Enhanced crude oil recovery using metal silicides

The invention relates to cement compositions containing a metal silicide such as an alkali metal silicide or an alkaline earth metal silicide. Upon mixing with water, the metal silicide reacts to generate hydrogen gas, a silicate, and heat&#x2014;each of which is advantageous for the large variety of uses to which cements are put. The invention relates to a foamable cement composition comprising about 99.999 wt % to about 98.5 wt % of a cement, and about 0.001 wt % to about 1.5 wt % of a metal silicide or a mixture of metal silicides. Concretes and grouts containing the cement composition are also disclosed. Other embodiments provide methods for forming cement structures, including in subterranean formations and wells.

Foamed cement compositions containing metal silicides usable in subterranean well operations

A catalytic process for dehydration of an aliphatic C-Calcohol to its corresponding olefin is disclosed. The process continuously flows through a reaction zone a liquid phase containing an aliphatic C-Calcohol to contact a non-volatile acid catalyst at a reaction temperature and pressure to at least partially convert the aliphatic C-Calcohol in the liquid phase to its corresponding olefin. The reaction pressure is greater than atmospheric pressure and the reaction temperature is above the boiling point of the olefin at reaction pressure, but below the critical temperature of the alcohol, and the olefin product is substantially in the gaseous phase. After the contacting step, the olefin containing gaseous phase is separated from the liquid phase. The invention also relates to catalytic processes such as a hydrolysis of an olefin to an alcohol, an esterification, a transesterification, a polymerization, an aldol condensation or an ester hydrolysis.

Catalytic dehydration of alcohols using non-volatile acid catalysts

A water reactive hydrogen generation system includes devices and methods to combine reactant fuel materials and aqueous solutions to generate hydrogen. The generated hydrogen is used in a fuel cell or other application. The water reactive hydrogen generation system includes a reactant fuel chamber, a reactor chamber (zone), a water solution inlet, a hydrogen output port, and a material delivery device. The material delivery device can include a drive screw and a sliding piston to move the fuel material into the reactor zone when a reaction is initiated. As the reaction takes place, the reaction waste product is removed from the reaction zone to allow additional reactant fuel materials and aqueous solutions to be introduced and to continue the hydrogen-generating reaction. A reaction waste product created is exchanged for additional reactant fuel material at determined intervals to allow the reaction to continue until the reactant fuel is exhausted.

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New York, NY, United States of America

Michael Lefenfeld