Fraunhofer-Gesellschaft Zur Foerderung Der Angewandten Forschung E.v.

Evonik Oxeno Gmbh

Michael Jakuttis

Robert Franke

Dirk Fridag

Peter Wasserscheid

Andrea Christiansen

Marc Becker

Nicole Brausch

Andreas Hornung

Andreas Apfelbacher

Marco Haumann

Samir Binder

Sebastian Werner

Andreas Schoenweiz

Systems and methods for thermocatalytic treatment of material are provided. The system can have a charging region to supply starting material, a preconditioning zone in which preconditioned material is formed from the starting material, a pyrolysis zone in which pyrolyzed material is formed from the preconditioned material, and a separation unit for separation of the pyrolyzed material. In the preconditioning zone and the pyrolysis zone, a heater can be provided for heating of the material. Also provided in the pyrolysis zone are recirculation means with which a solid portion of the pyrolyzed material can be recirculated directly into the region of the pyrolysis zone facing toward the preconditioning zone.

System and method for thermocatalytic treatment of material and pyrolysis oil produced therewith

The present invention provides a composition comprising: a) an inert porous support material, b) an ionic liquid, c) a metal selected from group 9 of the Periodic Table of the Elements, d) a phosphorus-containing organic ligand, e) at least one organic amine. The present invention further provides a process for hydroformylating olefin-containing hydrocarbon mixtures to aldehydes with addition of the inventive composition as a catalytically active composition, wherein: a) the water content of the olefin-containing hydrocarbon mixture is adjusted to not more than 20 ppm, b) the content of polyunsaturated compounds in the olefin-containing hydrocarbon mixture is adjusted to not more than 3000 ppm, c) a molar ratio of organic amines according to claims-to phosphorus-containing organic ligands according to claims-of at least 4:1 is established, d) a molar ratio of phosphorus-containing organic ligands according to claims-to rhodium of at least 10:1 is established.

Use of supported ionic liquid phase (SILP) catalyst systems in the hydroformylation of olefin-containing mixtures to aldehyde mixtures with a high content of aldehydes unbranched in the 2 position

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Sulzbach-Rosenberg, Germany

Michael Jakuttis