Evoqua Water Technologies Pte. Ltd.

Other

Michael J Shaw

Simon Paul Dukes

George Y Gu

Joshua Griffis

Li-Shiang Liang

Wenxin Du

Joseph D Gifford

Paul Beddoes

Michael J Muse

Savvas Hadjikyriacou

Darren Adrian Dale

Hao Dang

Gary C Ganzi

Frederick C Wilkins

Justin Wayne Higgs

Kee Hoe Ng

Rongqiang Fu

Ll-Shiang Liang

Methods for processing pretreated phosphogypsum wastewater are disclosed. The pretreated wastewater may be subjected to electrodialysis involving at least one monovalent cation selective membrane. Further downstream membrane treatment may be applied. Upstream precipitation and air-stripping techniques may optionally also be employed. Related systems are also disclosed.

Methods and systems for treating phosphogypsum-containing water

Methods for treating phosphogypsum-containing water are disclosed. The water may be treated so as to promote precipitation of one or more target constituents and to facilitate downstream membrane treatment. A coagulant may be added to promote phosphate recovery. Ammonia may optionally be removed. Related systems are also disclosed.

A method of operating an electrochemical device includes periodically discharging a volume of concentrate reject in a timed batch cycle and replacing the concentrate reject with feed water. An electrochemical water treatment system includes a recycle line having a valve controlled by a control module. The control module periodically opens the valve to discharge concentrate reject from the recycle line in a batch timed cycle. The recycle line is fed with feed water to replace the discharged concentrate reject.

Electrochemical system with concentration recirculation in cyclic batch mode

A water treatment system for producing potable water and water for irrigation from saline water, the system includes an electrodialysis apparatus including one or more monovalent selective membranes and having an inlet fluidly connectable to a source of water to be treated, a diluate outlet, and a concentrate outlet, a nanofiltration apparatus positioned downstream of the electrodialysis apparatus and having an inlet fluidly connectable to the diluate outlet of the electrodialysis apparatus, a permeate outlet, and a retentate outlet, and an electrolyzer in fluid communication with one of the concentrate outlet and the retentate outlet, and configured to generate a product stream including one or more of chlorine gas, hypochlorite ion, sodium hydroxide, sulfuric acid, hydrochloric acid, or sodium hypochlorite.

Treatment of saline water for agricultural and potable use and for generation of disinfectant solution

Methods of producing an ion exchange membrane support are disclosed. The methods include saturating a polymeric microporous substrate with a charged monomer solution comprising at least one functional monomer, a cross-linking agent, and an effective amount of at least one photopolymerization initiator and polymerizing the at least one functional monomer by exposing the saturated polymeric microporous substrate to ultraviolet light under conditions effective to cross-link the at least one functional monomer and produce the ion exchange membrane support. Methods of producing a monovalent selective ion exchange membrane are also disclosed. The methods include functionalizing an exterior surface of the ion exchange membrane support with a charged compound layer, drying the ion exchange membrane support and soaking the ion exchange membrane support in a solution comprising an acid or a base for an amount of time effective to produce the monovalent selective ion exchange membrane.

Ion exchange membrane through UV initiation polymerization

An electrochemical separation device includes a first electrode, a second electrode, and a cell stack including a plurality of sub-blocks each having alternating depleting compartments and concentrating compartments and each including frame and channel portions disposed between the first electrode and the second electrode. An internal seal formed of a first material is disposed between and in contact with the channel portions between adjacent sub-blocks in the cell stack and configured to prevent leakage between depleting compartments and concentrating compartments in the adjacent sub-blocks. An external seal formed of a second material having at least one material parameter different from the first material is disposed between and in contact with the frames of the adjacent sub-blocks in the cell stack and configured to prevent leakage from an internal volume of the electrochemical separation device to outside of the electrochemical separation device.

Sub-block sealing for electrochemical separation devices

A flow battery having at least one rechargeable cell is disclosed. The at least one rechargeable cell can include an anolyte compartment, a catholyte compartment, and an anion exchange membrane positioned between the anolyte and catholyte compartments. The anion exchange membrane can have a thickness of less than 100 μm and a steady state diffusivity of less than 0.4 ppm/hr/cmwith respect to a cation species in an electrolyte of the rechargeable cell. A method of facilitating use of a flow battery including providing the anion exchange membrane is also disclosed. A method of facilitating storage of an electric charge comprising providing the flow battery is also disclosed. A method of producing an anion exchange membrane is also disclosed.

Anion exchange membranes for redox flow batteries

A method of operating an electrochemical cell including introducing an aqueous solution into the electrochemical cell, applying a current across an anode and a cathode to produce a product, monitoring the voltage, dissolved hydrogen, or a condition of the aqueous solution, and applying the current in a pulsed waveform responsive to one of the measured parameters is disclosed. An electrochemical system including an electrochemical cell including an anode and a cathode, a source of an aqueous solution having an outlet fluidly connectable to the electrochemical cell, a sensor for measuring a parameter, and a controller configured to cause the anode and the cathode to apply the current in a pulsed waveform responsive to the parameter measurement is disclosed. Methods of suppressing accumulation of hydrogen gas within the electrochemical cell are also disclosed. Methods of facilitating operation of an electrochemical cell are also disclosed.

Pulsed power supply for sustainable redox agent supply for hydrogen abatement during electrochemical hypochlorite generation

An electrochemical cell including a first chamber having an anode, a second chamber having a cathode, at least one ionic connection between the first chamber and the second chamber, such that liquid electrolyte from the first chamber is prevented from mixing with liquid electrolyte in the second chamber is provided. The first chamber and the second chamber can be arranged in parallel and positioned remotely from each other. An electrochemical system including the electrochemical cell, and first and second sources of saline aqueous solutions is also provided. Water treatment systems are also provided. A method of operating an electrochemical cell including introducing first and second saline aqueous solutions into first and second chambers of the electrochemical cell, and applying a current across the anode and the cathode to generate first and second products, respectively is also provided. A method of facilitating operation of an electrochemical cell is also provided.

Half-cell electrochemical configurations for self-cleaning electrochlorination devices

An electrochlorination system includes an electrolyzer fluidically connectable between a source of feed fluid and a product fluid outlet, and a sub-system configured to one of increase a pH of the feed fluid, or increase a ratio of monovalent to divalent ions in the feed fluid, upstream of the electrolyzer.

Regulation of process stream composition for improved electrolyzer performance

A method of operating an electrochemical cell including introducing an aqueous solution into the electrochemical cell, applying a current across an anode and a cathode to produce a product, monitoring the voltage, dissolved hydrogen, or a condition of the aqueous solution, and reversing polarity of the anode and the cathode responsive to one of the measured parameters is disclosed. An electrochemical system including an electrochemical cell including an anode and a cathode, a source of an aqueous solution having an outlet fluidly connectable to the electrochemical cell, a sensor for measuring a parameter, and a controller configured to cause the anode and the cathode to reverse polarity responsive to the parameter measurement is disclosed. Methods of suppressing accumulation of hydrogen gas within the electrochemical cell are also disclosed. Methods of facilitating operation of an electrochemical cell are also disclosed.

Implementation of feedback control for improved electrochemical system design

An electrochlorination system comprising an electrochemical cell including a housing having an inlet, an outlet, and an anode-cathode pair disposed within the housing, a source of a chloride-containing aqueous solution having an outlet fluidly connectable to the inlet of the electrochemical cell, and a source of an oxidizing agent fluidly connectable to the source of chloride-containing aqueous solution upstream of the electrochemical cell.

In-situ delivery systems for reaction product abatement in electrochemical cells

Systems and methods for the desalination of seawater or brackish water for the purpose of obtaining potable water. Systems may include a combination of electrodialysis and electrodeionization modules. The system configuration and process controls may achieve low energy consumption and stable operation.

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Derry, NH, United States of America

Michael J Shaw