Nextech Materials, Ltd.

Nexceris Innovation Holdings, LLC

Michael J Day

Matthew M Seabaugh

Scott Lawrence Swartz

Paul H Matter

Katarzyna Sabolsky

Lora B Thrun

Buddy E McCormick

Jared R Archer

Todd G Lesousky

William John Dawson

Gene B Arkenberg

Chad T Sellers

Edward M Sabolsky

J Michael Funk

A sulfur tolerant anode current collector material includes a mesh or foam that includes a cermet. The cermet includes a metallic component and a ceramic component. The metallic component includes nickel, an alloy including nickel and cobalt, or a mixture including a nickel compound and a cobalt compound. The ceramic component includes a mixed conducting electrolyte material.

Current collectors for solid oxide fuel cell stacks

Electrode materials systems for planar solid oxide fuel cells with high electrochemical performance including anode materials that provide exceptional long-term durability when used in reducing gases and cathode materials that provide exceptional long-term durability when used in oxygen-containing gases. The anode materials may comprise a cermet in which the metal component is a cobalt-nickel alloy. These anode materials provide exceptional long-term durability when used in reducing gases, e.g., in SOFCs with sulfur contaminated fuels. The cermet also may comprise a mixed-conducting ceria-based electrolyte material. The anode may have a bi-layer structure. A cerium oxide-based interfacial layer with mixed electronic and ionic conduction may be provided at the electrolyte/anode interface.

High performance multilayer electrodes for use in reducing gases

An amperometric electrochemical sensor configured to be operable in an oxidizing atmosphere and under an applied bias to exhibit enhanced reduction of oxygen molecules at the sensing electrode in the presence of one or more target gas species and a resulting measurable increase in oxygen ion flux through the cell. The sensor has an electrolyte membrane, a sensing electrode on the electrolyte membrane, and a counter electrode on the electrolyte membrane, wherein the sensing electrode includes at least one molybdate or tungstate compound. An electrochemical sensor system is also provided, along with a method of detecting the concentration of one or more of NOx and NHin a gas sample or stream.

Amperometric electrochemical sensors, sensor systems and detection methods

Amperometric ceramic electrochemical cells comprise, in one embodiment, an electrolyte layer, a sensing electrode layer comprising a ceramic phase and a metallic phase, and a counter electrode layer, wherein the cell is operable in an oxidizing atmosphere and under an applied bias to exhibit enhanced reduction of oxygen molecules at the sensing electrode in the presence of one or more target gases such as nitrogen oxides (NO) or NHand a resulting increase in oxygen ion flux through the cell. In another embodiment, amperometric ceramic electrochemical cells comprise an electrolyte layer comprising a continuous network of a first material which is ionically conducting at an operating temperature of about 200 to 550&#xb0; C.; a counter electrode layer comprising a continuous network of a second material which is electrically conductive at an operating temperature of about 200 to 550&#xb0; C.; and a sensing electrode layer comprising a continuous network of a ceramic phase and a metallic phase which is electrically conductive at an operating temperature of about 200 to 550&#xb0; C., which sensing electrode is operable to exhibit increased charge transfer in the presence of one or more target gas species. These electrochemical cells and additional electrochemical cell embodiments are suitable for use in gas sensors and methods of sensing or detecting one or more target gases.

Amperometric electrochemical cells and sensors

A repeat unit for a fuel cell stack, the repeat unit having: a conductive interconnect plate; an electrolyte-supported fuel cell, wherein a dense sealing perimeter extends around the entire perimeter of the fuel cell; a cathode gasket adjacent the cathode side of the fuel cell; and an anode gasket adjacent the anode side of the fuel cell. First and second air manifolding ports, and first and second fuel manifolding ports are provided in each of the interconnect plate, dense sealing perimeter of the fuel cell, cathode gasket and anode gasket. An SOFC stack having an aligned stack of a plurality of repeat units is also provided, as well as an SOFC stack configured for cascade fuel flow.

Fuel cell repeat unit and fuel cell stack

Self-supporting thin film membranes of ceramic materials and related electrochemical cells and cell stacks. The membrane structure is divided into a plurality of self-supporting thin membrane regions by a network of thicker integrated support ribs. The membrane structure may be prepared by laminating a thin electrolyte layer with a thicker ceramic layer that forms a network of support ribs.

Two layer electrolyte supported fuel cell stack

Ceramic laminate structures, particularly laminate structures including stabilized zirconia compositions, as well as electrodes and electrochemical cells including such laminate structures. The stabilized zirconia composition preferably are selected from scandia-stabilized zirconia and yttria-stabilized zirconia. These laminate structures enhance the overall flexural strength of the electrolyte layer while preserving high electrical conductivity. Such laminate structures may be useful in electrochemical fuel cells such as solid oxide fuel cells.

Ceramic laminate structures

A dense ceramic electrolyte membrane supported by symmetrical porous ceramic electrolyte layers. The thin (t&#x3c;100 microns) electrolyte layer is sandwiched between two fugitive-containing electrolyte support layers that become highly porous after firing. The heat treated fugitive-containing support layers form a skeletal structure of strongly adhered electrolyte with an interpenetrating network of pores that extends well always from the electrolyte surface. The porous layers can be infiltrated with a range of electrode materials or precursors to form a solid oxide fuel cell or other electrochemical cell as well as electrochemical cell stacks. The supported ceramic membrane provides electrochemical performance advantages and reduces warpage during sintering compared to conventional structures.

Supported ceramic membranes and electrochemical cells and cell stacks including the same

Ceramic membranes with integral seals and support, and related electrochemical cells and cell stacks. The membrane comprises a thin electrolyte layer supported on a porous electrode layer which in turn is supported on a thick ceramic support layer, preferably a ceramic electrolyte support. The support layer is divided into a plurality of self-supporting thin membrane regions by a network of thicker integrated support ribs. The thin electrolyte layer and thick ceramic support layer preferably define a sealing perimeter surrounding the porous electrode layer.

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Dublin, OH, United States of America

Michael J Day