Arco Chemical Technology, L.p.

Arco Chemical Company

Michael J Cannarsa

Haven S Kesling, Jr

Hsiang-Ning Sun

Donald E Hostetler

Jeffrey A Klang

Frank J Liotta, Jr

Hsiang-ning Sun

Scott E Smyth

Daniel B Pourreau

Terence A Cooper

Thomas P Farrell

Hydroxy-functionalized polyoxybutylene ether compositions having improved thermal and oxidative stability are prepared by the polymerization of a mixture of C.sub.4 epoxides in the presence of an organic initiator containing hydroxy groups.

Hydroxy-functionalized polyoxyalkylene ether compositions derived from

Plasticized polyvinyl acetal resins based on 4-hydroxybutanal are disclosed. Laminar structures that include the resins, a process for making the resins, and a process for making an internally plasticized polyvinyl acetal resin by esterification, are also revealed.

Polyvinyl acetal resins based on hydroxyaldehydes and use of the resins

Discrete, non-agglomerating particles of polyalkylene carbonate are produced by solvent/non-solvent precipitation using certain solvent/non-solvent systems. The free-flowing particles obtained are from 30 to 3000 microns in diameter and are suitable for use in a variety of applications, particularly the preparation of foamed articles.

Formation of discrete polyalkylene carbonate particles by

Discrete, non-agglomerating particles of polyalkylene carbonate are produced by solvent/non-solvent precipitation using certain solvent/non-solvent systems. The free-flowing particles obtaine are from 30 to 3000 microns in diameter and are suitable for use in a variety of applications, particularly the preparation of foamed articles.

The selection of the proper solvent systems for polyalkylene carbonates which completely dissolve the polymer at high temperatures but are non-solvents at lower temperatures allows one to obtain discrete particles of the polymers suitable for many applications, processing and handling. The particles size can be controlled from about 30 to about 3000 microns in diameter.

Preparation of discrete particles of polyalkylene carbonate

The addition of a small amount of a second epoxide to the copolymerization of ethylene oxide or propylene oxide with carbon dioxide can give a melt processable polyalkylene carbonate terpolymer which can be processed without extensive thermal decomposition. This invention has particular utility in thermoplastic applications such as injection molding, blow molding, and film manufacture.

Melt processable aliphatic polycarbonate terpolymers

Copolymers or terpolymers of carbon dioxide and at least one epoxide are found to be useful in formulations for adhesive compositions. Polarity due to the carbonate group and non-polarity due to the alkylene groups in the resulting polyalkylene carbonates makes it possible to adhere a large number of different surfaces such as steel, aluminum, fluoropolymers, and polyesters to themselves or to each other.

Polyalkylene carbonate hot melt adhesive

The evaporative casting of molten metals has been shown to produce castings having smooth surfaces without any sign of carbon deposits thereon by using a copolymer polycarbonate prepared from cyclohexene oxide, cyclopentene oxide, cycloheptene oxide, or isobutylene oxide and carbon dioxide.

Process for preparing polycarbonate copolymer foam suitable for lost

The evaporative casting of molten metals has been shown to produce castings having smooth surfaces without any sign of carbon deposits thereon by using a terpolymer polycarbonate prepared from cyclopentene oxide or cyclohexene oxide, ethylene oxide, propylene oxide, or butylene oxide, and carbon dioxide in making patterns for the lost foam casting process.

Growing community of inventors

West Chester, PA, United States of America

Michael J Cannarsa