Dow Corning Corporation

Michael G Hales

David Robert Battice

William N Fenton

An improved process is provided for the preparation of siloxane-oxyalkylene block copolymer surfactant compositions which utilize a hydrosilylation reaction with a monocarboxylate ester of an alkanediol as the reaction solvent. The reaction solvent need not be removed from the block copolymer, particularly when the block copolymer is used as a surfactant for polyurethane foam formulations. 2,2,4-trimethyl-1,3-pentanediol monoisobutyrate is the preferred reaction solvent.

Process for the preparation of organopolysiloxane copolymers

What is disclosed is a method for preparing antimicrobially effective foams using certain silanes as co-catalysts, co-surfactants and antimicrobial agents to give soft, resilient, fine-celled foams that are capable of reducing the number of, or eliminating, microorganisms in all types of media. Such foams themselves are not susceptible to attack by the microorganisms. An example is the use of (CH.sub.3 O).sub.3 Si(CH.sub.2).sub.3 N.sup..sym. (CH.sub.3).sub.2 C.sub.18 H.sub.37 Cl.sup.- in a flexible polyurethane foam formulation to give a fine-celled, soft, resilient foam which is antimicrobially effective over a long period of time.

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Isabella County, MI, United States of America

Michael G Hales