Xerox Corporation

Michael F Cunningham

Hadi K Mahabadi

John A Creatura

Thomas Edward Enright

Michael J Duggan

Bernard A Kelly

Carl P Tripp

Thomas C Dombroski

Maria V McDougall

Denise Y Wright

Catherine A McKnight

Aron J Cogswell

Richard P N Veregin

Michael Steven Hawkins

Thomas W Smith

Paul Joseph Gerroir

George Liebermann

Nancy A Listigovers

John G Van Dusen

Daniel M McNeil

Heather M Wright

Sandra J Gardner

Richard P Veregin

Philip G Jessop

Timothy James Clark

Brian Ernest Mariampillai

Sean M Mercer

Kyle J Boniface

Tobias Robert

Resendes Rui,

Toner particles may be produced using a semisuspension polymerization process, which includes: (a) providing a mixture of a partially polymerized monomer or comonomers near the onset of the gel-effect; (b) forming a suspension of the partially polymerized monomer or comonomers; and (c) suspension polymerizing the partially polymerized monomer or comonomers while slowly adding a second monomer or comonomers in a starved feed manner. The process may be used to produce toner particles having varied particle properties, and having a morphology ranging from core-shell and inverted core-shell microcapsules to pseudo core-shell microcapsules and to polyblend composites having a low molecular weight phase dispersed in a high molecular weight matrix.

Polyblend polymeric composite and microcapsule toners, and a process for producing the same

A carrier comprised of a carrier core, optional polymer coating, and fluorosilanated pigment coating.

Carrier particles with halosilanated pigments

A process for the preparation of carrier powder polymer coatings which comprises the supercritical polymerization of two monomers and surfactant in a supercritical medium.

Supercritical polymerization processes

A process for the preparation of conductive polymers which comprises (a) mixing at least one monomer with at least one conductive component, solvent, at least one polymerization initiator, and an optional chain transfer component; (b) effecting solution polymerization by heating; (c) removing said solvent by azeotropic distillation in an aqueous phase to generate a mixture of polymer and conductive component; (d) drying and grinding the resulting mixture; thereafter dissolving the product resulting in at least one monomer, at least one initiator, and at least one crosslinking component, and an optional chain transfer agent to form an organic phase; (e) mixing said organic phase with a second aqueous phase comprised of water, stabilizer, and an alkali halide; (f) polymerizing the resulting suspension by heating; and (g) subsequently optionally washing and drying the polymeric product, and which product is comprised of polymer and conductive component dispersed therein.

Conductive polymers

Conductive polymeric particles can be formed by mixing a monomer, carbon black and a block copolymer, wherein the block copolymer contains an A block that is miscible with said monomer and a B block that anchors to the surface of the carbon black, such as polystyrene or a derivative of polystyrene. A polymerization initiator is added to the mixture and bulk polymerization is effected until about 5 to about 30 weight percent of the monomer has been polymerized. This partially polymerized product is then dispersed in water and further polymerized.

Conductive particles containing carbon black and processes for the

A conductive carrier composition comprised of a core with a coating thereover comprised of a mixture of first and second polymers, and wherein the first polymer contains a conductive component, and the second polymer contains a metal oxide.

Conductive developer compositions with coated carrier particles

A process for the preparation of conductive polymeric particles with linear and crosslinked portions, which comprises mixing a monomer with at least one conductive filler, solvent, at least one polymerization initiator, and a chain transfer component; effecting solution polymerization by heating until from about 80 to about 100 weight percent of the monomer has been polymerized; drying the mixture by removing the solvent to yield an intimate blend of polymer with conductive filler; dispersing the aforementioned blend of polymer and conductive filler in at least one monomer with at least one polymerization initiator, a crosslinking agent and a chain transfer agent to form an organic phase; dispersing the resulting organic phase mixture in water containing a stabilizing component to obtain a suspension of particles with an average volume diameter of from about 0.05 to about 5 microns in water; polymerizing the resulting suspension by heating; and subsequently optionally washing and drying the polymeric product.

Process for preparing conductive polymeric particles with linear and

A process for the preparation of conductive carrier particles which comprises mixing carrier core with a first polymer pair and a second polymer pair, heating the mixture, and cooling the mixture; and wherein the first and second polymer pair each contain an insulating polymer and a conductive polymer and wherein the carrier conductivity thereof is from about 10.sup.-6 to about 10.sup.-14 (ohm-cm).sup.-1.

Coated carrier particles and processes thereof

A process for the preparation of polymer which comprises effecting a bulk polymerization of a mixture containing at least one monomer, a chain transfer agent, a crosslinking agent, a free radical redox polymerization initiator pair, and at least one additional free radical initiator until from about 4 to about 50 weight percent of the monomer has been polymerized and one or both components in the redox initiator pair has been consumed; dispersing with a high shear mixer the aforementioned partially polymerized mixture in water containing a stabilizing component selected from the group consisting of nonionic and ionic water soluble polymeric stabilizers to obtain a suspension of particles; polymerizing the resulting suspension; and optionally subsequently insulating, washing and drying the polymer product.

Process for preparation of conductive polymeric composite particles

A process for preparation of conductive carrier particles which comprises mixing carrier core with a first polymer pair and a second polymer pair, heating the mixture, and cooling the mixture; and wherein the first and second polymer pair each contain an insulating polymer and a conductive polymer and wherein the carrier conductivity thereof is from about 10.sup.-6 to about 10.sup.-14 (ohm-cm).sup.-1.

A process for the preparation of conductive submicron polymeric particles which comprises mixing at least one monomer with a polymerization initiator, a crosslinking component, and a chain transfer component; adding thereto an AB type block copolymer; effecting bulk polymerization until from about 10 to about 50 weight percent of the monomer has been polymerized; terminating polymerization by cooling the partially polymerized monomer; adding thereto from about 1 to about 50 weight percent of a conductive filler, or conductive fillers, followed by mixing thereof; dispersing the aforementioned mixture of conductive filler or fillers, and partially polymerized product in water containing a stabilizing component to obtain a suspension of particles with an average diameter of from about 0.05 to about 1 micron in water; polymerizing the resulting suspension by heating; and subsequently optionally washing and drying the product.

Conductive composite particles and processes for the preparation thereof

A process for the preparation of carrier powder polymer coatings which comprises the supercritical polymerization of a monomer and surfactant in a supercritical medium to form a porous polymer, and thereafter adding thereto a conductive filler.

Growing community of inventors

Georgetown, Canada

Michael F Cunningham